Beside the point, yet possibly of interest:

On Sun, Jun 16, 2013 at 03:07:01AM +0200, Jan P. Kessler wrote:
> # /opt/vrnetze/openssl/bin/openssl s_client -connect
> mxtls.allianz.com:25 -starttls smtp
> CONNECTED(00000004)
snip
> ---
> 250 HELP
> HELO mail.EXAMPLE.COM
> 250 mailgw.allianz.de Hello mail.EXAMPLE.COM [91.235.236.8], 
> pleased to meet you
> MAIL FROM:j...@example.com
> 250 2.1.0 j...@example.com... Sender ok
> RCPT TO:xxx....@example.com
> RENEGOTIATING
> [CTRL+C]

Excerpt from s_client(1) manual:

"
CONNECTED COMMANDS
 If a connection is established with an SSL server then any data 
received from the server is displayed and any key presses will be 
sent to the server. When used interactively (which means neither 
-quiet nor -ign_eof have been given), the session will be 
renegotiated if the line begins with an R, and if the line begins 
with a Q or if end of file is reached, the connection will be closed 
down.
"

Your workaround is to use lowercase "r" in your RCPT TO command:

rcpt to:<xxx....@example.com>
rCPT TO:<xxx....@example.com>
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