> On 8 Feb 2022, at 6:14 am, Nitin N <nitin.wo...@gmail.com> wrote:
> 
> I am trying to run multiple instances of Postfix using Postmulti on a single 
> NIC using aliased IPs. Postmulti doesn't seem to bind the instances to the 
> aliased IPs. I do not get any errors in the maillog and all instances are 
> shown as having started fine.

The "postmulti" command is not involved with IP addressing.  Each
Postfix instance's master(8) process binds the listen endpoints of
"inet" services specified in master.cf at the addresses that are
specified either explicitly for each server ([address:]service),
or via "inet_interfaces" in main.cf.

Note also the setting of:

        master_service_disable

which defaults to "inet" for freshly minted secondary instances.

You've not shared any configuration details (postconf -nf for
the primary and at least one secondary instance) so hard to
provide specific advice.

Basically, read the documentation more closely, and take time
to give each instance an explicit "inet_interfaces" setting
(not smtp_bind_address, you don't need that) and then enable
"inet" services.

-- 
        Viktor.

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