check Help file for: "auto run when a window opens"
steps:

Create a commandlist called: "AutoRun"

[1]
Label = $=msgviewer
LCmd1 = win.traymin("AutoRun")
MCmd1 = (none)
RCmd1 = (none)

[2]
Label = $=appbridge
LCmd1 = win.hide("AutoRun")
MCmd1 = (none)
RCmd1 = (none)

the names I provided above is an example, put the real exename in there w/o the 
.exe
then, Configure > Command Lists | Setup > Special Lists ! Open:
in the dropdown, select "AutoRun" and apply.

Also, PowerPro can group several windows in the taskbar.
Configure > Command Lists | Setup > All Bars | "windows to show on active bars"
in the dropdown, select "1 per exe file"
Rearranging them AFAIK, not possible, however, if you do need to use such a 
feature I recommend Taskix, smaller than Taskbar Shuffle but does only that, 
google it...

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