Thanks for the info. When I have more time again I'll try some more combos 
if needed, but was able to get this to work with the below, I've also never 
put the NE args directly in a unit file they've always been sourced in 
exactly like the default config which is where I got the unit file from.

$ systemctl --version
> systemd 219
> +PAM +AUDIT +SELINUX +IMA -APPARMOR +SMACK +SYSVINIT +UTMP +LIBCRYPTSETUP 
> +GCRYPT +GNUTLS +ACL +XZ +LZ4 -SECCOMP +BLKID +ELFUTILS +KMOD +IDN


 $ tail -n1 /etc/sysconfig/node_exporter
> OPTIONS="--web.listen-address=0.0.0.0:9100 --web.max-requests=16 
> --collector.processes 
> --collector.diskstats.ignored-devices=^(sr0|sda1|sda2|sda3|dm-0|dm-1|dm-2|dm-3)$
>  
> --collector.filesystem.ignored-mount-points=^/(boot|dev|proc|sys|var/lib/docker/.+)($|/)
>  
> --collector.filesystem.ignored-fs-types=^(rootfs|tmpfs|autofs|binfmt_misc|bpf|cgroup2?|configfs|debugfs|devpts|devtmpfs|fusectl|hugetlbfs|mqueue|nsfs|overlay|proc|procfs|pstore|rpc_pipefs|securityfs|selinuxfs|squashfs|sysfs|tracefs)$"

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