as a 1st test of this pyside build, a downstream build of 
Pyside&Shiboken-dependent FreeCAD, using the install described in this^ thread,

with config including

        ...
        -DPySide2_DIR=/usr/local/lib/cmake/PySide2-5.14.1 \
        -DShiboken2_DIR=/usr/local/lib/cmake/Shiboken2-5.14.1 \
        -DPYSIDE2RCCBINARY=/usr/local/bin/rcc \
        -DPYSIDE2UICBINARY=/usr/local/bin/uic \
        ...

_does_ complete without apparent error

        FreeCAD --version
                FreeCAD 0.19 Revision: 19717 (Git)

        ldd `which FreeCAD` | egrep -i "pyside|shiboken|pivy"
                libpyside2.cpython-38-x86_64-linux-gnu.so.5.14 => 
/usr/local/lib/libpyside2.cpython-38-x86_64-linux-gnu.so.5.14 
(0x00007f7f2ca10000)
                libshiboken2.cpython-38-x86_64-linux-gnu.so.5.14 => 
/usr/local/lib/libshiboken2.cpython-38-x86_64-linux-gnu.so.5.14 
(0x00007f7f2c7c5000)

(again, note libs are in wrong-arch libdirs, /lib not /lib64 ...)

on launch, the app _does_ start, and seems nominally functional.

non-fatal launch errors include,

        During initialization the error "No module named 'PySide2'" occurred in 
/usr/local/FreeCAD/Mod/Tux/InitGui.py
        Please look into the log file for further information
        During initialization the error "No module named 'PySide2'" occurred in 
/usr/local/FreeCAD/Mod/AddonManager/InitGui.py
        Please look into the log file for further information
        During initialization the error "No module named 'PySide2'" occurred in 
/usr/local/FreeCAD/Mod/Draft/InitGui.py
        Please look into the log file for further information
        Error: Pivy not found, Draft Workbench will be disabled.
        Unknown command 'Std_AddonMgr'

I _suspect_ those are FreeCAD-config related; for later
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