Thank you Seth  and Duncan for your input! 

> BTW, do you have a schema for the XML document you are working on?

Yes, a schema is available here
http://psidev.sourceforge.net/ms/xml/mzdata/mzdata.xsd
Informations around mzData xml format are available here
http://psidev.sourceforge.net/ms/#mzdata

Next question I want to come up with: is there a way to validate xml
again a schema or a dtd while parsing using xmlEventParse()?

cheers
        Jan

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