<<
Is it possible to make my app send a email to me when someone starts my app
and could this process be invisible to the user?
>>

Yes, if the user has an internet connection and 1) you can program his mail 
server info into your application or 2) you have available to you a mail server 
that will accept mail relayed from any address without authentication.

Consider also either storing the login information in the database and 
connecting when you want to see it or setting up your own server that would 
accept an incoming HTTP PUT request to log the user's use and then LAUNCHing 
that request on user startup.
--
Larry


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