We are only on your back until you to do the advisable thing: Sell them a 
battery capacity monitor. It is a hard fact that NO off grid, battery based 
power system should be without a battery capacity monitor. They are cheap (only 
$150!) and not an option. Apparently, it is also hard learned fact. ;-)

Larry Crutcher
Starlight Solar Power Systems




On Nov 16, 2011, at 12:20 AM, Ron Young wrote:

> Hi Larry, no amp hour meter installed yet as the customer is penny pinching. 
> We're trying to solve the problem first and I've been out there twice, once 
> to do general diagnostics and check all connections, try to load test the 
> batteries, and so on; the second time I 'dropped in' to try a different load 
> test on the batteries to see if I could replicate the problem and to resolve 
> some other problems with a Whisper controller that had given up the ghost 
> when disconnected & re-connected to the batteries (all precautions taken). 
> It's a seven hour round trip and with time spent on the job makes for an 
> expensive service call. I only charged for one call and I have to go back at 
> least once more. So customer wanted to save some money on the installation of 
> the TriMetric until the spring... sorry for the long winded reply. I know, 
> it's false economy. So I'm thinking I'll just put the meter in and tell them 
> to pay me when they feel like it. It'll help solve the problem and get some 
> of the Wrenches off my back ... ;-)
> 
> Ron Young
> 
> On 2011-11-13, at 8:26 AM, <[email protected]> 
> <[email protected]> wrote:
> 
>> Ron,
>> I stick by my evaluation as seen here: 
>> http://www.mail-archive.com/[email protected]/msg10694.html
>> 
>> The #1 reason for my opinion is that you can NOT drive up voltage on a 
>> healthy bank that size in just 5 minutes. It is impossible with a 2500 watt 
>> generator.
>> 
>> Here is the pertinent part from my post:
>> You mentioned that the the battery drops to 24.5 in the early AM without any 
>> heavy loads on. For the 4KS25 battery this equates to about 800AH at the 72 
>> hour rate. Then you said that the customer ran a 2500 watt generator for 5 
>> minutes and drove the voltage up to 29 volts. Here's the Ah-Ha moment: That 
>> is EXACTLY the behavior of a heavily sulfated battery bank. A fast rise in 
>> voltage indicates sulfation. It is impossible for that tiny generator, or 
>> any charge source they own for that matter, to replace the hundreds of AH it 
>> would take to drive a healthy battery up to the absorb voltage of 29 volts. 
>> The bank is about 45,000 watt hours (72h rate). There would have to be over 
>> 20,000 Wh removed to be at that voltage. How many Wh's are replaced in 5 
>> minutes by a 2500 watt genny? I'm sure you are getting the picture. 
>> 
>> Also, why have you not installed a battery monitor yet? It will give you 
>> "eyes" into the battery and spare countless hours of time diagnosing the 
>> problem.
>> 
>> Larry
>> 
>> -------- Original Message --------
>> Subject: Re: [RE-wrenches] intermittent battery problem; ...Battery
>> Sulfation
>> From: Ron Young <[email protected]>
>> Date: Sat, November 12, 2011 9:57 pm
>> To: RE-wrenches <[email protected]>
>> 
>> Folks, this one really has me puzzled. The client has done regular two hour 
>> EQ's, at least once a month. When did a site visit and I topped up the 
>> electrolyte (they'd been starving the batteries for water but always just 
>> above the plates) the problem seemed to go away. They were satisfied that 
>> the problem was solved but I wasn't and I told them what I had been hearing 
>> from this group - essentially that the batteries needed a deep EQ, 
>> discharge, recharge and EQ again two or three times to scrub the sulphates. 
>> They declined until just a few days ago when they said the rapid voltage 
>> drop was back. Here's a quote:
>> 
>> We had another rapid voltage loss this morning ---it was 25.2 when we got up 
>> and it dropped rapidly to 22.8.  We turned on the generator and charged the 
>> batteries until our display showed 30.2  for awhile with the generator 
>> running.  We turned off the generator and the voltage settled at about 26.4. 
>>  We turned off all loads and wind and solar.
>>   
>> At 9.15 our batteries were at 26.4
>> At 9:16 we turned on an 8W light bulb, a1600W hair dryer, and a 1.5HP (120V 
>> 5.75A) shop vac
>> The display showed a load of 1.9kw
>> At 9:40 the inverter shut down---display showed batteries at 18.4
>> By 9.47 the display showed the batteries at 25.2----the solar and wind were 
>> still shut down.
>> We turned everything back on (a light, Sunfrost RF16, phone)  and all seems 
>> to be normal.
>> 
>> They agreed to do the EQ process but only have a 3kw generator so we started 
>> with 8 hours with the EQ voltage set for 32v (24v system). They completed 
>> that yesterday and here's what resulted:
>> 
>> Before starting EQ the batteries were at 25.8, hydrometer reading 1283 with 
>> temp. correction
>> Began EQ                                            32.6 v                   
>>                                                       Buying 1.5 kw
>> Hour 1                                                  32.4 v               
>>              1283  with temp. correction       Buying  1.4
>> Hour 2                                                  32.4 v               
>>                1285  with temp. correction      Buying 1.5
>> Hour 3                                                  32.2 v               
>>                                                          Buying 1.7
>> Hour 4                                                  32.2 v               
>>                1290  with temp correction        Buying 1.8
>> HOur 5                                                 32.0 v                
>>               1290   with temp correction        Buying 1.8 
>> Hour 6                                                  32.0 v               
>>                                                          Buying 1.9 
>> Hour 7                                                  31.8 v               
>>                 1292 with temp correcton        Buying 1.9
>> Hour 8 complete---turned off Gen and turned on loads ---Batteries dropped to 
>> 25.4 within 30 minutes and stayed there until this morning---fridge was 
>> running, telephone, internet, wool carding machine, lights.  This morning 
>> hydrometer reading  was at 1290.
>>> 
>> 
>> 
>> Then today I just got this email:
>> 
>> Just experienced another rapid voltage drop.  As soon as the voltage hits 
>> 24.8 the voltage drops like a rock if we don't have any input (no solar or 
>> wind).
>> 
>> This is not what I expected after a lengthy EQ. I'm getting them to do 
>> another one tomorrow after a discharge cycle and charge but I'm really 
>> beginning to think we have something else going on here, something 
>> electrical, not chemical. The rapid voltage drop is puzzling. 
>> 
>> To review, it's an Outback 3524 on an Epanel, Whisper 100 & controller, 6 
>> 4KS 25 Surrette batteries in 24v configuration - 4.5 years old, .7kw solar. 
>> I know the charging end is undersized but they have been compensating with 
>> the generator and they get lots of wind in the fall, winter, spring.
>> 
>> Any more thoughts on this anyone?
>> 
>> Best Regards,
>> Ron Young
>> earthRight Products - Solareagle.com
>> Alternative Energy Solutions ~ Renewable Energy Products
>> 
>> 
>> On 2011-10-24, at 6:50 AM, Larry Crutcher, Starlight Solar Power Systems 
>> wrote:
>> 
>>> Hi Ron,
>>> Accurate SG readings are not simple. Was temperature compensation properly 
>>> employed? Have they been keeping a log book to identify changes? How 
>>> accurate is the hydrometer? How skilled is the person taking the reading? 
>>> 
>>> Most of the Battery Wrench responses suggest equalization but I don't see 
>>> from any of your posts that this has been done yet. I suggest this to be 
>>> the next step and I recommend that you carefully watch voltage and current. 
>>> This will tell you a lot. I use a Fluke ScopeMeter in the TrendPlot mode 
>>> and track voltage and current over time. It provides a good visual 
>>> understanding.
>>> 
>>> In case others are using this forum to glean information, attached is a 
>>> chart for illustration of the charge cycle. You should see a constant, 
>>> somewhat linear rise in voltage until the constant voltage setting is 
>>> reached. If you see a sudden rise: suspect sulfation. If you see a quick 
>>> reduction in current: suspect sulfation. The current should drop to about 
>>> 8-10 amps at the constant voltage towards the end of charge cycle. The 
>>> health and DoD will determine the time this takes, expect many hours. Begin 
>>> equalization.
>>> 
>>> <3s-chart.gif>
>>> 
>>> A couple other points: Is the MX absorb voltage at 29.6V? Did you program 
>>> the MX controller for an extended absorb time (advanced menu, absorb time 
>>> limits)? The default setting is poor for large batteries. I use 90 minutes 
>>> minimum and 4 hours max. This can greatly reduce the possibility of 
>>> undercharging the battery but it may use more water. The timer (ChgT) will 
>>> determine how long it stays in absorb each day.
>>> 
>>> Larry Crutcher
>>> Starlight Solar Power Systems
>>> 
>>> On Oct 24, 2011, at 12:49 AM, Ron Young wrote:
>>> 
>>>> Hi Larry,
>>>> 
>>>> I immediately assumed sulphated battery when I heard the customers 
>>>> description a couple of weeks ago but the hydrometer readings didn't jive. 
>>>> Any sulphated battery I've encountered, and I defer to your greater 
>>>> experience, has always revealed itself with a simple S.G. test and these 
>>>> batteries were reading above 1.265. I then thought the possibility of a 
>>>> defective hydrometer and had them test with another but we just got 
>>>> confirmation of the same thing. 
>>>> 
>>>> The weird drop in voltage also isn't explained by your description. Why 
>>>> would this just happen without loads or charging present (except maybe the 
>>>> DC Sunfrost load) at the same predictable time at 4 a.m. The fact that 
>>>> when the generator was turned on and sent a surge of current into the 
>>>> system and the problem went away made the detective in me think there had 
>>>> to be another explanation. The bank was at rest for several hours through 
>>>> the night and the voltage dropout was cured by a brief application of 
>>>> charge current. 
>>>> 
>>>> When I arrived on site my discovery that the client was under watering the 
>>>> batteries and this chronic condition resulted in a very rich electrolyte, 
>>>> reading well above 1.265 - into the 1.280 range made me think that was the 
>>>> problem and it seems to have gone away now that the electrolyte level was 
>>>> raised and the batteries given a good charge. But it still nags at me that 
>>>> something else is lurking in the shadows. Your description of the sulphate 
>>>> converting to a crystalline form has me worried because if this is the 
>>>> case this expensive battery bank is in danger. I would have to camp out at 
>>>> the site and monitor the charging over a day or so. I'm going to forward 
>>>> some of your comments and those of others that have generously offered 
>>>> suggestions and we'll see if I can convince the client who now believes 
>>>> everything is A-Ok.
>>>> 
>>>> Best Regards,
>>>> Ron Young
>>>> earthRight Products - Solareagle.com
>>>> Alternative Energy Solutions ~ Renewable Energy Products
>>>> 
>>> 
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