Dear All.

I fully support the nice idea of Helio for establishing a powder diffraction
Database. If we can make it, this will be one of the biggest achievements of
these two groups (Rietveld and SDPD). My personal opinion is that such a
database will provide excellent opportunities for inter-labs cooperation and
will surely improve our skills. The advantages:
1. Large number of powder diffraction patterns with Lab X-ray, neutron and
synchrotron will give to the people chance to get familiar with different
diffraction spectra,
2. Everyone will have a chance to exercise himself on different samples:
well and poorly crystalline, modulated structures, defect structures,
standards, pure and mixed materials,
3. Different applications of the Rietveld refinement can be done by number
of people: from more routine ones as simple structural refinement,
quantification, particles size, site occupancy to some details of the
refinement - rigid body adjustment, lattice strain etc.,
4. For SDPD purposes the usefulness of such database is even more obvious -
one can try to solve the structure by using other approach than the authors
+ some other varieties in the overall strategy.

I think that the goodness of creating and maintaining the Database is
obvious for every one. Now, the question is HOW we will do it. My suggestion
is that if someone (how about it, Lachlane?) agree to create it we have to
set a rules such as:
Everyone can submit the file(s) + a written text (free format, in Notepad
for easy opening from everyone), in which he have to provide all info about
the sample/experiment (if the data are not published yet) + his e-mail
address. These of us that will work on his/her sample/pattern will further
contact him/her for practical details, instead to bother the rest of the lists.
Note that such inter-labs work will give another answer: why quite often the
same data refined by different people provide different R-values and even
some differences in the refined parameters? This happened this summer, when
we refined the same data set using GSAS with Ms. N. from Italy.
Anyway, I am really a great supporter of this nice idea and hope that it
will be made very soon.
However, I do not agree that PDF-3 can do the same job. We are talking about
creation of something else - a large varieties of data sets from DIFFERENT
samples for improving our capabilities of refining/solution of crystal
structures, but not to make any kind of reference database like PDF-3.

Regards,

Srebri

/\/\/\/\/\/\/\/\/\/\/\/\/\/\/\/\/\

Dr. Sr. Petrov/PXRD Analyses,
Dept. of Chemistry, U of T,
80 St.George Str., R.417
Toronto ON M5S 3H6, Canada
Tel/Fax: (416)-978-1389.
e-mail: [EMAIL PROTECTED]

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