Dear Rietvelders,

I would appreciate your help in the following problem,

Even with a stoichiometric mixture of starting materials, NdBa2Cu3Oy is
known to form a solid solution of the type Nd1+xBa2-xCu3Oy(Non
stoichiometric). So a small amount of BaCO3 and CuO are expected to be the
impurities.

I have taken two models

1.NdBa2Cu3O7 (Stoichiometric)
2.Nd(Ba1-xNdx)2Cu3O7 (Non-stoichiometric)

I have considered the following cases with XND. 

      Stoichiometric?    Impurites included?
1.    Yes                No
2.    No                 No
3.    Yes                Yes
4.    No                 Yes

I have obtained different R factors. Now I want to decide which is the
most correct model. I have been suggested to use Hamilton R-factor
ratio test.

Could anybody give me the details of Hamilton R-factor ratio test?

Thanks 

-Nagesh Kini
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