Hi,

 

I am a new member of the mailing list. My name is Maria Chrysochoou and I am
a ph.D. student in Environmental Engineering at Stevens Institute of
Technology, USA. I deal with soils, cements and cementitious systems in my
research and currently use Rietveld to study the mineralogy of a
cementitious waste. I use the Jade software by Materials Data Inc. I have
the following problem, if anyone can provide some insight:

The cementitious system I study contains common cement phases, such as
ferrite and periclase, and several alteration products, which have much
lower absorption coefficients. The problem is that the system contains
temperature sensitive phases and we are forced to hand-grind our samples
down to a #400 sieve (37 μm). We have not managed to reduce the particle
size further manually. 

I have two questions:

1)       Would you recommend the micronizing mill for a high-pH,
temperature-sensitive system that contains a lot of Al-phases? How would you
suggest to deal with the microabsorption problem?

2)       Would you trust Rietveld results without microabsorption correction
at this particle size (37 μm)?

 

Thanks,

 

Maria Chrysochoou

W.M. Keck Geoenvironmental Laboratory

Stevens Institute of Technology

Tel.: +1 201 216 8773

Fax: +1 201 216 8212

E-mail: [EMAIL PROTECTED] 

 

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