Hi all, 

 

I have a question concerning density calculations, 

I'm actually working on an amorphous phase quantification method using
Rietveld and most part of the samples I'm working with contain high
quantity of silica (amorphous and crystalline). 

I've attentively read the paper: "Determination of the crystallized
fractions of a largely amorphous multiphase material by the Rietveld
method" (X. Orlhac, C. Fillet,...) and I found out that the Brindley
correction can be applied in my case. 

When I calculate the linear absorption coefficient of each phase I must
to take into account also the amorphous phase, isn't it? . I just would
like to know if someone could indicate me how to calculate this factor
making difference between an amorphous and a crystalline phase (for
example, concerning silica). 

I know the atomic absorption coefficient of each element must be
multiplied by the packaging density in the case of powders but it just
talks about the crystalline phases, what about the amorphous phase? 

 

Thanks for your help

 

Sincerely, 

 

Maria Fabra Puchol
Responsable Laboratoire Structures
Structural Laboratory Manager
-------------------------------------
Saint-Gobain CREE 
550 Avenue Alphonse Jauffret 
BP224
84306 Cavaillon Cedex - France
 
tel: 00 33 4 32 5  09 36
fax: 00 33 4 32 50 08 51
e-mail: [EMAIL PROTECTED]

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