expr.poly(x) does not really make expr a polynomial in x, it's a quite 
useless method.
If you give no parameter to ex.coefficients() it takes the 
lexicographically first variable.
So instead of ex.poly(x).coefficients do ex.coefficients(x), and you get:

sage: (zeta*diff(f(tau), tau)).coefficients(tau)
[[zeta*diff(f(tau), tau), 0]]
sage: (zeta*diff(f(tau), tau)).coefficients(zeta)
[[diff(f(tau), tau), 1]]
sage: (a*diff(f(b), b)).coefficients(a)
[[diff(f(b), b), 1]]
sage: (a*diff(f(b), b)).coefficients(b)
[[a*diff(f(b), b), 0]]

Regards,

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