One more time,

THE PRACTICE of expressing the strength of a vitamin preparation in "units"
is a relic t
of the days before isolation of the pure chemical substance. Units represent
the first approximation attempts at dealing quantitatively with the new
factor in question, and were a
convenient device to express the activity of a preparation containing an
unknown amount
of an uncharacterized material. The availability of crystalline vitamins
made it possible
and desirable to work in terms of milligrams or micrograms of the pure
substance.
The accuracy of any assay is enhanced when a standard product is available
for comparison. Standard vitamin preparations were first made available by
the Permanent Commission
on Biological Standardization of the Health Organization of the League of
Nations and
distributed through National Control Centers to qualified investigators. Its
functions have been assumed by the Expert Committee on Biological
Standardization of the World
Health Organization. These standards are widely used for research and to
prepare work
ing standards for use by manufacturers and enforcement agencies.
International standards
have been established for vitamins A, B1, C,D and E. An "International Unit"
is, by definition, based on the activity of an International Standard
preparation. The United
States Pharmacopoeia Convention has been designated as the Control Center
for the
United States. Its Committee on Reference Standards has extended the work of
the
original Commission until USP standards for ascorbic acid, calcium
pantothenate, choline
chloride, nicotinamide, nicotinic acid, pyridoxine hydrochloride,
riboflavin, thiamine
hydrochloride, eight "essential" amino acids, vitamin A and vitamin D (forms
for both rat
and chick assay) are now available. (Address USP Reference Standards, 46
Park Ave., New
York 16, N. Y.) When an International Standard exists, the U.S.P. standard
is compared
and brought as closely as possible into agreement. Therefore, a "USP unit"
is equal to an
"International Unit." The existence of adequate standards has proved a boon,
both to research workers and to Federal and state control officials.

Vitamin A

1 I.U. = 1 USP unit the vitamin A activity of .344 micrograms of crystalline
vitamin A acetate, corresponding to .30 micrograms of vitamin A alcohol.

Provitamin A: beta-carotene

1 I.U. = 0.6 micrograms of beta-carotene. The International Standard is a
solution in vegetable oil, containing 200 I.U. per gram.

Vitamin D

1 I.U. = 1 USP unit= the vitamin D activity of 0.025 micrograms of
crystalline vitamin D3. Products assayed against this new standard (official
May 1, 1951) will have only 93.4 per cent of the unit dosage? shown when
assayed against the last USP Cod Liver Oil Reference Standard.

An even greater difference is shown when the new USP Standard is used for
assay of chicken feeds. Products assayed against the new standard show about
75 per cent of the unitage shown when assayed against the last USP Cod Liver
Oil Reference Standard. In order to differentiate between the present
A.O.A.C. Chick Unit, and the new Unit which is 33 per cent larger, the term
"International Chick Unit" has been adopted.

Other vitamin units

The activity of other vitamins is expressed as the weight in milligrams or
micrograms of the various chemically pure materials.

One still occasionally encounters values for vitamins other than A and D
listed in "units". For reference use, we list these below.

Thiamine: 1 I.U. = the thiamine activity of 3.0 micrograms of crystall.ne
thiamine hydrochloride.

Ascorbic acid: 1 I.U. = the vitamin C activity of .05 mg. of 1-ascorbic
acid.

Vitamin E: 1 I.U. = the vitamin E activity of 1 milligram of synthetic,
racemic alphatocopherol acetate.






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