Re: [geo] RE: recent papers on marine ecosystem geoengineering

2013-02-11 Thread rongretlarson
Greg (cc list and pboyd): 

I like your paper. But I wonder if the concept of using ocean biomass for 
harvest and eventual partial placement of half the carbon in soil (as 
biochar) was inadvertently or intentionally omitted. 

I see major advantages of using ocean biomass (macroalgae and smaller) for 
biochar as worthy of your and this list's consideration for these reasons, that 
seem not to be shared by the options you did discuss: 

a. it provides rather than consumes energy 
b. the generated energy can be of any form - solid, gas or liquid - for any end 
use sector. My preference is to back up wind and solar, not for base load 
service. 
c. It can improve most soil types - almost all of which are rapidly depleting - 
with significant improved out-year nutrition benefits from increased primary 
production. 
d. the carbon sequestration, although not infinite, is possibly measured in 
millennia, certainly centuries - perhaps longer than some you include. 
e. such harvesting is already occurring, and generally the practice would seem 
to have little international legal/moral concern, especially if practiced in 
near-shore waters. 

Ron 

- Original Message -
From: Greg Rau r...@llnl.gov 
To: pb...@chemistry.otago.ac.nz, geoengineering@googlegroups.com 
Sent: Sunday, February 10, 2013 9:44:13 PM 
Subject: [geo] RE: recent papers on marine ecosystem geoengineering 


Nor should iron fertilization necessarily be viewed as the poster child for 
marine CDR. Some other ideas attached - I was limited to 2,00O words. 
-Greg 




From: geoengineering@googlegroups.com [geoengineering@googlegroups.com] on 
behalf of Philip Boyd [pb...@chemistry.otago.ac.nz] 
Sent: Sunday, February 10, 2013 6:54 PM 
To: geoengineering@googlegroups.com 
Subject: [geo] FW: recent papers on marine ecosystem geoengineering 





Dear Geo group, I have noticed that much of the discussion on this topic are 
based on older papers. Here is a recent one. 




Williamson P., D. W.R. Wallace , C.S. Law, P.W. Boyd, Y. Collos, P. Croot, K. 
Denman, U. Riebesell, S. Takeda, C. Vivian (2012) Ocean fertilization for 
geoengineering: A review of effectiveness, environmental impacts and emerging 
governance. Process Safety and Environmental Protection, 9, 475–488. 

and also a link to a Theme Section on this topic from 2008 

Implications of large-scale iron fertilization of the oceans 
Idea: Howard Browman, Philip W. Boyd 
Coordination: Philip W. Boyd 


MEPS 364:213-309 | Complete Theme Section in pdf format (2 MB) 



Philip 

Professor Philip Boyd FRSNZ 
NIWA Centre of Chemical  Physical Oceanography 
Department of Chemistry 
University of Otago 
Dunedin 
New Zealand 

03-479-5249 


From: geoengineering@googlegroups.com [geoengineering@googlegroups.com] On 
Behalf Of Ken Caldeira [kcalde...@carnegiescience.edu] 
Sent: Monday, February 11, 2013 1:06 PM 
To: drisc...@atm.ox.ac.uk 
Cc: geoengineering 
Subject: Re: [geo] A Cheap and Easy Plan to Stop Global Warming By David 
Rotman 



A nicely done article. 


I would like to expand on one of Ray Pierrehumbert's comments. 


He is quoted as saying: 


“The term ‘solar radiation management’ is positively Orwellian. It’s a way to 
increase comfort levels with this crazy idea.” —Raymond Pierrehumbert 

He is right that it was created to inrease comfort level, but it was done so 
with ironic intent. 


In 2007, I was organizing a meeting that took place at NASA-Ames. 
(Incidentally, that meeting is where this google group started. 
http://hdl.handle.net/2060/20070031204 ) 


There was some nervousness on the part of local NASA officials that the term 
geoengineering might raise red flags back in Washington. At the time, DOE was 
talking about carbon management which was a bureaucratic way to speak about 
the potential for CO2 emissions reduction. 


To avoid the use of the word geoengineering in the meeting name, I suggested 
that we create the term Solar Radiation Managment to use for the workshop. It 
was meant as parody of US-government-style bureaucratic jargon. It was meant as 
a joke and was intentionally obscurantist. We were laughing about it at the 
time and never dreamed that it would become standard jargon. 


The term Solar Radiation Management was meant to lower the profile of the 
meeting while parodying Washington jargon. It amuses me that it has become 
standard jargon. 


What started out as parody has moved on from its comedic roots. Comedy has 
become drama. 


Incidentally, lately I have been using the term solar geoengineering as my 
term of choice to refer to what SRM has come to denote. 


Best, 


Ken 
___ 
Ken Caldeira 

Carnegie Institution for Science 
Dept of Global Ecology 

260 Panama Street, Stanford, CA 94305 USA 

+1 650 704 7212 kcalde...@carnegiescience.edu 
http://dge.stanford.edu/labs/caldeiralab @kencaldeira 


Caldeira Lab is hiring postdoctoral researchers. 
http://dge.stanford.edu/labs/caldeiralab/Caldeira_employment.html 



Our YouTube 

Re: [geo] Re: Sooty ships may be geoengineering by accident - 06 February 2013 - New Scientist

2013-02-11 Thread Andrew Lockley
I wonder if there are any historic measurements of ocean albedo which would
allow the effect of these ships on ocean color  to be quantified

A
On Feb 9, 2013 10:32 AM, Russell Seitz russellse...@gmail.com wrote:

 I'm surprised  *New Scientist*  writer Jeff Hect failed to note my 2008
 account of inadvertant iron fertilization by smokestack fallout from ships,
 which appeared in *Science* online in response to a 2007  ocean
 fertilization piece by Eli Kintisch:
 CARBON SEQUESTRATIONShould Oceanographers Pump Iron?

- Eli Kintisch

 Science 30 November 2007: 1368-1370.

- Summary http://www.sciencemag.org/content/318/5855/1368.summary


1.

 http://www.sciencemag.org/content/318/5855/1368.summary/reply#content-block
Ocean Iron Fertilization
- Russell Seitz
Cambridge, MA, USA

E. Kintisch’s article, Should oceanographers pump iron? (News Focus,
30 November 2007, p. 1368) reminds us that controversy surrounds ocean
fertilization as a means of offsetting atmospheric carbon dioxide.
Biologists are skeptical, because despite the late John Martin’s famous
assertion, Give me a half tanker of iron and I'll give you an ice age (
*1*), many offshore areas sequester little carbon because their waters
are perennially deficient in nitrogen and phosphorus as well.

But Martin’s wish for a series of massive experiments may have been
realized anyway—before he was born. During the decades before oil became
the dominant marine transportation fuel, burning coal to raise steam at sea
spewed literally megatons a year of iron, nitrogen, and phosphorous into
nutrient-deficient surface waters.

Burning coal typically generates ash equal to ~10% of the fuel mass.
In modern combustion technology, electrostatic precipitators, bag houses,
and scrubbers remove over 95% of particulates. But no effort was made to
capture fly ash in early marine propulsion, and about three-fourths was
entrained and released with hot flue gases, the rest being incorporated
into stack ash, boiler slag, and scoria (*2*).

Owing to the low energy density of coal relative to oil, the
50,000,000 ton fleet of coal-burning ships operating in the early 20th
century (*3*) consumed many times its displacement in fuel annually.
The efficient but ill-fated Titanic consumed 1.5% of its 42,000 tonne
displacement daily, and lesser vessels typically combusted their
displacement in bunker coal in a matter of months. The scale of marine fuel
demand was such that Europe's 1913 export of 213 million tons of bunker
coal represented less than half the world total (*4*).

Coal ash typically contains from 2.5% to 8.5% iron (*5*). Much occurs
as pyrites (FeS2), and sulfate enrichment of ash particles by its
oxidation may enhance the bioavailability of fly ash iron. This suggests
that early 20th century European maritime activity alone annually released
~0.39 to 2.16 teragrams of iron at sea, with a high and frequently
replenished flux of aerosol iron flux along heavily traveled shipping 
 lanes.

But what of nitrogen and phosphorus? Before the Haber process
revolutionized nitrogen fixation, one of the most important fertilizers was
the ammonium sulfate inevitably co-produced with coal tar in gas works and
coke ovens. Since ship's coal typically contains 1 to 3% nitrogen, mostly
in polycyclics, the pyrolysis yield of water-soluble pyrroles, pyridine and
ammonium compounds from combustion at sea, may also have been in the
low-teragram range. Unlike metallurgical coal, the ash of that mined to
raise steam typically contained on the order of a kilogram of phosphorus
per ton.

This suggests that the co-deposition of nutrient phosphorus and
nitrogen with iron may have at least locally met the N-P-Fe synergy
criterion for enhancement of carbon fixation. Given that literal shiploads
of fly ash fell at sea for decades, understanding what exactly was
combusted along historic shipping lanes may shed light on the risks and
benefits of the more modest CO2 sequestration experiments of today,
and perhaps add the record of another historic aerosol (*6*) to the
list of those already known to impact climate model estimates of 20th
century and future radiative forcing.

Russell Seitz

Cambridge, MA 02138, USA.

References

1. J. H. Martin *et al*., *Nature* 371, 123 (1994).

2. *U.S. EPA Radiation Protection* (
http://www.EPA.gov/rpdweb00/tenorm/coalandcoalash.html).

3. *Lloyds Register* (
http://www.coltoncompany.com/shipping/statistics/wldflt.htm).

4. J. F. Bogardus, *Geographical Review* 20 (4), 642 (1930).

5. S. K. Gupta, T. F. Wall, R. A. Creelman, R. P. Gupta, *Fuel
Processing Technology* 56 (issues 1–2), 33 (1998).

6. R. Seitz, *Nature* 323, 116 (1986).
... 

[geo] Climate engineering and climate tipping-point scenarios

2013-02-11 Thread Bickel
Friends -
 
You may be interested in the following paper (*
http://www.springerlink.com/openurl.asp?genre=articleid=doi:10.1007/s10669-013-9435-8
* http://www.springer.com/alert/urltracking.do?id=Lf45461Mba44a1Sb02fb61).
 
*Title*: Climate engineering and climate tipping-point scenarios
 
*Abstract*: Many scientists fear that anthropogenic emissions of greenhouse 
gases have set the Earth on a path of significant, possibly catastrophic, 
changes. This includes the possibility of exceeding particular thresholds 
or tipping points in the climate system. In response, governments have 
proposed emissions reduction targets, but no agreement has been reached. 
These facts have led some scientists and economists to suggest research 
into climate engineering. In this paper, we analyze the potential value of 
one climate engineering technology family, known as solar radiation 
management (SRM) to manage the risk of differing tipping-point scenarios. 
We find that adding SRM to a policy of emissions controls may be able to 
help manage the risk of climate tipping points and that its potential 
benefits are large. However, the technology does not exist and important 
indirect costs (e.g., change in precipitation) are not well understood. 
Thus, we conclude the SRM merits a serious research effort to better 
understand its efficiency and safety. 
 
Best,
 
Eric Bickel
University of Texas at Austin
 
 

 

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[geo] Volcanos and climate change: Location, location, location

2013-02-11 Thread Rau, Greg
Interesting – no discussion of cooling effects of aerosol release? Short-lived 
relative to CO2? -Greg

Volcano Location: Greenhouse-Icehouse Key? Episodic Purging of 'Carbonate 
Capacitor' Drives Long-Term Climate Cycle

http://www.sciencedaily.com/releases/2013/02/130207115014.htm

Feb. 6, 2013 — A new Rice University-led study finds the real estate mantra 
location, location, location may also explain one of Earth's enduring climate 
mysteries. The study suggests that Earth's repeated flip-flopping between 
greenhouse and icehouse states over the past 500 million years may have been 
driven by the episodic flare-up of volcanoes at key locations where enormous 
amounts of carbon dioxide are poised for release into the atmosphere.



We found that Earth's continents serve as enormous 'carbonate capacitors,' 
said Rice's Cin-Ty Lee, the lead author of the study in this month's GeoSphere. 
Continents store massive amounts of carbon dioxide in sedimentary carbonates 
like limestone and marble, and it appears that these reservoirs are tapped from 
time to time by volcanoes, which release large amounts of carbon dioxide into 
the atmosphere.

Lee said as much as 44 percent of carbonates by weight is carbon dioxide. Under 
most circumstances that carbon stays locked inside Earth's rigid continental 
crust.

One process that can release carbon dioxide from these carbonates is 
interaction with magma, he said. But that rarely happens on Earth today 
because most volcanoes are located on island arcs, tectonic plate boundaries 
that don't contain continental crust.

Earth's climate continually cycles between greenhouse and icehouse states, 
which each last on timescales of 10 million to 100 million years. Icehouse 
states -- like the one Earth has been in for the past 50 million years -- are 
marked by ice at the poles and periods of glacial activity. By contrast, the 
warmer greenhouse states are marked by increased carbon dioxide in the 
atmosphere and by an ice-free surface, even at the poles. The last greenhouse 
period lasted about 50 million to 70 million years and spanned the late 
Cretaceous, when dinosaurs roamed, and the early Paleogene, when mammals began 
to diversify.

Lee and colleagues found that the planet's greenhouse-icehouse oscillations are 
a natural consequence of plate tectonics. The research showed that tectonic 
activity drives an episodic flare-up of volcanoes along continental arcs, 
particularly during periods when oceans are forming and continents are breaking 
apart. The continental arc volcanoes that arise during these periods are 
located on the edges of continents, and the magma that rises through the 
volcanoes releases enormous quantities of carbon dioxide as it passes through 
layers of carbonates in the continental crust.

Lee, professor of Earth science at Rice, led the four-year study, which was 
co-authored by three Rice faculty members and additional colleagues at the 
University of Tokyo, the University of British Columbia, the California 
Institute of Technology, Texas AM University and Pomona College.

Lee said the study breaks with conventional theories about greenhouse and 
icehouse periods.

The standard view of the greenhouse state is that you draw carbon dioxide from 
the deep Earth interior by a combination of more activity along the mid-ocean 
ridges -- where tectonic plates spread -- and massive breakouts of lava called 
'large igneous provinces,' Lee said. Though both of these would produce more 
carbon dioxide, it is not clear if these processes alone could sustain the 
atmospheric carbon dioxide that we find in the fossil record during past 
greenhouses.

Lee is a petrologist and geochemist whose research interests include the 
formation and evolution of continents as well as the connections between deep 
Earth and its oceans and atmosphere..

Lee said the conclusions in the study developed over several years, but the 
initial idea of the research dates to an informal chalkboard-only seminar at 
Rice in 2008. The talk was given by Rice oceanographer and study co-author 
Jerry Dickens, a paleoclimate expert; Lee and Rice geodynamicist Adrian 
Lenardic, another co-author, were in the audience.

Jerry was talking about seawater in the Cretaceous, and he mentioned that 93.5 
million years ago there was a mass extinction of deepwater organisms that 
coincided with a global marine anoxic event -- that is, the deep oceans became 
starved of oxygen, Lee said. Jerry was talking about the impact of anoxic 
conditions on the biogeochemical cycles of trace metals in the ocean, but I 
don't remember much else that he said that day because it had dawned on me that 
93 million years ago was a very interesting time for North America. There was a 
huge flare-up of volcanism along the western margin of North America, and the 
peak of all this activity was 93 million years ago.

I thought, 'Wow!' Lee recalled. I know coincidence doesn't mean causality, 
but it certainly got me