Re: [geo] Carbon budget/removal in NYTimes interactive

2017-09-08 Thread Christoph Voelker

Dear Robert,

I am a physicist, not an engineer, so I can't really judge how feasible 
it is to pump half a percent of the total volume of the ocean (this is 
what I got from my nutrient calculations, and I think they are correct) 
from a depth of 1000m or more up to the surface every year by tidal 
pumping, but I have to admit that I am sceptical.
I also cannot fully follow your argument about the concentration of 
nutrients, but I think your numbers are not correct. The average 
concentration of nitrate in the deep ocean is around 30 micromol/L (not 
3 ppm, which is neither correct in mol/mol, nor in volume/volume); and 
that of phosphate is not the same, but around 15 times less, i.e. around 
2 micromol/L.


Anyway, there is a much more fundamental problem with the approach that 
you are suggesting that is independent of its scale: When you pump up 
deep ocean water to get at the nutrients therein, you also pump up water 
that contains more dissolved inorganic carbon than surface ocean water. 
On average deep ocean water contains as much more dissolved carbon as 
you can fix with the nitrogen/phosphorus contained in it (again assuming 
a constant Redfield C:N:P ratio); this is because the higher carbon 
content in the deep ocean has been brought there mostly by the sinking 
and subsequent remineralisation of organic matter. Of course, with the 
nutrients that you bring up, most of that carbon will again be fixed in 
your algal biomass and can then be disposed of (whereever, maybe as 
biochar). But: That then leaves almost no room for using the algae to 
fix additional carbon from power plants, as you suggest.


So in effect what you do with that approach is: You pump up the carbon 
that has been stored in the deep ocean by the natural biological pump, 
which without anything else would increase CO2 in the surface. Then you 
fix this carbon in biomass and store it on land. In the end you have 
only shifted carbon from the deep ocean to the storage on land, and have 
achieved very little, if anything at all in terms of fixing the 
fossil-fuel-generated carbon. The only way out of this that I see is to 
use algae with an elevated C:N and C:P ratio compared to the Redfield 
ratio, because then you can fix more carbon than you bring up.


But then again, I would be sceptical about the possible scale that you 
mention, from my back-of-the-envelope calculation of the nutrient 
requirements from my last email.


Best regards, Christoph


On 08.09.17 01:15, Robert Tulip wrote:

Thanks Cristoph.
Deep Ocean Water, with volume about a billion cubic kilometres below 
the thermocline, has about three ppm nitrate and phosphate, about 3000 
cubic kilometres of each, as I understand the numbers. Tidal pumping 
arrays along the world's continental shelves could raise enough DOW to 
the surface, mimicking natural algae blooms, to fuel controlled algae 
production at the scale required for seven million square kilometres 
of factories.  Piping CO2 from power plants etc out to ocean algae 
farms could clean up all the polluted air of the world.

Robert Tulip



*From:* Christoph Voelker <christoph.voel...@awi.de>
*To:* geoengineering@googlegroups.com
*Sent:* Friday, 8 September 2017, 8:43
*Subject:* Re: [geo] Carbon budget/removal in NYTimes interactive

I must admit that I am getting skeptical when I hear numbers in that 
order of magnitude:
The total net primary production in the oceans presently is about 50 
Gt carbon, and 80% of that is converted back into inorganic carbon 
(and nutrients) by heterotrophs before it gets a chance to sink out 
from the sunlit upper layer of the ocean. The roughly 10 Gt carbon 
(some newer works even estimate just 6 Gt carbon) that sink out have 
to be balanced by the upward mixing of nutrients (and a little bit by 
atmospheric deposition of bioavailable nitrogen and phosphorus) in the 
Redfield ratio of about 106:16:1 of C:N:P.
So, if you want to remove 20 Gt carbon per year from the atmosphere, 
you'd have to increase the nutrient supply to the total surface ocean 
by a factor of three, maybe four. Maybe I am a bit too pessimistic 
here, because there are species like Sargassum which have a higher 
C:N:P ratio than the average phytoplankton, so you get somewhat more 
carbon per nitrogen/phosphorus. But even if it is just doubling, I 
can't imagine that you can sustain such a nutrient consumption by 
fertilizing from outside the ocean (especially since phosphorus is 
scarce already now), you'd have to tap into the inorganic nutrients 
stored in the deep ocean. How long can you do that?
If we assume that we harvest all the 20 Gt carbon in algae from these 
factories and do something durable with them (to minimize lossed 
through heterotrophy and problems with creating oxygen minimum zones), 
we effectively remove nitrogen/phosphorus from the ocean. How much is 
that per year?
Let us for simplicity assume Re

Re: [geo] Carbon budget/removal in NYTimes interactive

2017-09-07 Thread Christoph Voelker
I must admit that I am getting skeptical when I hear numbers in that 
order of magnitude:


The total net primary production in the oceans presently is about 50 Gt 
carbon, and 80% of that is converted back into inorganic carbon (and 
nutrients) by heterotrophs before it gets a chance to sink out from the 
sunlit upper layer of the ocean. The roughly 10 Gt carbon (some newer 
works even estimate just 6 Gt carbon) that sink out have to be balanced 
by the upward mixing of nutrients (and a little bit by atmospheric 
deposition of bioavailable nitrogen and phosphorus) in the Redfield 
ratio of about 106:16:1 of C:N:P.


So, if you want to remove 20 Gt carbon per year from the atmosphere, 
you'd have to increase the nutrient supply to the total surface ocean by 
a factor of three, maybe four. Maybe I am a bit too pessimistic here, 
because there are species like Sargassum which have a higher C:N:P ratio 
than the average phytoplankton, so you get somewhat more carbon per 
nitrogen/phosphorus. But even if it is just doubling, I can't imagine 
that you can sustain such a nutrient consumption by fertilizing from 
outside the ocean (especially since phosphorus is scarce already now), 
you'd have to tap into the inorganic nutrients stored in the deep ocean. 
How long can you do that?


If we assume that we harvest all the 20 Gt carbon in algae from these 
factories and do something durable with them (to minimize lossed through 
heterotrophy and problems with creating oxygen minimum zones), we 
effectively remove nitrogen/phosphorus from the ocean. How much is that 
per year?


Let us for simplicity assume Redfield ratios, I grant errors by a factor 
of two or so. 20 Gt carbon then corresponds to (20 
g/12(g/mol)/6.625(molC/molN))*1.0e15 or about 2.5e14 mol nitrogen. The 
ocean has a volume of 1.33e18 m^3, and the average concentration of 
available nitrogen (mostly nitrate) is 30 micromol/L or mmol/m^3 
(calculated from the world ocean atlas), most of that is in the deep 
ocean. This gives a total inventory of 4.0e16 mol nitrogen. 2.5e14 
mol/year is thus more than half of a percent of the total available 
nitrogen in the world oceans, which means you could try that for about 
150 years, then everything is gone At that pace, nitrogen fixers are 
unlikely to resupply the loss (nowaday, the residence time of nitrogen 
is roughly 5000 years), and they can do that only for nitrogen, not for 
phosphorus anyway. Letting technological problems aside (like: How do 
you move 2.5% of the total nitrogen in the world oceans evry year up to 
an area 2% of the ocean surface) I would call the whole idea - at least 
that the scale suggested - a prime example of an unsustainable process.


Best regards,

Christoph Voelker


On 07.09.17 23:37, 'Robert Tulip' via geoengineering wrote:
The assumption behind the NYT interactive model 
<https://www.nytimes.com/interactive/2017/08/29/opinion/climate-change-carbon-budget.html?action=click=Homepage=story-heading=opinion-c-col-right-region=opinion-c-col-right-region=opinion-c-col-right-region> 
that the upper bound for carbon removal is 12 GT CO2 by 2080 is too 
slow and small.  We should think five times as much and five times as 
fast.
Immediate aggressive investment to build industrial algae factories at 
sea could remove twenty gigatons of carbon (50 GT CO2) from the air 
per year by 2030, using 2% of the ocean surface, funded by use of the 
produced algae.
That would stabilise the climate and enable no change in emission 
trajectories, a policy result that would satisfy both the needs of the 
climate and the traditional economy.

Robert Tulip



*From:* Eric Durbrow <durb...@gmail.com>
*To:* geoengineering <geoengineering@googlegroups.com>
*Sent:* Thursday, 7 September 2017, 3:13
*Subject:* [geo] Carbon budget/removal in NYTimes interactive


FYI There is a slick interactive graphic at the NYTimes that lets 
people see if they can meet the world’s carbon budget restriction but 
a combination of reduced emissions AND achieving Carbon Removal.


At

https://www.nytimes.com/interactive/2017/08/29/opinion/climate-change-carbon-budget.html?action=click=Homepage=story-heading=opinion-c-col-right-region=opinion-c-col-right-region=opinion-c-col-right-region

I failed after clicking on Reduce in all geographic areas and Achieve 
in Carbon Removal.





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Re: [geo] Re: Researchers propose 'cocktail geo-engineering' to save climate

2017-07-31 Thread Christoph Voelker

Hi all,

this engineering approach of separately switching cocktail components on 
and off is probably not so simple: attribution and detection of climate 
change are notoriously difficult (which has been exploited a lot by 
climate change deniers), with the main problem that both require 
knowledge of the internal climate variability on the time scales 
considered. A good introduction to the subject is the chapter 9.1.2 in 
the 2007 IPCC report:


https://www.ipcc.ch/publications_and_data/ar4/wg1/en/ch9s9-1-2.html

Cheers, Christoph


On 31.07.17 16:23, Stephen Salter wrote:


Hi All

Florian is worried about separating the effects of different 
components of a mixture of cocktails.  It should be possible to do 
this for techniques with a high frequency response by turning them on 
and off with different random sequences and correlating the results at 
different observing stations.


Stephen

On 31/07/2017 12:58, Andrew Lockley wrote:
As long as the effects were largely exclusive, cocktail 
geoengineering could greatly reduce impacts from side effects, as 
they may have non-linear impacts.


For example, techniques A have two different side effects, each 
with damages proportional to the square of the dose. Both are equally 
damaging. A combination of the two therefore leads to lower side 
effects that each alone.


A

On 31 Jul 2017 12:53, "Florian Rabitz" <florian.rab...@ktu.lt 
<mailto:florian.rab...@ktu.lt>> wrote:


I guess a major problem with a cocktail approach would be the
amplification of uncertainties. How would we be able to attribute
the outcomes to either technique? An increase in global
precipitation might result either from the effect of CCT being
larger-than-expected
or from the effect of aerosols being smaller-than-expected (vice
versa for decreasing global precipitation). Seems like this would
require
a lot of fine-tuning. Also, in my view, the governance
implications don't look pretty.

Best,
Florian

On Monday, July 31, 2017 at 1:26:58 AM UTC+3, Andrew Lockley wrote:



http://www.tribuneindia.com/mobi/news/science-technology/researchers-propose-cocktail-geo-engineering-to-save-climate/443998.html

<http://www.tribuneindia.com/mobi/news/science-technology/researchers-propose-cocktail-geo-engineering-to-save-climate/443998.html>

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Re: [geo] Negative Emissions: Arrows in the Quiver, Life Preserver, and/or Moral Hazard?

2016-11-15 Thread Christoph Voelker
Hi All,

I am astonished at the lack of courtesy, also in a scientific manner,
here. Before suggesting that IPCC has made a 'blunder', or that someone
who defends the AR5 report uses 'weasel words' it would be helpful going
back to the sources. The figure in the AR5 is taken from Cao and
Caldeira (2010) and shows the results of idealized experiments with a
global carbon cycle and climate model, where no such thing has been
committed as to 'ignore the warming effect of accumulated CO2'. The
model solves for the carbon balance, so there is no way how the
accumulated carbon (and hence its warimg effect) could have vanished.
One might criticise the model for being overly simplistic, but a simple
'blunder' it certainly isn't.

Best regards, Christoph

Am 15/11/16 um 10:47 schrieb Stephen Salter:
>
> Hi All
>
> "Approximately" is the weasel word. 
>
> Stephen
>
>
> On 15/11/2016 08:39, Olivier Boucher wrote:
>>
>>
>> Dear John,
>> there is no blunder here. This is an idealized scenario. If CO2
>> emissions go to zero abruptly (red curve), then the committed warming
>> (ie the warming in the pipeline because the ocean hasn't equilibrated
>> yet) is approximately compensated by the decrease in CO2 emissions
>> induced by zero emissions (because natural sinks to vegetation and
>> ocean keep working).
>> Regards,
>> Olivier
>>> *Blunder 2*. IPCC has ignored the warming effect of accumulated
>>> CO2.  They say that global temperature rise will be halted when net
>>> CO2 emissions have fallen to zero, ignoring the effect of
>>> accumulated CO2 and other forcing agents in the atmosphere.
>>
>> -- 
>> 
>> Our opinion piece is now published in PNAS
>> <http://www.pnas.org/content/113/27/7287>
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-- 
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Am Handelshafen 12
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e: christoph.voel...@awi.de
t: +49 471 4831 1848

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Re: [geo] Re: Real Climate Change Solutions Too Cheap To Meter - Russ George

2015-05-30 Thread Christoph Voelker
Dear Baskar,

where did you get the numbers from? They don't agree with common
estimates of biomass in the ocean (which may be wrong, but then please
enlighten me):

Taking your number of a decline of 10 billion tons of phytoplankton
(btw, are you talking about phytoplankton carbon or phytoplankton
biomass here? The difference is a factor of roughly 2) earnestly, I
would arrive at the conclusion that now the biomass of phytoplankton is
probably negative: the total biomass is commonly assessed to be around 3
Pg of carbon (see e.g. the overview figure on the global carbon cycle in
the IPCC assessment report 5).
I don't have the time right now to check the sources for that, but I
believe it not to be too far off. So, depending on whether you mean
carbon or (wet) biomass, that leaves us now with -2 or -7 Pg C biomass
in the ocean. Miraculous, isn't it? Or do you think that this is the
biomass after the reduction that you claim? Then biomass should have
been 8 (or 13 if your 10 is carbon) PgC before the change; I think such
a change would have been noticed before.

Btw: in your comparison with the anthropogenic carbon emissions you mix
up two very different things: The emissions are per year, while the
decline in stocks are totals. So even if I assume all your numbers are
true and in carbon units, the total decline in biomass is only about 2
years worth of anthropogenic emissions. So, no, I don't think that
biomass restoration is the point here. If there is a point then it is an
increase of anual carbon fluxes into the deep ocean, i.e. the biological
pump. And that is estimated at around 10 PgC/year; a realistic change
that may be attainable (independent of if one may want that) may be
around 1 PgC/year, so ocean fertilization can probably be not more than
a 10% contribution to the solution.

Cheers, Christoph


On 5/21/15 1:29 PM, M V Bhaskar wrote:
 The only thing that appears to have declined substantially in the 20th
 century is the biomass in Oceans.

 Fish declined -
 http://www.bbc.com/future/story/20120920-are-we-running-out-of-fish
 Whales and Krill declined -
 http://www.fbbva.es/TLFU/dat/02SMETACEKSEPARATA.pdf
 Phytoplankton declined -
 http://www.scientificamerican.com/article/phytoplankton-population/

 The decline is about 8 to 14 Billion tons of Fish, 100 million tons of
 Whales, 500 million tons of Krill, 10 Billion tons of Phytoplankton. 

 All this adds upto a much higher figure than the 10 Billion tons of
 Anthropogenic Carbon emissions.
 Mere restoration of the biomass in the oceans appears to be adequate
 to deal with all the carbon emissions.

 Regards

 Bhaskar


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Re: [geo] Energy Planning and Decarbonization Technology | The Energy Collective

2015-01-25 Thread Christoph Voelker
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Re: [geo] FW: emitting or capturing CO2

2015-01-03 Thread Christoph Voelker
Dear all,

I have no real expertise on that, but I'd like to add a word of caution:
Have you ever added some fine-grained powder to a liquid oversaturated
with a gas? You get a lot of bubbles quickly. The result could well be
that the grains trigger a spontaneous ebullition of the CO2 before it
has time to react with the olivine. That would be catastrophic, so even
if the chance is very low I'd rather be cautious.

Best regards, Christoph

On 1/3/15 2:22 PM, Schuiling, R.D. (Olaf) wrote:

 Dear All,

 Andrew suggested that I should share this discussion  with the group
 on whether to emit the CO2 from that acid lake in Spain to the
 atmosphere, or capture it as  bicarbonate by adding fine-grained
 olivine to the lake, while at the same time reduce its acidity, Olaf
 Schuiling

  

 *From:*Schuiling, R.D. (Olaf)
 *Sent:* vrijdag 2 januari 2015 12:23
 *To:* andrew.lock...@gmail.com
 *Subject:* emitting or capturing CO2

  

 Dear Andrew

 Just a few additional data on olivine use instead of degassing. I have
 no money to carry out full-scale field experiments, so I am limited to
 the following.

 1.   There is an olivine mine (the PASEK mine) in NW Spain, close
 to the sea, with a harbor for small (up to 8.000 tons) freighters.
 They have no clients for their finest fraction, which would be
 excellent for the acid lake, so they have to store it back in their
 own mine (slight negative value!)

 2.   The acid lake is not easy to reach, but the river
 Guadalquivir (navigable to Sevilla) makes it possible to bring that
 olivine cheaply by ship not too far from the acid lake.

 3.   I have done experiments with a well-known table water (Spa
 red), bottled under CO2 pressure. Its starting pH was 3.9. After
 passing through a tube filled with medium sized olivine grains (a
 passage that took somewhere between 15 and 30 minutes), the pH had
 risen to 8.2!

 4.   When the lake is neutralized this way, the reaction will also
 release some silica in solution. This will attract siliceous algae
 (diatoms), a favorite fish food, so the lake may become a favorite
 spot for fishing after treatment, and it will also have become
 suitable for irrigation in dry summers.

 5.   I attach a paper describing the  experiment of converting a
 CO2 rich table water into a healthy magnesium bicarbonate mineral
 water. (Schuiling, R.D., Hogesteger, A.W. and Praagman, E.(2011) From
 Spa to Corinth, a road to CO2 sequestration)

  

 I think we should use any way to reduce CO2 emissions, so capturing
 CO2 instead of freely emitting it should normally be preferred, Olaf
 Schuiling

  

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