On the other hand acidification = less marine calcification = less CO2 flux to 
air from calcification. - Greg

http://www.newscientist.com/article/dn24098-acidifying-oceans-will-heat-the-planet-more.html


Acidifying oceans will heat the planet more

18:00 25 August 2013 by Michael Marshall
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Acidifying oceans could be bad news (Image: ESA)
WHAT goes around comes around. Our greenhouse gas emissions don't just warm the 
planet, they also acidify the oceans. Now it turns out that the change in ocean 
chemistry they cause will feed back into the climate, further driving up 
temperatures.

Ocean acidification poses a threat to many marine organisms such as corals – 
the shells of some marine snails are already dissolving. Until now it seemed 
like this was strictly a problem for marine organisms and the people who depend 
on them: 'climate scientists consider the carbon dioxide that is absorbed by 
the ocean to be stored and unable to affect the climate.

But research now suggests that the acidification it causes will rebound on the 
entire planet, by acting on tiny marine plants called phytoplankton. These 
produce a chemical called dimethyl sulphide (DMS) that drifts up into the air 
and reflects sunlight back into space, cooling the planet. DMS also makes 
clouds brighter, with the same effect.

Katharina Six of the Max Planck Institute for Meteorology in Hamburg, Germany, 
and her team gathered experimental data showing that phytoplankton produce less 
DMS as seawater becomes less alkaline. After feeding these figures into climate 
models, they estimate that 18 per cent less DMS will be released from the 
oceans in 2100, compared with preindustrial times.

If the concentration of CO2 in the atmosphere doubles – which is likely to 
happen later this century – temperatures are expected to rise between 2 and 4.5 
°C. Ocean acidification will add between 0.23 and 0.48 °C to that figure, Six 
estimates. "We were surprised that the effect was so large," she says. "It 
certainly speeds up the warming."

The finding adds to a roster of unexpected positive feedback effects that could 
amplify global warming.

These effects could make a big difference, says Paul Pearson of Cardiff 
University in the UK. But he adds that Six's estimate of temperature change is 
based on processes that are poorly understood, like cloud physics. "These sorts 
of changes are possible, but very difficult to predict with certainty."

Journal reference: Nature Climate Change, DOI: 10.1038/NCLIMATE1981

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