Re: [biofuels-biz] Fwd: Biorefinery projects take first steps

2003-11-07 Thread David Teal

Quite impressive by the American funding agencies.  One reservation though:

The project's goal is to develop catalyst
systems and a continuous process to produce isosorbide from sorbitol
and to support a scale-up of the process, purification and recovery,
and pilot plant operation. 

So are we heading for huge factories with feedstock being hauled large
distancesagain?

Another intersting snippet I came across recently:

The oil to be esterified must be extremely dry and low in free fatty acids,
peroxides and any other material that may react with sodium methoxide. A few
minutes after the catalyst is added, the oil acquires a reddish brown color
due to the formation of a complex between the sodium and the glycerides.
This complex is thought to be the true catalyst.

David T.


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Re: [biofuels-biz] Fwd: Biorefinery projects take first steps

2003-11-07 Thread Keith Addison

Hello David

Quite impressive by the American funding agencies.  One reservation though:

 The project's goal is to develop catalyst
 systems and a continuous process to produce isosorbide from sorbitol
 and to support a scale-up of the process, purification and recovery,
 and pilot plant operation. 

So are we heading for huge factories with feedstock being hauled large
distancesagain?

They certainly are, we, hopefully, are not. Feedstock and product 
both. I don't think replacing Big Oil with Big Biofuels would 
necessarily be much of an improvement, if any, and maybe even worse. 
It'd be many or all of the same players, with all the same precepts 
that we've come to know and love, along with Jolly Nice Folks like 
Archer Daniels Midland, Dow-Cargill, Monsanto, et al. But at least 
there'd be less greenhouse gas emissions? Maybe not even that - very 
large amounts of land would be turned over to intensive agribusiness 
monocropping of biofuels crops, with huge fossil-fuels inputs (and 
the usual massive externalizations). As it is, agribusiness is a 
very major producer of CO2. (So they'd help use up the remaining oil 
even faster.) At least the petroleum resources are underground and 
don't take up that much surface area, but this stuff would blight the 
land. Of course their thinking and planning would be to provide 
enough biofuels - enough to replace dino-d use with growth 
calculated at current rates, so business-as-usual as far as highly 
inequitable and unsustainable OECD energy use is concerned. That's 
just how the US DOE does calculate it. Quote from a speech by a 
biodiesel industry figure (Tim Haig):

... in the year 2001, the European Union produced and used 300 
million gallons of biodiesel. In the United States last year [2001], 
they produced and used 35 million gallons. The projections are as 
follows: by the year 2016, the US expects to produce in excess of 800 
million gallons. The Department of Energy has gone on the record to 
say they are in support of six billion gallons by the year 2020. That 
would be 15.5% of the diesel consumed in North America, and that is 
indeed possible to do.

This won't get us very far, it certainly won't get us a sustainable 
energy future. That, as I often say here and at the Biofuel list, and 
so do quite a few others, means greatly reduced fuel use, greatly 
increased fuel efficiency, and, most important, decentralization of 
supply. That's not what we're going to be getting from the USDA or 
the US DOE or their ilk.

Another intersting snippet I came across recently:

The oil to be esterified must be extremely dry and low in free fatty acids,
peroxides and any other material that may react with sodium methoxide. A few
minutes after the catalyst is added, the oil acquires a reddish brown color
due to the formation of a complex between the sodium and the glycerides.
This complex is thought to be the true catalyst.

David T.

That is interesting. But many other catalysts can be used apart from 
sodium methoxide. Would they all form such a complex?

regards

Keith


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Re: [biofuel] home heating with biodiesel?

2003-11-07 Thread rajesh sk

Dear Mark,
 
Biodiesel can be used in place of furnace oil but it needs burner 
modification.If u can modify burner your furnace efficiency can be improved.
 
Rajesh 
IIT Delhi

Mark Finewood [EMAIL PROTECTED] wrote:
Does anyone have experience using biodiesel for home heat in place 
of fuel oil in their furnace?

Let me know,

Regards,
Mark




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Re: [biofuel] home heating with biodiesel?

2003-11-07 Thread Dan Maker

Mark Finewood said:
 
 Does anyone have experience using biodiesel for home heat in place 
 of fuel oil in their furnace?

Take a quick look in the archives for October or September, there is an
article in Home Power magazine (I think that's it) by a couple that
converted their fuel oil furnace to biodiesel.  They detail the problems
they had, and how they overcame them.

There is a link given to a download location for the article.

Good luck,
Dan
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Fiber Artist - Genealogist - Kilt Maker - Linux Geek - Piper - Woodworker
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Re: [biofuel] RE: daihatsu - was Digest Number 1832

2003-11-07 Thread Keith Addison

Hi Dan

Keith Addison said:
 
  Also the wvo that i have acquired is mainly ground nut oil 
rather than rape.
 
  It shouldn't be a problem. It's not a drying oil, so it won't
  polymerise.

I'm probably wrong, but you may wish to double check and make sure that
the nut oil you are getting is not a drying oil.  In the work I've done,
finishing wood, nut oils are usually drying to one degree or another.
As this experience is from wood working and not biofuels, it may not
apply.

Make sure the oil you are getting isn't a drying oil.

Indeed. But groundnuts/peanuts aren't really nuts, nor do they come 
from trees. It's an annual legume, in other words a vegetable, and 
the nuts are a sort of underground bean.

Peanut oil has a lower Iodine Value than rapeseed oil, and it's quite 
a lot lower than soybean oil. Peanut oil - 93, Rapeseed oil - 98, 
Soybean oil - 130, Tung oil (drying) - 168, Linseed oil (drying) - 
178, Sardine oil (drying) - 185.

Best

Keith


Dan


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Re: [biofuel] home heating with biodiesel?

2003-11-07 Thread Appal Energy

Article on a residential oil-fired furnace running biodiesel from Homepower
Magazine, October/November, 2003, page 40-44
http://www.homepower.com/files/97p1-47.pdf

Biodiesel Blends in Space Heating Equipment
NREL-BNL68852
http://www.homepower.com/files/Biodiesel_Space_Heating.pdf

- Original Message - 
From: Mark Finewood [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, November 06, 2003 12:40 AM
Subject: [biofuel] home heating with biodiesel?


 Does anyone have experience using biodiesel for home heat in place
 of fuel oil in their furnace?

 Let me know,

 Regards,
 Mark




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Re: [biofuel] RE: daihatsu - was Digest Number 1832

2003-11-07 Thread Dan Maker

Keith Addison said:
 
 Indeed. But groundnuts/peanuts aren't really nuts, nor do they come 
 from trees. It's an annual legume, in other words a vegetable, and 
 the nuts are a sort of underground bean.

True, I read ground nut, as in chopped and processed to extract the oil.
The peanut is a legume, not a nut and does not produce a drying oil.
My miss understanding.  I'm sorry.

Dan
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Re: [biofuel] RE: daihatsu - was Digest Number 1832

2003-11-07 Thread Keith Addison

Keith Addison said:
 
  Indeed. But groundnuts/peanuts aren't really nuts, nor do they come
  from trees. It's an annual legume, in other words a vegetable, and
  the nuts are a sort of underground bean.

True, I read ground nut, as in chopped and processed to extract the oil.
The peanut is a legume, not a nut and does not produce a drying oil.
My miss understanding.  I'm sorry.

Dan
--
Jack of all trades, master of none.
Fiber Artist - Genealogist - Kilt Maker - Linux Geek - Piper - Woodworker
http://www.xmission.com/~redbeard

Well Dan, you could be right. I guess Dave will confirm what he meant.

Best

Keith


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[biofuel] glycerin use

2003-11-07 Thread Mccall Tom WP US

After one removed the water could the glycerin be mixed with SVO
and burned in a Diesel?
 
Tom

 



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Re: [biofuel] glycerin use

2003-11-07 Thread Appal Energy

No.

First, you would need to find to incorporate an emuslifying agent to get the
glycerol to mix with the oil.

Second, you would also be adding a water fraction unless you distilled it
out first. (The presumption is being made that you are speaking of
glycerol/ffa separation as discussed at
http://journeytoforever.org/biodiesel_glycsep.html )

Third, you would be increasing the ratio of glycerol to fatty acids by
adding it to the already-glycerol-bearing glycerides (SVO).

Aside from that, one has to ask why would a person extract glycerol from
glycerides (make biodiesel) and then add a fluid that is as thick as
molasses back to a fluid that is already as viscous a fluid as SVO or WVO?

Todd Swearingen

- Original Message - 
From: Mccall Tom WP US [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, November 07, 2003 10:36 AM
Subject: [biofuel] glycerin use


 After one removed the water could the glycerin be mixed with SVO
 and burned in a Diesel?

 Tom





 [Non-text portions of this message have been removed]




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[biofuel] Producing cellulosic ethanol

2003-11-07 Thread MH

 An article below QA with Iogen... but first something -- 

ABOUT  The Environmental and Energy Study Institute (EESI)
is a non-profit organization dedicated to promoting
environmentally sustainable societies 
EESI was founded in 1984 by a bipartisan group of
Members of Congress concerned about energy and
environmental issues.  http://www.eesi.org/about/about.htm 

- ECO Newsletter - 
Published monthly, this newsletter
provides an open forum for discussion of
Ethanol, Climate change, and Oil reduction issues. 
http://www.eesi.org 


 APRIL 2003 
 Q  A with Iogenâs Jeff Passmore regarding cellulosic ethanol 
 http://www.eesi.org/publications/Newsletters/ECO/eco%2019.htm 

 ECO recently interviewed Jeff Passmore, Executive Vice President of Iogen 
Corporation. 
 Iogen [http://www.iogen.ca] is a privately owned Canadian business that has 
recently
 announced that its demonstration facility in Ottawa, Canada is successfully 
processing
 30 tons of wheat straw per week into fermentable sugar and is on track to 
reach annual
 production of 320,000 liters (roughly 85,000 gallons) of cellulosic ethanol. 

 Potential feedstocks for producing cellulosic ethanol include a broad range of
 agricultural residues and forest wastes such as sugar cane bagasse, rice hulls 
and
 forest thinnings, municipal wastes such as waste paper, yard waste, 
construction debris,
 and industrial wastes such as pulp/paper and sludge.  According to research 
done at the
 Argonne National Laboratory, cellulosic ethanol also greatly reduces the 
emission of
 greenhouse gases when compared to gasoline. 

 [SEE:  Briefing Summary - Elements of a BioBased Economy: BioBased Energy, 
Fuels, and Products
  May 20, 2003 
http://www.eesi.org/briefings/2003/EnergyandClimate/5.20.03%20Biomass/5.20.03%20Biomass.htm]
  

Why does Iogen think the development of a cellulose market is 
important/desirable? 

 Iogenâs goals include meeting the challenge of reducing North Americaâs 
greenhouse gas
 emissions, creating a domestic fuel supply, increasing market opportunities 
for farmers,
 and creating local jobs. 

 Our technology will allow for major impacts on the CO2 put back into the 
atmosphere in
 the transportation sector.  The demonstration facility in Ottawa, Canada has 
been
 designed and engineered to process up to 40 tons of feedstock per day.  
Currently, the
 facility is successfully processing 30 tons of wheat straw per week into 
fermentable
 sugar ö which would produce 320,000 liters of ethanol annually.  No one has 
ever used
 modern enzyme technology to successfully convert cellulose material (a polymer 
made up
 of repeating units of glucose, a simple sugar) such as straw into fermentable 
sugar on
 this scale before.  The demo plant construction began in 1999 and was 
commissioned in
 April of 2002. 

What technology is Iogen using in its demonstration facility?  

 Iogen Corporation is an industrial manufacturer of enzyme products for the 
pulp and paper,
 textiles and animal feed industries, and is a developer of technology to make 
clean fuels
 from plant fiber.  Since it's founding in the early 1970's, Iogen has been 
focused on the
 processing of natural fiber, and has made a substantial commitment to 
technology in the
 field.  The company's effort has resulted in a range of enzyme products used 
to improve
 the way fiber is processed. 

 EcoEthanolú is the same as conventional (or grain derived) ethanol; the 
difference lies in
 how it is produced.  Our focus for feedstocks has been wheat straw and corn 
stover ö but any
 cereal straw is useable - as long as the yields make it economical and as long 
as the
 cellulose content is there.  To be useable in our process, a feedstock must 
have roughly
 60 percent carbohydrate content, and be available in very large quantities 
such as
 750,000 tons per year within an 80-mile radius.  There would also be the 
question of
 harvesting the material. 

 In laymen's terms what happens is that the feedstock, frequently straw, is 
crushed into
 a powder.  It is then put through a patented pretreatment process to open up 
the fibers. 
 Enzymes (a natural catalyst used in many industries) are added to the 
pretreated feedstock. 
 The enzymes break down the cellulose content into sugar.  That sugar is then 
fermented and
 distilled into ethanol. 

 In our process we use the lignin in the straw and stover.  It can be used to 
produce
 electricity and becomes an integral part of the massive greenhouse gas 
reductions we see
 with ethanol from cellulose.  On average, one dry metric ton of wheat straw 
will produce
 250kg of combustible materials.  Of this, approximately 200kg is lignin, all 
of which
 can be burned to create electricity.  Lignin has around 80 percent of the heat 
content of
 typical thermal coal, or approximately 20,000 BTU/kg.  Depending on the 
feedstock used
 and its growing conditions, there can be a surplus of lignin that 

Re: [biofuel] Microturbines vs fuel cells

2003-11-07 Thread Alan Petrillo

Greg and April wrote:
 Possibly, it was what I was told by a friend sometime ago, that was taking a 
 course in school, and one of the problems that they were working on, of 
 course it could of been something else, it was 10 - 15 yrs ago. 

Noted.

 As for the aircraft, don't forget that with warm air, it is a lower density 
 and they would need more thrust just to maintain altitude, that in it's self, 
 would cause higher fuel consumption.

Ah, yes, Density Altitude.

It isn't so much that they need more thrust to maintain altitude, it's 
really that they need more _throttle_ to maintain altitude. 
Particularly with piston engines, but also with turbines.  This is 
because the air, which is their working fluid, is less dense, so they 
become less efficient.

In the case of helicopters, when you have less dense air you have to 
pull more pitch on the rotor blades so you can move a greater volume of 
the less dense air in order to creat enough lift to hold the thing up. 
This creates more drag on the rotor system, and results in a higher fuel 
burn.

But the really big worry when operating in hot weather was overtemping 
the engine.  Part of our preflight was to check the density altitude and 
ambient temperature to make sure we could stay inside the operating 
envelope of the engine.

There was a point at which we couldn't get full rated power out of the 
engine without exceeding its maximum temperature.

It was particularly important to make sure the weather wasn't too hot to 
_start_ the engine.  There were some days we couldn't get it started on 
batteries, and we'd have to get a GPU start, which was a real PITA.  I'm 
sure this is part of the reason that the OH-58A/C is no longer in the 
inventory.

And even with jets, at high altitude there is a certain throttle setting 
that you don't go _below_, because if you do then the engines will 
flame-out.  The explanation I got of this was that you needed to 
maintain a certain compression in the burner section of the engine or it 
wouldn't have enough oxygen to maintain combustion.

The flip side of that is that if you run the throttles too high at high 
altitudes you risk overtemping the engines.  Generally the way pilots 
fine tune their engines at altitude is to match up the turbine inlet 
temperatures.  Go too high, and the engines literally run out of gas.

If I understand it correctly, the service ceiling of the engine is the 
point at which the maximum throttle setting to avoid overtemping the 
engine is the same as the minimum throttle setting to avoid flaming out.

I could have that wrong, particularly as I'm writing this through an 
antihistamine/decongestant haze.  (Flu sucks)


AP


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[biofuel] 350 Liter Reactor w/agitator

2003-11-07 Thread Appal Energy

http://cgi.ebay.com/ws/eBayISAPI.dll?ViewItemitem=2571419677

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[biofuel] Re: [vegoil-diesel] Re: Pumps on eBay

2003-11-07 Thread Alan Petrillo

Dana wrote:
 They look more like vacuum pumps to me.

Could be.  I'm used to general aviation vacuum pumps, so I'm not 
familiar with what kind of pumps The Big Boys use.

Even so, they might be useful for some of the guys building biodiesel 
processors if they can figure out how to power them.


AP



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[biofuel] Re: [vegoil-diesel] Chemical jug fitting (long)

2003-11-07 Thread Alan Petrillo

Well, leave it to me to reinvent the wheel.

I found out what I have built is a dual flow rotating fitting.

Now you can buy dual flow rotating fittings, but they're expensive.  You 
can probably get them used from an agricultural junkyard, but I wouldn't 
bet on it.

The good part about doing it yourself is cost.  You can either buy 
something pretty for $150, or build something functional but ugly for 
around $30.


AP

Alan Petrillo wrote:
 Change 1:
 The 3/8 fuel line has too large an outer diameter to use as a lift tube 
 in the fitting built with 1/2 parts.  It causes too much restriction on 
 the return side.  I changed the inside hose barb to 5/16, and used 5/16 
 fuel line instead.  This eliminated the restriction on the return side, 
 but we'll see what happens on the supply side.
 
 An option would be to rebuild the fitting using 3/4 parts instead of 
 1/2, but that would make a fitting that's already big and clunky even 
 clunkier.  Depending on what happens fuel pressurewise that's what I 
 might have to do.
 
 An issue I completely forgot about was venting.  Originally I was going 
 to install vents on the jugs, but I changed my mind, and drilled a 1/8 
 hole in the cap of the tap fitting for venting.  Considering the 
 potential problems with polymerization I thought it'd be a better idea 
 to leave the jugs of WVO sealed until it was time to put the tap on them.
 
 Alan Petrillo wrote:
 
Here's a fitting I built to enable me to use chemical jugs as fuel 
tanks.  They're only about 5 gallons, but they're easy to get, and cheap 
or free.

Since diesels need both a fuel supply and a return set up as an open 
loop to function properly, the idea is to build a fitting which will 
allow this to take place without major modifications to the chemical jugs.

This can be built with either galvanized or brass parts, but I chose 
brass.  Whatever you make it from it's going to be ugly, but it'll work.

These jugs usually have a 3/4 NPT fitting in the middle of the cap, and 
that makes building this fitting easy.

All of the parts are available at either Home Depot or Lowes.

The parts are:

One cap from a chemical jug

One 3/4 to 1/2 pipe bushing

Two 1/2 close pipe nipples (Hex pipe nipples will work, but will make 
the fitting longer)

One 1/2 pipe union (If you can find a proper pipe swivel then use it 
instead, but if you can find a proper pipe swivel you're doing better 
than I am.  If you do find a proper pipe swivel then please tell me 
where you got it so that I can go get one.)

One 1/2 T

One 1/2 male to 1/2 female elbow

One 1/2 to 1/4 bushing

One 1/2 NPT to 3/8 hose barb

One 1/4 NPT to 3/8 hose barb

One 1/4 NPT to 5/16 hose barb (Expect this one to be hard to find.)

Some 3/8 diesel fuel line

Some teflon tape which is approved for petroleum pipe.

The tools you will need are a sharp knife, a couple of spanner wrenches 
and a 1/4 NPT inside tap.  A bench vice will help but isn't 100.0% 
necessary.

The fitting is built in two parts.  The first is a body that attaches to 
the cap, and the second is a holder for a tube to pass through the main 
body.  The idea is to draw fuel up through the middle of the fitting 
while returning fuel through the side.

Use teflon tape to seal all of the pipe joints.

First, screw the 3/4-1/2 bushing into the cap without using teflon 
tape, pierce the middle of the cap if it isn't already, and cut it out 
until the plastic of the cap is even with the inside diameter of the 
bushing.  Then take the cap off of the bushing and put it aside.  We'll 
get back to it later.

Screw the 3/4-1/2 onto one of the 1/2 close pipe nipples.

Screw the pipe union onto the pipe nipple.

Screw the other pipe nipple into the other end of the pipe union.

Screw one end of the T onto that pipe nipple.

Into the middle of the T screw the 1/2-1/4 bushing.

Into the bushing screw the 1/4 NPT - 5/16 hose barb.

Using teflon tape this time, screw the jug cap back onto the bottom.

This completes the assembly of the main body of the fitting.

Now, take the elbow and use the 1/4 NPT inside tap to thread the inside 
of the male end.

Into the now threaded inside of the male end screw the 1/4 NPT - 3/8 
hose barb.

Into the female end of the elbow screw the 1/2 - 3/8 hose barb.

Now take one of the chemical jugs you're going to be using, put the cap 
with the main fitting on it onto the jug, and then take the diesel fuel 
line, run it through the middle of the fitting down to the bottom of the 
jug, and mark the depth on the fuel line.  Pull the line back out and 
cut it off at the mark.

Push the fuel line onto the hose barb on the _male_ end of the elbow.

Now run the line back through the fitting and screw the elbow onto the 
top of the main fitting, stopping so that the two outside hose barbs are 
lined up together.

Trim the end of the fuel line so that it is just above the bottom of the 
jug.

That's it, you're done.  You now have a fitting that will allow you to 
use chemical 

Re: Bypass Filtration was Re: [biofuel] Engine oil choices

2003-11-07 Thread craigreece

Aidan,

My pleasure. I think it was a fruitful discussion.

Craig

A Wilkins wrote:

  Craig,

 Thank you for hitting the head on the nail.  I apologize for
 mixing up a deep clean bypass filter with a full flow filter which
 has gone into bypass mode.


 Aidan

   - Original Message -
   From: craigreece
   To: biofuel@yahoogroups.com
   Sent: Wednesday, November 05, 2003 9:56 PM
   Subject: Re: Bypass Filtration was Re: [biofuel] Engine oil
 choices


   I think I can clear up the confusion. The filter that the CAT
 mechanic
   may be talking about is probably a Racor LFS or Oberg type filter
 that
   is cleanable, and normally full flow, but if blocked, goes into
 bypass,
   as Aidan describes.

snip



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