RE: [Biofuel] Energy content

2005-08-19 Thread Bede
coconuts one of the best yielding and easiest to grow..
, although its worth more per liter for cosmetics (shampoo soap etc)
and cooking oil.
how ever the whole dehusking bit is some what tiresome...

I gave it a go a few weeks ago..
It does help you build up upper body strength =D

see http://journeytoforever.org/biodiesel_yield.html



-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] Behalf Of james porakari
Sent: Friday, August 19, 2005 5:26 PM
To: Biofuel@sustainablelists.org
Subject: [Biofuel] Energy content



Dear all,

Anyone can anyone help me to find information on
energy content of palm oil and Kernel oil and also
coconut oil. I am doing a research on bifuels as
alternatives in Solmon Islands (South Pacific). I am
student at University of South Pacific, Fiji.

Thanks,

James


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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread Pieter Koole




 My question is since 
composting does a good job of breaking down lignin, would it be possible to use 
composting as part of the ethanol creation process?

I can imagine that the micro organisms "eat" also 
the sugars, leaving nothing for you to ferment to sugar.

Greetings,
Pieter
Netherlands

  
  

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Re: [Biofuel] Energy content

2005-08-19 Thread bob allen
James, the energy content of all vegetable and animal fat/oil is about 9 
kCalories/gram or about 38 kJoules/gram.

james porakari wrote:


Dear all,

Anyone can anyone help me to find information on
energy content of palm oil and Kernel oil and also
coconut oil. I am doing a research on bifuels as
alternatives in Solmon Islands (South Pacific). I am
student at University of South Pacific, Fiji.




--
Bob Allen
http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves — Richard Feynman

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Re: [Biofuel] The New Blue States/Country

2005-08-19 Thread capt3d
i don't think there's anything about the context which implicitly leans 
toward either legitimate government involvement from any number of agencies, 
or 
downright censorship.  it was simply stated that the game had been banned on 
ebay.  most people would probably read that as suggesting that there is 
something fishy about ebay's position vis-a-vis the game( it's not an 
unreasonable 
assumption that this was marilyn's intent).  whether that something be 
political 
bias on the part of ebay management, or some sort of broader conspiracy, or 
even the goernment itself, whichever way it  leads is entirely up to the 
reader's imagination (not to imply that any of those conclusions would be 
entirely 
imaginary).

cheers,

-chris

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[Biofuel] Ethanol automation

2005-08-19 Thread Rich
I would like to see variables and numbers put on the different processes 
of making ethanol in an effort to identify the equipment requirements 
and tolerances needed to ultimately lead to automation of the ethanol 
making process? Variables such as temperature in Fahrenheit or Celsius, 
speed in rpm, etc.


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Re: [Biofuel] Sodium Methoxide MSDS (Sodium methylate)

2005-08-19 Thread Joe Street

Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
Jimmy hendrix song I enjoy.)


Yeah I get that a lot. When they ask me where you goin with that gun in 
your hand I say This is my rifle and this is my gun,  This is for 
shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist you 
are a boon to this list.  Have you given any thought to the other thread 
about using some form of energy input to make the esterification 
reaction go?  Apparently it can be done with a high electric field 
strength and passing the oil/alcohol mixture at elevated temperature 
(and pressure I am guessing since the vapor pressure of methanol at 85 
deg C must be above atmoshpere).  I was also wondering about using 
intense UV light.  Any thoughts?


Joe



more below


Joe Street wrote:


Hi Bob;   see comments below.

bob allen wrote:



  Hey Joe,

Joe Street wrote:


Where is the toxicology?
For those on the list unfamiliar with MSDS (Material Safety Data 
Sheet) and the terminology this is what is missing


no LD50  (lethal dose for 50% death rate -usually tested with rats)
no LC50   (lethal concentration for 50% death rate)





 There may not be data on sodium methoxide due to its reactivity: in 
the body it quickly (essentially instantaneously)  equilibrates to 
sodium hydroxide and methanol.




Well I don't know if it is that simple. 



for my example yes.  when you combine sodium or potassium hydroxide 
with methanol, you establish an equilibrium:


sodium hydroxide + methanol -- sodium methoxide + water

addition of water such as occurs in vivo, forces the equilibrium back 
to the left.



 For example I am familar with

TMAH (TetraMethylAmmonium Hydroxide) which is essentially Methanol 
and Ammonium Hydroxide



no, not by a long shot.  Tetramethylammonium hydroxide has a formula 
of C4H13NO.  It is chemically quite different than a mixture of 
ammonium hydroxide (it self an equilibrium mixture of water, ammonia 
and ammonium hydroxide) and methanol.




 which is used as a modifier in semiconductor chemical

etching processes.  The MSDS lists a drastically different toxicity 
for the METHANOL component  approx 5000 ppm vs the TMAH  at only 25 
ppm. See:   http://www.jtbaker.com/msds/englishhtml/t1816.htm

I am no chemist



I am
 and I don't know if it is fair to make this comparison


since



not here

 we are talking about ammonium hydroxide instead of potassium

hydroxide but clearly the compound is much more toxic than the sum of 
its components.




you're comparing oranges and apples.  I spoke of a simple mixture 
NaOH/MeOH and you are talking about a compound  (CH3)4 N (+) (OH)-









and more importantly
no TLV (Threshold Limit Value which relates to the maximum 
allowable exposure before serious health effects appear due to 
daily repeated exposure)
no OEL (Time Weighted Average (TWA) which refers to what someone 
decides is an acceptable concentration which a worker can be 
exposed to over a working shift time period)





  TEL and OEL as far as I am aware relate only to volatiles.  Sodium 
Methoxide is a hygroscopic solid, hence no data.





The methoxide that I make by mixing 99% methanol with 85% assay KOH 
is volitile and definitely liquid.



You are making a mixture, the volatile component of which is still 
methanol


 So I would think it should be of

interest.  The datasheet we found for sodium methoxide refers to a 
solid you are right but that just shows the relevance of the comments 
from before that one must know something in order to even read an 
MSDS and even then it may be of limited value.  You are right though 
it is still the best info we have. I just think it is sad that the 
documentation does a very poor job of what the legislation ( or the 
intent behind the legislation) was supposed to accomplish which is to 
provide meaningful information to protect workers who have to handle 
hazardous subtsances.  



If you dug around long enough you may find a supplier of the mixture 
you are preparing.  If they sell that mixture, then they have to have 
a MSDS on it.


In this case (methoxide solution), use the methanol component msds for 
things such as an LD50 or TLV and the NaOH or KOH msds for other 
risks, such as extremely caustic, etc.




It is an echo of the type of situation so often discussed in this 
forum where legislation which is supposed to protect people ends up 
having gaps and loopholes that allow big industry to go on  with 
little more than a nod to regulations and the rest is status quo. 
Still it is better than no information.  But not much better.  I have 
worked with proprietary formulations of liquid teflon from dupont 
which required so many promises of non disclosure and confidentialty 
you would almost wonder if they really want anyone using the stuff 
and then when you finaly get it and read the MSDS it tells you there 
are proprietary elements which 

Re: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread marilyn
  My question is since composting does a good job of breaking 
down lignin, would it be possible to use composting as part of  
the ethanol creation process?

I can imagine that the micro organisms eat also the sugars, 
leaving nothing for you to ferment to sugar.
Pieter

A related question:

Mother Earth News had an article about a Missouri farmer who 
uses earthworms to turn distiller's grains into organic fertilizer. 
Could worms also break down lignin residue before distillation? 
If this is a dumb question, I apologize. I have made ethanol, but I 
am not a chemist. 

This farmer also has made a low energy vacuum distillation 
system that reduces the cost of ethanol to 38 cents a gallon. He 
will share his info with anyone. (See below)

Read about his work at
http://www.motherearthnews.com/library/1980_November_Dece
mber/A_Self_Sufficient_Energy__Livestock_System_

Some quotes from the article:

But McCutcheon's concept of integrated farming for 
self-sufficiency involves more than simply producing fuels. In 
order to manufacture ethanol at a reasonable cost, one must 
take full advantage of the value of the process's by-product . . . 
the leftover distiller's grains. Normally, such protein-rich remains 
(which usually total about one-third of the raw materials' original 
weight) can be sold outright as a livestock feed supplement or 
used directly on the farm for the same purpose. Charles, 
however, employs the residue to produce a sizable crop of 
earthworms! 

The McCutcheon brainchild is a fiberglass-fabricated, 
500-gallon-capacity still that operates under 26 inches of 
vacuum . . . a factor which allows it to work at a temperature of 
only 130 °F, as compared with the approximately 175°F that a 
distillery exposed to atmospheric pressure would have to 
achieve. 

To further improve the efficiency of his operation, Mr. McCutcheon 
uses a hardy imported yeast in his mash, which he claims can 
withstand as much as a 13% alcohol content, compared with the 
8-10% that normal yeast can handle. The additional few 
percentage points of tolerance, of course, allow the tiny 
organisms to produce more distillable ethanol per batch of 
beer. 

EDITOR'S NOTE: Charlie McCutcheon can provide further 
information concerning any of his various miracle products to 
anyone who writes hire at McCutcheon's Midwest Miracle Marts, 
Dept. TMEN, Highway 5 at Lucky Street, Payette, Missouri 65248 
(please include a self-addressed, stamped envelope). 



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Re: [Biofuel] The New Blue States/Country

2005-08-19 Thread capt3d
i think you need to check your facts.  :^)

-chris

Heck,



most Americans don't even know the proverbial Franklin stove (round 

and made of steel) has nothing to do with Ben Franklin.

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RE: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread Bede
In nz, Australia and England, we make such fantastic spreads like marmite,
and vegemite from the stuff left over from beer brewing, You yanks
don't see to like it too much tho...

http://www.marmite.com/

Cheers,

Bede



-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] Behalf Of
[EMAIL PROTECTED]
Sent: Saturday, August 20, 2005 2:43 AM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] Lignin crop redidue breakdown


  My question is since composting does a good job of breaking
down lignin, would it be possible to use composting as part of
the ethanol creation process?

I can imagine that the micro organisms eat also the sugars,
leaving nothing for you to ferment to sugar.
Pieter

A related question:

Mother Earth News had an article about a Missouri farmer who
uses earthworms to turn distiller's grains into organic fertilizer.
Could worms also break down lignin residue before distillation?
If this is a dumb question, I apologize. I have made ethanol, but I
am not a chemist.

This farmer also has made a low energy vacuum distillation
system that reduces the cost of ethanol to 38 cents a gallon. He
will share his info with anyone. (See below)

Read about his work at
http://www.motherearthnews.com/library/1980_November_Dece
mber/A_Self_Sufficient_Energy__Livestock_System_

Some quotes from the article:

But McCutcheon's concept of integrated farming for
self-sufficiency involves more than simply producing fuels. In
order to manufacture ethanol at a reasonable cost, one must
take full advantage of the value of the process's by-product . . .
the leftover distiller's grains. Normally, such protein-rich remains
(which usually total about one-third of the raw materials' original
weight) can be sold outright as a livestock feed supplement or
used directly on the farm for the same purpose. Charles,
however, employs the residue to produce a sizable crop of
earthworms! 

The McCutcheon brainchild is a fiberglass-fabricated,
500-gallon-capacity still that operates under 26 inches of
vacuum . . . a factor which allows it to work at a temperature of
only 130 0F, as compared with the approximately 1750F that a
distillery exposed to atmospheric pressure would have to
achieve. 

To further improve the efficiency of his operation, Mr. McCutcheon
uses a hardy imported yeast in his mash, which he claims can
withstand as much as a 13% alcohol content, compared with the
8-10% that normal yeast can handle. The additional few
percentage points of tolerance, of course, allow the tiny
organisms to produce more distillable ethanol per batch of
beer.

EDITOR'S NOTE: Charlie McCutcheon can provide further
information concerning any of his various miracle products to
anyone who writes hire at McCutcheon's Midwest Miracle Marts,
Dept. TMEN, Highway 5 at Lucky Street, Payette, Missouri 65248
(please include a self-addressed, stamped envelope).



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Re: [Biofuel] Sodium Methoxide MSDS (Sodium methylate)

2005-08-19 Thread bob allen

Joe Street wrote:

Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
Jimmy hendrix song I enjoy.)



Yeah I get that a lot. When they ask me where you goin with that gun in 
your hand I say This is my rifle and this is my gun,  This is for 
shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist you 
are a boon to this list.  Have you given any thought to the other thread 
about using some form of energy input to make the esterification 
reaction go?  Apparently it can be done with a high electric field 
strength and passing the oil/alcohol mixture at elevated temperature 
(and pressure I am guessing since the vapor pressure of methanol at 85 
deg C must be above atmoshpere).  I was also wondering about using 
intense UV light.  Any thoughts?





To drive a chemical reaction, you need two things:  Provide activation 
energy to move the reaction along and some way to force any equilibrium 
in the direction you want it to go (for reversible processes). 
Traditional base catalyzed transesterification uses heat to provide the 
activation energy and excess methanol to drive the equilibrium further.



Other ways to provide the activation energy may be possible, but I would 
question whether one process was any more cost effective or energy 
efficient than the traditional methods.  To make a long story short, I 
haven't given it a lot of thought, but for your average Joe(ok another 
feeble pun), stick with what works.

--
Bob Allen
http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves — Richard Feynman

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Re: [Biofuel] Energy content

2005-08-19 Thread Tom Irwin




Hi James,

If you are looking for oil production per hectare then I believe palm oil is at the top of the list. Check the archieves for more info.

Tom Irwin


From: bob allen [mailto:[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Fri, 19 Aug 2005 09:50:12 -0300Subject: Re: [Biofuel] Energy contentJames, the energy content of all vegetable and animal fat/oil is about 9 kCalories/gram or about 38 kJoules/gram.james porakari wrote: Dear all,  Anyone can anyone help me to find information on energy content of palm oil and Kernel oil and also coconut oil. I am doing a research on bifuels as alternatives in Solmon Islands (South Pacific). I am student at University of South Pacific, Fiji. -- Bob Allenhttp://ozarker.org/bob"Science is what we have learned about how to keepfrom fooling ourselves" — Richard Feynman___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/



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RE: [Biofuel] The New Blue States/Country

2005-08-19 Thread Chris Lloyd
According to the judgment of history and of their contemporaries, the
two foremost geniuses among the founding fathers were Thomas Jefferson
and Benjamin Franklin. But even geniuses make mistakes, and Franklin
made a lulu with the stove he invented.  It just plain did not work. 
 In one of those examples of being too clever by half, Franklin
designed it so that the smoke came out the bottom.   His idea was that
the stove would produce more heat, but in fact the fire went out if you
looked the other way for ten seconds.   
The basic idea was a good one: to build a freestanding cast-iron
fireplace that could be situated away from the wall, thus radiating more
heat around the room.  But Franklin did not really grasp that heat
rises, and that the smoke would have to be removed through a pipe with
access to the outside placed above the stove. 
Eventually the stove was redesigned by David R. Rittenhouse and was in
wide use by the 1790s.  Quite reasonably, he called it a Rittenhouse
stove.  But legend has its prerogatives; the device is known to this day
as the Franklin stove.



 


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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread Brian Rodgers




Glad to see others are looking at this.

Rich wrote:


  


I am looking at the second chapter of Mother Earth Alcohol Fuel -Raw
materials chapter at
http://journeytoforever.org/biofuel_library/ethanol_motherearth/meCh2.html#2_1.
  


I was involved in a recent thread called Re: [Biofuel] de-polymerizing
cellulose not practical at this point  Re: [Biofuel] ethanol from
wood
using mushrooms. I have by no means given up on these ideas. However as
a
newbie here and with biofuel I believe that I should try some of the
things
which these people have been doing with great success for many years
before I
dive head first into something that needs serious research at this
stage of its
development. 


I know I sound like a hick or worse a hippie but
I'm gonna
trade in my 6 cylinder gas powered tractor and get me a diesel and
plant some
crops on our family ranch.
I particularly like the things Kim and Garth talk about with their
sustainable
lives. I gives me a lot of hope for the future. Oh and yip, gonna git
some
chickens too, because I love eggs and I had chickens before although
the
coyotes are troublesome here. 


I think the best thing to do with cellulose is
combine it
with cow dung as was also suggested here and make our own methane! This
sounds
really good to me considering that we owe the propane company $185.00
and the
tank is at 10%. I shudder at the thought of buying a hundred pounds or
gallons
or whatever they measure that gas in. I count my blessings that we rely
only on
propane for the hot water heater and the cook stove. One hundred
gallons has
lasted for four months, still I need to get my family off of the
petro-products
nipple. We can not afford it anymore.

Brian





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[Biofuel] Question on methoxide

2005-08-19 Thread Pieter Koole
Hi friends,
For some reason or another I made some horrible BD and started to doubt
about what I am doing.
So I decided to make a range of 12 bottles of sodiummethoxide, varying from
3½ to 9 grams of lye per liter.
After mixing each liter of methanol with exactly the amount of lye, I found
out that the first liter was almost still one liter, and the last liter was
app. 10% less, with every next bottle a little less than the one before.
If it would be the evaporation, every bottle would lose the same amount, so
it must have to do something with the reaction between methanol and lye.
Can anyone give me the answer on the question what is the chemical reaction
?
Or is there something else happening which I don't know ?

The next question is of course, do I need 200 ml of the mixture (so that
would be more concentrated than 200 ml methanol + for example 4 grams of
lye) ?

Met  dank en vriendelijke groet,
Pieter Koole




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Re: [Biofuel] The New Blue States/Country

2005-08-19 Thread bob allen
Chris, please add quotes, and provide a link when copying text from a 
website.  Not doing so implies you wrote the material.  (If you wrote 
the stuff on the website, my apologies)


http://www.ideafinder.com/history/inventions/story034.htm


give credit where credit is due. it's the right thing to do


Chris Lloyd wrote:

According to the judgment of history and of their contemporaries, the
two foremost geniuses among the founding fathers were Thomas Jefferson
and Benjamin Franklin. But even geniuses make mistakes, and Franklin
made a lulu with the stove he invented.  It just plain did not work. 
 In one of those examples of being too clever by half, Franklin

designed it so that the smoke came out the bottom.   His idea was that
the stove would produce more heat, but in fact the fire went out if you
looked the other way for ten seconds.   
The basic idea was a good one: to build a freestanding cast-iron

fireplace that could be situated away from the wall, thus radiating more
heat around the room.  But Franklin did not really grasp that heat
rises, and that the smoke would have to be removed through a pipe with
access to the outside placed above the stove. 
Eventually the stove was redesigned by David R. Rittenhouse and was in

wide use by the 1790s.  Quite reasonably, he called it a Rittenhouse
stove.  But legend has its prerogatives; the device is known to this day
as the Franklin stove.



 






--
Bob Allen
http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves — Richard Feynman

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Re: [Biofuel] B.P. methanol m100?

2005-08-19 Thread Felipe Navarrete


Is that .90 cents a gallon?
If so, Can I run my 1990 honda civic on M100?
That would be a direct way to save money and burn a more environmentally 
safe

fuel...


Eriva Randriamanjatosoa wrote:


Hi Felipe,
it depends on what is reasonable. But it can be even cheaper 
-up to as low as USD .9 per gal-  at www.methanex.com  there

must be a minimum quantity per order though, which I don't know.
Try asking them at

NORTH AMERICA
Suite 1150
15301 Dallas Parkway
Addison, TX
75001
USA
T: +1 972 702 0909
F: +1 972 702 0910

Eriva


--- Felipe Navarrete [EMAIL PROTECTED] wrote:

 


Hi All,

This is my first post on the list so hello fellow Biofuelers.

I found a source for buying methanol here in Miami Florida.
Location:
South florida performance 18728 SW 107th Ave
Miami, FL (305) 233-8520

Product: B.P.  methanol.  I believe he said it was  m100.
This is 100% percent methanol according to the guy on the
phone.
Anyone familiar with this product? will this do the trick?
Price: 5 gallon pale= $33 Is this a reasonable price?
It must be special ordered.






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Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate) now alternative biodiesel process

2005-08-19 Thread Joe Street

Hi Bob;

Well although I agree if it aint broke don't fix it but according to the 
original post this electrically activated process does not require 
methoxide.  If it is true what a nice advancement.  According to the 
original post IIRC it said the process involves adding 15% methanol and 
the reaction happens at 85 deg C while passing by a DC electrode of 3 to 
5kv potential.  Here I just found and copied the text out of a reply to 
a previous post.  The subject line of the thread was Titanium (?)


snip -

Hi There:

The following US patent offers making biodiesel by adding 15% MeOH
and running the mix at 85degC past very high DC electrode to get
100% conversion - no glycerine, it is converted to 1,2,3-proprionate.
The only other byproduct is hydrogen.  Very cool, just a little
scary.

http://appft1.uspto.gov/netacgi/nph-Parser?Sect1=PTO2Sect2=HITOFFp=1u=%2Fnetahtml%2FPTO%2Fsearch-bool.htmlr=1f=Gl=50co1=ANDd=PG01s1=biodeiselOS=biodeiselRS=biodeisel  
http://tinyurl.com/8hjv7


Ray

snip-


The patent reference does not appear to be the right one.  Ray??

Joe



bob allen wrote:


Joe Street wrote:


Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
Jimmy hendrix song I enjoy.)




Yeah I get that a lot. When they ask me where you goin with that gun 
in your hand I say This is my rifle and this is my gun,  This is 
for shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist 
you are a boon to this list.  Have you given any thought to the other 
thread about using some form of energy input to make the 
esterification reaction go?  Apparently it can be done with a high 
electric field strength and passing the oil/alcohol mixture at 
elevated temperature (and pressure I am guessing since the vapor 
pressure of methanol at 85 deg C must be above atmoshpere).  I was 
also wondering about using intense UV light.  Any thoughts?





To drive a chemical reaction, you need two things:  Provide activation 
energy to move the reaction along and some way to force any 
equilibrium in the direction you want it to go (for reversible 
processes). Traditional base catalyzed transesterification uses heat 
to provide the activation energy and excess methanol to drive the 
equilibrium further.



Other ways to provide the activation energy may be possible, but I 
would question whether one process was any more cost effective or 
energy efficient than the traditional methods.  To make a long story 
short, I haven't given it a lot of thought, but for your average 
Joe(ok another feeble pun), stick with what works.




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Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate) now alternative biodiesel process

2005-08-19 Thread bob allen
Joe, just a couple of comments.  all kinds of claims can be made in 
patent applications, whether they work or not remains to be seen.  the 
process is simple enough that one could try it and see.  I did look at 
the  patent application.  some of their nomenclature is ambiguous, so it 
is not clear exactly what the products are claimed to be.



BTW, the link you provided is unrelated. It discusses an enzyme 
catalyzed process.



Joe Street wrote:

Hi Bob;

Well although I agree if it aint broke don't fix it but according to the 
original post this electrically activated process does not require 
methoxide.  If it is true what a nice advancement.  According to the 
original post IIRC it said the process involves adding 15% methanol and 
the reaction happens at 85 deg C while passing by a DC electrode of 3 to 
5kv potential.  Here I just found and copied the text out of a reply to 
a previous post.  The subject line of the thread was Titanium (?)


snip -

Hi There:

The following US patent offers making biodiesel by adding 15% MeOH
and running the mix at 85degC past very high DC electrode to get
100% conversion - no glycerine, it is converted to 1,2,3-proprionate.
The only other byproduct is hydrogen.  Very cool, just a little
scary.

http://appft1.uspto.gov/netacgi/nph-Parser?Sect1=PTO2Sect2=HITOFFp=1u=%2Fnetahtml%2FPTO%2Fsearch-bool.htmlr=1f=Gl=50co1=ANDd=PG01s1=biodeiselOS=biodeiselRS=biodeisel  
http://tinyurl.com/8hjv7


Ray

snip-


The patent reference does not appear to be the right one.  Ray??

Joe



bob allen wrote:


Joe Street wrote:


Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
Jimmy hendrix song I enjoy.)





Yeah I get that a lot. When they ask me where you goin with that gun 
in your hand I say This is my rifle and this is my gun,  This is 
for shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist 
you are a boon to this list.  Have you given any thought to the other 
thread about using some form of energy input to make the 
esterification reaction go?  Apparently it can be done with a high 
electric field strength and passing the oil/alcohol mixture at 
elevated temperature (and pressure I am guessing since the vapor 
pressure of methanol at 85 deg C must be above atmoshpere).  I was 
also wondering about using intense UV light.  Any thoughts?





To drive a chemical reaction, you need two things:  Provide activation 
energy to move the reaction along and some way to force any 
equilibrium in the direction you want it to go (for reversible 
processes). Traditional base catalyzed transesterification uses heat 
to provide the activation energy and excess methanol to drive the 
equilibrium further.



Other ways to provide the activation energy may be possible, but I 
would question whether one process was any more cost effective or 
energy efficient than the traditional methods.  To make a long story 
short, I haven't given it a lot of thought, but for your average 
Joe(ok another feeble pun), stick with what works.





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RE: [Biofuel] The New Blue States/Country

2005-08-19 Thread Chris Lloyd
 Chris, please add quotes, and provide a link when copying text from a 
website.  Not doing so implies you wrote the material. 

Sorry will do in future, It should have had the header, photo and
credits but they went when it converted to plain text Chris.

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Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate) now alternative biodiesel process

2005-08-19 Thread Joe Street

Hi Bob;

Yes I figured the link was bogus (I guess you didn't notice my note to 
that effect) so where is the real patent application do you have a 
link?  How did you find it? Ray do you have it?
BTW I did a quick test last night using a tesla coil and 40ml of WVO 
with 15% methanol.  Of course the potential was ac instead of dc but I 
was curious and it was an easy thing to try.  I could see a light 
colored phase coming off the wire at the tip where the feild is most 
concentrated.  This was at ambient conditions.  I didn't see any gas 
bubbles (the email said a byproduct was hydrogen) until I actually drew 
a submerged arc which was probably just vaporized methanol.  I'll have 
to build a proper HV stack and try it with DC.


Joe

bob allen wrote:

Joe, just a couple of comments.  all kinds of claims can be made in 
patent applications, whether they work or not remains to be seen.  the 
process is simple enough that one could try it and see.  I did look at 
the  patent application.  some of their nomenclature is ambiguous, so 
it is not clear exactly what the products are claimed to be.



BTW, the link you provided is unrelated. It discusses an enzyme 
catalyzed process.



Joe Street wrote:


Hi Bob;

Well although I agree if it aint broke don't fix it but according to 
the original post this electrically activated process does not 
require methoxide.  If it is true what a nice advancement.  According 
to the original post IIRC it said the process involves adding 15% 
methanol and the reaction happens at 85 deg C while passing by a DC 
electrode of 3 to 5kv potential.  Here I just found and copied the 
text out of a reply to a previous post.  The subject line of the 
thread was Titanium (?)


snip -

Hi There:

The following US patent offers making biodiesel by adding 15% MeOH
and running the mix at 85degC past very high DC electrode to get
100% conversion - no glycerine, it is converted to 1,2,3-proprionate.
The only other byproduct is hydrogen.  Very cool, just a little
scary.

http://appft1.uspto.gov/netacgi/nph-Parser?Sect1=PTO2Sect2=HITOFFp=1u=%2Fnetahtml%2FPTO%2Fsearch-bool.htmlr=1f=Gl=50co1=ANDd=PG01s1=biodeiselOS=biodeiselRS=biodeisel  
http://tinyurl.com/8hjv7


Ray

snip-


The patent reference does not appear to be the right one.  Ray??

Joe



bob allen wrote:


Joe Street wrote:


Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to 
a Jimmy hendrix song I enjoy.)






Yeah I get that a lot. When they ask me where you goin with that 
gun in your hand I say This is my rifle and this is my gun,  This 
is for shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist 
you are a boon to this list.  Have you given any thought to the 
other thread about using some form of energy input to make the 
esterification reaction go?  Apparently it can be done with a high 
electric field strength and passing the oil/alcohol mixture at 
elevated temperature (and pressure I am guessing since the vapor 
pressure of methanol at 85 deg C must be above atmoshpere).  I was 
also wondering about using intense UV light.  Any thoughts?





To drive a chemical reaction, you need two things:  Provide 
activation energy to move the reaction along and some way to force 
any equilibrium in the direction you want it to go (for reversible 
processes). Traditional base catalyzed transesterification uses heat 
to provide the activation energy and excess methanol to drive the 
equilibrium further.



Other ways to provide the activation energy may be possible, but I 
would question whether one process was any more cost effective or 
energy efficient than the traditional methods.  To make a long story 
short, I haven't given it a lot of thought, but for your average 
Joe(ok another feeble pun), stick with what works.






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Re: [Biofuel] alternative biodiesel process

2005-08-19 Thread Randall

Bob,

Do you have the link for the correct patent?  Or can you repost the relevant 
information?


Thanks!

Randall

- Original Message - 
From: bob allen [EMAIL PROTECTED]

To: Biofuel@sustainablelists.org
Sent: Friday, August 19, 2005 1:33 PM
Subject: Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate)now 
alternative biodiesel process



Joe, just a couple of comments.  all kinds of claims can be made in patent 
applications, whether they work or not remains to be seen.  the process is 
simple enough that one could try it and see.  I did look at the  patent 
application.  some of their nomenclature is ambiguous, so it is not clear 
exactly what the products are claimed to be.



BTW, the link you provided is unrelated. It discusses an enzyme catalyzed 
process.



Joe Street wrote:

Hi Bob;

Well although I agree if it aint broke don't fix it but according to the 
original post this electrically activated process does not require 
methoxide.  If it is true what a nice advancement.  According to the 
original post IIRC it said the process involves adding 15% methanol and 
the reaction happens at 85 deg C while passing by a DC electrode of 3 to 
5kv potential.  Here I just found and copied the text out of a reply to a 
previous post.  The subject line of the thread was Titanium (?)


snip -

Hi There:

The following US patent offers making biodiesel by adding 15% MeOH
and running the mix at 85degC past very high DC electrode to get
100% conversion - no glycerine, it is converted to 1,2,3-proprionate.
The only other byproduct is hydrogen.  Very cool, just a little
scary.

http://appft1.uspto.gov/netacgi/nph-Parser?Sect1=PTO2Sect2=HITOFFp=1u=%2Fnetahtml%2FPTO%2Fsearch-bool.htmlr=1f=Gl=50co1=ANDd=PG01s1=biodeiselOS=biodeiselRS=biodeisel 
http://tinyurl.com/8hjv7


Ray

snip-


The patent reference does not appear to be the right one.  Ray??

Joe



bob allen wrote:


Joe Street wrote:


Howdy Pardner

bob allen wrote:

Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
Jimmy hendrix song I enjoy.)





Yeah I get that a lot. When they ask me where you goin with that gun 
in your hand I say This is my rifle and this is my gun,  This is for 
shooting and this is for fun


Ok thanks for your corrections and information below.  As a chemist you 
are a boon to this list.  Have you given any thought to the other 
thread about using some form of energy input to make the esterification 
reaction go?  Apparently it can be done with a high electric field 
strength and passing the oil/alcohol mixture at elevated temperature 
(and pressure I am guessing since the vapor pressure of methanol at 85 
deg C must be above atmoshpere).  I was also wondering about using 
intense UV light.  Any thoughts?





To drive a chemical reaction, you need two things:  Provide activation 
energy to move the reaction along and some way to force any equilibrium 
in the direction you want it to go (for reversible processes). 
Traditional base catalyzed transesterification uses heat to provide the 
activation energy and excess methanol to drive the equilibrium further.



Other ways to provide the activation energy may be possible, but I would 
question whether one process was any more cost effective or energy 
efficient than the traditional methods.  To make a long story short, I 
haven't given it a lot of thought, but for your average Joe(ok another 
feeble pun), stick with what works.





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Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate) now alternative biodiesel process

2005-08-19 Thread ings . group



snip-


The patent reference does not appear to be the right one.  Ray??

Joe




My apologies

http://tinyurl.com/cxukc

Ray


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RE: [Biofuel] The New Blue States/Country

2005-08-19 Thread Keith Addison

 Chris, please add quotes, and provide a link when copying text from a
website.  Not doing so implies you wrote the material. 

Sorry will do in future, It should have had the header, photo and
credits but they went when it converted to plain text Chris.


Please send all messages in plain text in the first place. No html 
code or attachments.


Thanks.

Keith Addison
Journey to Forever
KYOTO Pref., Japan
http://journeytoforever.org/
Biofuel list owner




Wessex Ferret Club  (http://www.wessexferretclub.co.uk)



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Re: [Biofuel] FW: a problem

2005-08-19 Thread Keith Addison

Hi Derick


Hi all


Uh, Houston...

im not sure but I may have a problem. after many disappointing test 
batches I finally got several good test batches. I now moved on to a 
large batch using the same w v o used in the test batches. there was 
almost instant separation


Sorry, what's that mean? Do you mean what they call a split? It 
changes quite suddenly from WVO to esters, or most of it does anyway. 
It's the rest of it that's the problem though.


and as I have read mixing should be continued for 2 hours. so I left 
the mixer going for 2.5 hours.


Movable feast. The variables are the amount of methanol used, the 
amount of lye used, the processing temperature, the amount of 
agitation and the duration of agitation, and it's the last two that 
might not translate so easily from a one-litre test batch to a 
130-litre batch.


Anyway that sounds okay. There's been some fuss about a reverse 
reaction when you process it for too long, but if anything that would 
perhaps be a minor concern for later, when you're fine-tuning it. 
IMHO.


buy that time it was late at night and I needed to get some sleep. I 
left the batch for 8 hours and before I left for work I figured I 
would try to drain the glycerin from the bottom of my 55 gal 
galvanized reactor vessel. it was a block.


Did it solidify in the test-batches you did with that oil? It should 
have done. Not that it should solidify necessarily, but if it 
solidified in the one then it should do in the other too. See: How 
much glycerine? Why isn't it solid?

http://journeytoforever.org/biodiesel_make2.html#howmuchglyc
More important is how much soap there is -- the more soap, the more 
likely the by-product layer will solidify, no matter what oil you 
used.


Eight hours is on the quick side for settling, by the way.

After work I pumped the top layer off to a wash tank. The solid mass 
at the bottom of the reactor was much more that I had expected it 
should be from 130 liters w v o I had aprox 15 gal of solid. Is it 
me or is there way to much solid left from what I started with?


About twice as much as there would be if you got a 100% yield. We'd 
need to know how much lye you used and the titration results.


Now I have done the first wash using the bubble wash metherd. I know 
I over did it to much air to fast i have 35 gal for blended oil and 
water.


You shouldn't be able to achieve that with bubble-washing, no matter 
how much air or how fast.


I have separated some and heated it to 140 deg F  and held it for a 
few hours. When I get home ill see the results. If this didn't work 
what should i try? I have read on the postings about salt and 
vinegar im not sure what ether is supposed to do or what one to try.


I suggest you read the whole page:

http://journeytoforever.org/biodiesel_bubblewash.html
Washing: Journey to Forever
Why bother?
Which way is best?
Mist-washing
Bubble washing
Stir washing
Settling
Recycling the wash-water
Washing temperature
Emulsions
Using acid
Wash-water disposal
Drying the fuel


Any input could help.

Well I got home and there was little progress with the heat.


Two problems:

1. How to rescue the batch.

2. How to get it right next time.

We should be able to help you solve them both, I hope.

Please tell us how you get on.

Best wishes

Keith


thanks.

Derick



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Re: [Biofuel] Sodium Methoxide MSDS (Sodium methylate)

2005-08-19 Thread Keith Addison

Hi Bob and all

snip

The methoxide that I make by mixing 99% methanol with 85% assay KOH 
is volitile and definitely liquid.


You are making a mixture, the volatile component of which is still methanol


So would it be correct to say there's no such thing as methoxide fumes?

Best wishes

Keith


snip




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RE: [Biofuel] FW: a problem

2005-08-19 Thread DERICK GIORCHINO








Thanks Keith 



After reading your reply I have a sinking feeling.

Maybe my filling in the blanks will help you help me. 



-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED]]
On Behalf Of Keith Addison
Sent: Friday, August 19, 2005 12:26 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] FW: a problem



Hi Derick



Hi all



Uh, Houston...



im not sure but I may have a problem. after many disappointing test


batches I finally got several good test batches. I now moved on to
a 

large batch using the same w v o used in the test batches. there
was 

almost instant separation



Sorry, what's that mean? Do you mean what they call a
split? Yes I guess it I mean as the met oxide was
added it turned murky for a few min and then quickly started to clarify and
thin out.



It changes quite suddenly from WVO to esters, or most of it does
anyway. 

It's the rest of it that's the problem though.



and as I have read mixing should be continued for 2 hours. so I
left 

the mixer going for 2.5 hours.



Movable feast. The variables are the amount of methanol used, the 

Amount of lye used, the processing temperature, 



The amount of the met oxide was total
10 grams per liter and 20% methanol the temp was maintained at 130 to 140 deg f
depending on where I put the thermometer on the drum I use a digital lazar
thermometer

Agitation and the duration of agitation, and it's the last two that agitation
was quite vigorous I had to tie the drill to a post and clamp the lid to stop
it from spinning

Might not translate so easily from a one-litre test batch to a 

130-litre batch. 



The agitation was quite vigorous I had
to tie the drill to a post and clamp the lid to stop it from spinning





Anyway that sounds okay. There's been some fuss about a reverse 

reaction when you process it for too long, but if anything that would 

perhaps be a minor concern for later, when you're fine-tuning it. 

IMHO.



buy that time it was late at night and I needed to get some sleep.
I 

left the batch for 8 hours and before I left for work I figured I 

would try to drain the glycerin from the bottom of my 55 gal 

galvanized reactor vessel. it was a block.



Did it solidify in the test-batches you did with that oil? Yes it did.

It should have done. Not that it should solidify necessarily, but if it


solidified in the one then it should do in the other too. See:
How 

much glycerine? Why isn't it solid? I did read this and I know that there is no set amount.
I just felt there was s much, thats why I asked all of you. I will
call you experts. But I am merely a novas. 

http://journeytoforever.org/biodiesel_make2.html#howmuchglyc

More important is how much soap there is -- the more soap, the
more 

likely the by-product layer will solidify, no matter what oil you 

Used.. Im not to
concerned about the solids I only wish I had started earlier so I could have
drained it off before it got solid.



Eight hours is on the quick side for settling, by the way. So how do you let it sit for longer without getting a
brick in the bottom?



After work I pumped the top layer off to a wash tank. The solid
mass 

at the bottom of the reactor was much more that I had expected it 

should be from 130 liters w v o I had aprox 15 gal of solid. Is it 

me or is there way to much solid left from what I started with?



About twice as much as there would be if you got a 100% yield. We'd 

Need to know how much lye you used and the titration results. Titration was 5 using the world famous chopstick method.
With a total of 10 grams per liter @ 20% methanol by volume.



Now I have done the first wash using the bubble wash metherd. I know


I over did it to much air to fast i have 35 gal for blended oil and


water.



You shouldn't be able to achieve that with bubble-washing, no matter 

how much air or how fast.



I have separated some and heated it to 140 deg F and held it
for a 

few hours. When I get home ill see the results. If this didn't work


what should i try? I have read on the postings about salt and 

vinegar im not sure what ether is supposed to do or what one to
try.



I suggest you read the whole page:



http://journeytoforever.org/biodiesel_bubblewash.html
I thought I had at least 3 times, Ill look
again maybe I missed something or allot.

Washing: Journey to Forever

Why bother?

Which way is best?

Mist-washing

Bubble washing

Stir washing

Settling

Recycling the wash-water

Washing temperature

Emulsions

Using acid

Wash-water disposal

Drying the fuel



Any input could help.



Well I got home and there was little progress with the heat.



Two problems:



1. How to rescue the batch.



2. How to get it right next time.



We should be able to help you solve them both, I hope.



Please tell us how you get on.



Best wishes



Keith



thanks.



 Derick





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RE: [Biofuel] biofuel and Dodge

2005-08-19 Thread DERICK GIORCHINO








Im very new at this. But I have had
one really good batch so far and lots of bad tests. But I ran my 04 24valve on
the 15 gal I had better mileage than dino and I feel better performance. About
95% bio in the tank.











From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]] On Behalf Of Miles Dave
Sent: Thursday, August 18, 2005
9:33 PM
To: Biofuel@sustainablelists.org
Subject: [Biofuel] biofuel and
Dodge







I would like to get some input from some of you Dodge
Cummins owners about how your trucks are running on biodiesel.What % biodiesel
are you running and how long have you been running biodiesel? Any problems?
What effect if any on fuel mileage. I own a 2001 Dodge with a H.O. 24 valve
Cummins and I would like to run 100% biodiesel That has beenwashed and
dried . I would appreciate any input.











thanks,





Dave








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[Biofuel] Questions on drying Ethanol

2005-08-19 Thread Tom Irwin




Hi All,

I´m trying to figure my local costs for ethanol to try some batches in BioD from waste oil. Ethanol 100% is quite expense, 95 % a bit less and 70% least costly. I have a supplier of 3A molecular sieve at about US $40 per kilogram. I was planning on starting with the 95% and running it through a column filled with about 250 grams of the 3A sieve. I generate my own electricity. Though it is a cost, I have some excess capacity. I alsohave a muffle furnace that can get at least to 550 C. The last time I worked with zeolites and molecular sieves I had access to nitrogen gas to pump through to regenerate the columns to remove bound water. I no longer have that nitrogen gas.Is it possible to regenerate the 3A mole sieve without a blanketing gas? I may be able to pump air through the column. Does my procedure seem right for removing the water from 95% ethanol? Would the same procedure work with the 70% ethanol?

Thanks,

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Re: [Biofuel] Lignin crop redidue breakdown

2005-08-19 Thread Mike Weaver

I keep a little jar in my fridge.  I love Marmite on fresh bread.

Just a crazy Yank

Bede wrote:


In nz, Australia and England, we make such fantastic spreads like marmite,
and vegemite from the stuff left over from beer brewing, You yanks
don't see to like it too much tho...

http://www.marmite.com/

Cheers,

Bede



-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] Behalf Of
[EMAIL PROTECTED]
Sent: Saturday, August 20, 2005 2:43 AM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] Lignin crop redidue breakdown


 


My question is since composting does a good job of breaking
   


down lignin, would it be possible to use composting as part of
the ethanol creation process?

 


I can imagine that the micro organisms eat also the sugars,
   


leaving nothing for you to ferment to sugar.
Pieter

A related question:

Mother Earth News had an article about a Missouri farmer who
uses earthworms to turn distiller's grains into organic fertilizer.
Could worms also break down lignin residue before distillation?
If this is a dumb question, I apologize. I have made ethanol, but I
am not a chemist.

This farmer also has made a low energy vacuum distillation
system that reduces the cost of ethanol to 38 cents a gallon. He
will share his info with anyone. (See below)

Read about his work at
http://www.motherearthnews.com/library/1980_November_Dece
mber/A_Self_Sufficient_Energy__Livestock_System_

Some quotes from the article:

But McCutcheon's concept of integrated farming for
self-sufficiency involves more than simply producing fuels. In
order to manufacture ethanol at a reasonable cost, one must
take full advantage of the value of the process's by-product . . .
the leftover distiller's grains. Normally, such protein-rich remains
(which usually total about one-third of the raw materials' original
weight) can be sold outright as a livestock feed supplement or
used directly on the farm for the same purpose. Charles,
however, employs the residue to produce a sizable crop of
earthworms! 

The McCutcheon brainchild is a fiberglass-fabricated,
500-gallon-capacity still that operates under 26 inches of
vacuum . . . a factor which allows it to work at a temperature of
only 130 0F, as compared with the approximately 1750F that a
distillery exposed to atmospheric pressure would have to
achieve. 

To further improve the efficiency of his operation, Mr. McCutcheon
uses a hardy imported yeast in his mash, which he claims can
withstand as much as a 13% alcohol content, compared with the
8-10% that normal yeast can handle. The additional few
percentage points of tolerance, of course, allow the tiny
organisms to produce more distillable ethanol per batch of
beer.

EDITOR'S NOTE: Charlie McCutcheon can provide further
information concerning any of his various miracle products to
anyone who writes hire at McCutcheon's Midwest Miracle Marts,
Dept. TMEN, Highway 5 at Lucky Street, Payette, Missouri 65248
(please include a self-addressed, stamped envelope).



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[Biofuel] RE: High energy electrode process

2005-08-19 Thread Andy Karpay
I didn't read the Patent, and I'm not an electrical engineer, but have
worked on processes that involved high energy electrodes in liquids to
produce combustible fuels (Hydrogen, CO, and other hydrocarbons).  3-5
kV is going to be difficult to attain.  I guess it's possible at ultra
low current.  If allowed to arc it will produce a combustible gas in the
make-up described above.  This gas can be dangerous not only due to its
combustible nature, but also, I believe, to be hazardous to health if
breathed.  I have worked with the stuff, and have friends harmed
(permanent) from being around the gas.  I have no idea what the electric
will do to the chemical reaction, but as an energy source I believe it
will be expensive.  Just chiming in...

Regards to all
Andy



Message: 1
Date: Fri, 19 Aug 2005 12:06:46 -0400
From: Joe Street [EMAIL PROTECTED]
Subject: Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate) now
alternative biodiesel process
To: Biofuel@sustainablelists.org
Message-ID: [EMAIL PROTECTED]
Content-Type: text/plain; charset=windows-1252; format=flowed

Hi Bob;

Well although I agree if it aint broke don't fix it but according to the

original post this electrically activated process does not require 
methoxide.  If it is true what a nice advancement.  According to the 
original post IIRC it said the process involves adding 15% methanol and 
the reaction happens at 85 deg C while passing by a DC electrode of 3 to

5kv potential.  Here I just found and copied the text out of a reply to 
a previous post.  The subject line of the thread was Titanium (?)

snip -

Hi There:

The following US patent offers making biodiesel by adding 15% MeOH
and running the mix at 85degC past very high DC electrode to get
100% conversion - no glycerine, it is converted to 1,2,3-proprionate.
The only other byproduct is hydrogen.  Very cool, just a little
scary.

http://appft1.uspto.gov/netacgi/nph-Parser?Sect1=PTO2Sect2=HITOFFp=1u
=%2Fnetahtml%2FPTO%2Fsearch-bool.htmlr=1f=Gl=50co1=ANDd=PG01s1=bio
deiselOS=biodeiselRS=biodeisel  
http://tinyurl.com/8hjv7

Ray

snip-


The patent reference does not appear to be the right one.  Ray??

Joe



bob allen wrote:

 Joe Street wrote:

 Howdy Pardner

 bob allen wrote:

 Howdy Joe (I just had to write Hey Joe before.  its the lead to a 
 Jimmy hendrix song I enjoy.)



 Yeah I get that a lot. When they ask me where you goin with that gun

 in your hand I say This is my rifle and this is my gun,  This is 
 for shooting and this is for fun

 Ok thanks for your corrections and information below.  As a chemist 
 you are a boon to this list.  Have you given any thought to the other

 thread about using some form of energy input to make the 
 esterification reaction go?  Apparently it can be done with a high 
 electric field strength and passing the oil/alcohol mixture at 
 elevated temperature (and pressure I am guessing since the vapor 
 pressure of methanol at 85 deg C must be above atmoshpere).  I was 
 also wondering about using intense UV light.  Any thoughts?



 To drive a chemical reaction, you need two things:  Provide activation

 energy to move the reaction along and some way to force any 
 equilibrium in the direction you want it to go (for reversible 
 processes). Traditional base catalyzed transesterification uses heat 
 to provide the activation energy and excess methanol to drive the 
 equilibrium further.


 Other ways to provide the activation energy may be possible, but I 
 would question whether one process was any more cost effective or 
 energy efficient than the traditional methods.  To make a long story 
 short, I haven't given it a lot of thought, but for your average 
 Joe(ok another feeble pun), stick with what works.





--

Message: 2
Date: Fri, 19 Aug 2005 12:33:57 -0500
From: bob allen [EMAIL PROTECTED]
Subject: Re: [Biofuel] ws Sodium Methoxide MSDS (Sodium methylate)
now
alternative biodiesel process
To: Biofuel@sustainablelists.org
Message-ID: [EMAIL PROTECTED]
Content-Type: text/plain; charset=windows-1252; format=flowed

Joe, just a couple of comments.  all kinds of claims can be made in 
patent applications, whether they work or not remains to be seen.  the 
process is simple enough that one could try it and see.  I did look at 
the  patent application.  some of their nomenclature is ambiguous, so it

is not clear exactly what the products are claimed to be.


BTW, the link you provided is unrelated. It discusses an enzyme 
catalyzed process.


Joe Street wrote:
 Hi Bob;
 
 Well although I agree if it aint broke don't fix it but according to
the 
 original post this electrically activated process does not require 
 methoxide.  If it is true what a nice advancement.  According to the 
 original post IIRC it said the process involves adding 15% methanol
and 
 the reaction happens at 85 deg C while passing by a DC electrode of 3
to 
 5kv potential.  Here I just found and copied the text out of a 

RE: [Biofuel] FW: a problem

2005-08-19 Thread Keith Addison

Hello Derick


Thanks Keith

After reading your reply I have a sinking feeling.

Maybe my filling in the blanks will help you help me.

-Original Message-
From: [EMAIL PROTECTED] 
[mailto:[EMAIL PROTECTED] On Behalf Of Keith 
Addison

Sent: Friday, August 19, 2005 12:26 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] FW: a problem

Hi Derick

Hi all

Uh, Houston...

im not sure but I may have a problem. after many disappointing test

batches I finally got several good test batches. I now moved on to a

large batch using the same w v o used in the test batches. there was

almost instant separation

Sorry, what's that mean? Do you mean what they call a split? Yes I 
guess it I mean as the met oxide was added it turned murky for a few 
min and then quickly started to clarify and thin out.


It changes quite suddenly from WVO to esters, or most of it does anyway.

It's the rest of it that's the problem though.

and as I have read mixing should be continued for 2 hours. so I left

the mixer going for 2.5 hours.

Movable feast. The variables are the amount of methanol used, the

Amount of lye used, the processing temperature,


The amount of the met oxide was total 10 grams per liter and 20% 
methanol the temp was maintained at 130 to 140 deg f depending on 
where I put the thermometer on the drum I use a digital lazar 
thermometer


Agitation and the duration of agitation, and it's the last two that 
agitation was quite vigorous I had to tie the drill to a post and 
clamp the lid to stop it from spinning

Might not translate so easily from a one-litre test batch to a

130-litre batch.

The agitation was quite vigorous I had to tie the drill to a post 
and clamp the lid to stop it from spinning


You're using a drill for agitating a 130-litre batch? Unsecured? And 
the processor isn't properly closed? Lots of methanol fumes at 130 to 
140 deg F and drill motors spark. NOT recommended!


You're probably losing methanol due to fuming as well so your process 
isn't going far enough and the by-product is thicker than it should 
be.



Anyway that sounds okay. There's been some fuss about a reverse

reaction when you process it for too long, but if anything that would

perhaps be a minor concern for later, when you're fine-tuning it.

IMHO.

buy that time it was late at night and I needed to get some sleep. I

left the batch for 8 hours and before I left for work I figured I

would try to drain the glycerin from the bottom of my 55 gal

galvanized reactor vessel. it was a block.

Did it solidify in the test-batches you did with that oil? Yes it did.

It should have done. Not that it should solidify necessarily, but if it

solidified in the one then it should do in the other too. See: How

much glycerine? Why isn't it solid?I did read this


Did you read all of it?

Other factors:

* Excess methanol makes the by-product layer thinner
* Too much lye creates excess soap
* Potassium hydroxide (KOH) makes the by-product slightly thinner 
than sodium hydroxide (NaOH).


and I know that there is no set amount. I just felt there was s 
much, that's why I asked all of you. I will call you experts.


Everybody's learning, no experts.


But I am merely a novas.

http://journeytoforever.org/biodiesel_make2.html#howmuchglyc

More important is how much soap there is -- the more soap, the more

likely the by-product layer will solidify, no matter what oil you

Used.. I'm not to concerned about the solids I only wish I had 
started earlier so I could have drained it off before it got solid.


Eight hours is on the quick side for settling, by the way. So how do 
you let it sit for longer without getting a brick in the bottom?


We don't use NaOH-sodium hydroxide, we use KOH, potassium hydroxide, 
so the glycerine by-product is always liquid. However, even when we 
were using NaOH, IIRC we only got solid by-product twice, in the very 
early days before we learnt to control the process properly. It was 
solid because we used too much lye. Just as you're doing.



After work I pumped the top layer off to a wash tank. The solid mass

at the bottom of the reactor was much more that I had expected it

should be from 130 liters w v o I had aprox 15 gal of solid. Is it

me or is there way to much solid left from what I started with?

About twice as much as there would be if you got a 100% yield. We'd

Need to know how much lye you used and the titration results. 
Titration was 5 using the world famous chopstick method. With a 
total of 10 grams per liter @ 20% methanol by volume.


Sigh... All is explained. You've been keeping bad company and getting 
bad advice. No wonder you had so many failed test batches.


Go back to the beginning, start all over again. Start here:
Where do I start?
http://journeytoforever.org/biodiesel_make.html#start

Do one-litre test batches and use virgin oil with 3.5 gm of lye per 
litre of oil, NOT 5 gm.


When you move on to WVO do a proper titration. Follow the instructions 

[Biofuel] Plastic and metal recycling

2005-08-19 Thread Rich
Does Journey to Forever have any tips on recycling plastic and metal?  
The only reference I found on Journey to Forever was that Mike Pelly 
using salvage scrap metal for his equipment.   I know plastic is not 
compostable, obviously it needs some pre-treatment before even 
attempting to bring plastic back into nature.  Maybe use ultraviolet 
rays to degrade plastic?  How about metal cans, can the natural decay of 
metal be accelerated?  What are consumer-grade metal cans made of?


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Re: [Biofuel] Plastic and metal recycling

2005-08-19 Thread Rich

[EMAIL PROTECTED] wrote:

Does Journey to Forever have any tips on recycling plastic and metal?  
The only reference I found on Journey to Forever was that Mike Pelly 
using salvage scrap metal for his equipment.   I know plastic is not 
compostable, obviously it needs some pre-treatment before even 
attempting to bring plastic back into nature.  Maybe use ultraviolet 
rays to degrade plastic?  How about metal cans, can the natural decay 
of metal be accelerated?  What are consumer-grade metal cans made of?


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Maybe use fire.  Metal cans exposed to intense heat rust faster.

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Re: [Biofuel] FW: a problem

2005-08-19 Thread DERICK GIORCHINO
Hi keith
 I understand what you're saying.
No the drum is not sealed air tight but it is closed I used 1/4 flat steel
plate 4 larger than the drum diameter. I drilled a pilot hole in the top
and put pillow block bearings one on the inside and one on the outside to
hold the mixing paddle straight up and down also seals the fumes in the
drum. And I have the end of the shaft 14 above that.
Bear in mind if the process works I will build a much more professional
mixer using a sealed motor.

-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] On Behalf Of Keith Addison
Sent: Friday, August 19, 2005 7:33 PM
To: Biofuel@sustainablelists.org
Subject: RE: [Biofuel] FW: a problem

Hello Derick

Thanks Keith

After reading your reply I have a sinking feeling.

Maybe my filling in the blanks will help you help me.

-Original Message-
From: [EMAIL PROTECTED] 
[mailto:[EMAIL PROTECTED] On Behalf Of Keith 
Addison
Sent: Friday, August 19, 2005 12:26 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] FW: a problem

Hi Derick

 Hi all

Uh, Houston...

 im not sure but I may have a problem. after many disappointing test

 batches I finally got several good test batches. I now moved on to a

 large batch using the same w v o used in the test batches. there was

 almost instant separation

Sorry, what's that mean? Do you mean what they call a split? Yes I 
guess it I mean as the met oxide was added it turned murky for a few 
min and then quickly started to clarify and thin out.

It changes quite suddenly from WVO to esters, or most of it does anyway.

It's the rest of it that's the problem though.

 and as I have read mixing should be continued for 2 hours. so I left

 the mixer going for 2.5 hours.

Movable feast. The variables are the amount of methanol used, the

Amount of lye used, the processing temperature,


The amount of the met oxide was total 10 grams per liter and 20% 
methanol the temp was maintained at 130 to 140 deg f depending on 
where I put the thermometer on the drum I use a digital lazar 
thermometer

Agitation and the duration of agitation, and it's the last two that 
agitation was quite vigorous I had to tie the drill to a post and 
clamp the lid to stop it from spinning
Might not translate so easily from a one-litre test batch to a

130-litre batch.

The agitation was quite vigorous I had to tie the drill to a post 
and clamp the lid to stop it from spinning

You're using a drill for agitating a 130-litre batch? Unsecured? And 
the processor isn't properly closed? Lots of methanol fumes at 130 to 
140 deg F and drill motors spark. NOT recommended!

You're probably losing methanol due to fuming as well so your process 
isn't going far enough and the by-product is thicker than it should 
be.

Anyway that sounds okay. There's been some fuss about a reverse

reaction when you process it for too long, but if anything that would

perhaps be a minor concern for later, when you're fine-tuning it.

IMHO.

 buy that time it was late at night and I needed to get some sleep. I

 left the batch for 8 hours and before I left for work I figured I

 would try to drain the glycerin from the bottom of my 55 gal

 galvanized reactor vessel. it was a block.

Did it solidify in the test-batches you did with that oil? Yes it did.

It should have done. Not that it should solidify necessarily, but if it

solidified in the one then it should do in the other too. See: How

much glycerine? Why isn't it solid?I did read this

Did you read all of it? Sorry I must have skimmed and stopped after I found
the specific info I was looking for. But Now I have. 

Other factors:

* Excess methanol makes the by-product layer thinner
* Too much lye creates excess soap
* Potassium hydroxide (KOH) makes the by-product slightly thinner 
than sodium hydroxide (NaOH).

and I know that there is no set amount. I just felt there was s 
much, that's why I asked all of you. I will call you experts.

Everybody's learning, no experts.

But I am merely a novas.

http://journeytoforever.org/biodiesel_make2.html#howmuchglyc

More important is how much soap there is -- the more soap, the more

likely the by-product layer will solidify, no matter what oil you

Used.. I'm not to concerned about the solids I only wish I had 
started earlier so I could have drained it off before it got solid.

Eight hours is on the quick side for settling, by the way. So how do 
you let it sit for longer without getting a brick in the bottom?

We don't use NaOH-sodium hydroxide, we use KOH, potassium hydroxide, 
so the glycerine by-product is always liquid. However, even when we 
were using NaOH, IIRC we only got solid by-product twice, in the very 
early days before we learnt to control the process properly. It was 
solid because we used too much lye. Just as you're doing.
Do you mean that the titration # should be ... + 3.5 gpl instead of 5  gpl. 
I wondered about that when I read it on the chopstick method it was quite

Re: [Biofuel] Plastic and metal recycling

2005-08-19 Thread Keith Addison
Does Journey to Forever have any tips on recycling plastic and 
metal?  The only reference I found on Journey to Forever was that 
Mike Pelly using salvage scrap metal for his equipment.

You sure didn't look very hard.

http://journeytoforever.org/biodiesel_processor7.html
Test-batch mini-processor: Journey to Forever
Cost -- in our case, zero: this was all discarded junk, including 
the drill, and all in perfect working order.

http://journeytoforever.org/biodiesel_processor5.html
Simple 5-gallon processor: Journey to Forever
Like our test-batch processor, it's easy to make from not very much, 
mostly scrap and junk... The only thing we bought was the immersion 
heater, which we already had.

http://journeytoforever.org/biodiesel_processor10.html
Journey to Forever 90-litre processor
The main expense with this processor set-up was the pump (US$35). 
Most other parts were salvaged from junkyards and so on, including 
all the valves -- 12 of them altogether, which would have cost about 
US$100 if bought new. The temperature gauge was also salvaged from a 
dump, found lying face-down in the mud, but it works and it's 
accurate.

This stove is made of tin cans:
http://journeytoforever.org/teststove.html
Cookstove for schools: Journey to Forever

And so on. We use junk for just about everything, in all our biofuels 
work and all our farm work too.

Solar box cookers are made of cardboard boxes. Our incubator is made 
from cardboard boxes, a junked heating element, junked plate glass, 
junked thermometer. There's a whole section in the Education section 
on what to do with waste cardboard boxes. There are more stoves 
there too, made from tin cans and Coke cans. Our previous garden pond 
was an old bathtub.

Reduce-reuse-recycle is basic, it's instinctive with us, it's in 
everything we do.

I know plastic is not compostable, obviously it needs some 
pre-treatment before even attempting to bring plastic back into 
nature.  Maybe use ultraviolet rays to degrade plastic?  How about 
metal cans, can the natural decay of metal be accelerated?  What are 
consumer-grade metal cans made of?

Plastic and metal should be recycled, not degraded and decayed.

Best

Keith Addison
Journey to Forever
KYOTO Pref., Japan
http://journeytoforever.org/

 


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Re: [Biofuel] B.P. methanol m100?

2005-08-19 Thread Rademan, Jacobus
Hi Felipe,and all,according to me to run your car on methanol you will need 
about double the volume thus bigger injectors which is expensive and like i 
said methanol burns to +-6/1 were petrol burns 14 / 1 so u will need more feul 
to go the same distance in South Africa methanol costs r 2.37/l and petrol 
r5.80 +- i was also thinking of that.saving money .
regards 
Kobus S.A 

-Original Message-
From: [EMAIL PROTECTED]
[mailto:[EMAIL PROTECTED] Behalf Of Felipe
Navarrete
Sent: Friday, August 19, 2005 5:40 PM
To: Biofuel@sustainablelists.org
Subject: Re: [Biofuel] B.P. methanol m100?



Is that .90 cents a gallon?
If so, Can I run my 1990 honda civic on M100?
That would be a direct way to save money and burn a more environmentally 
safe
fuel...


Eriva Randriamanjatosoa wrote:

Hi Felipe,
 it depends on what is reasonable. But it can be even cheaper 
-up to as low as USD .9 per gal-  at www.methanex.com  there
must be a minimum quantity per order though, which I don't know.
 Try asking them at

 NORTH AMERICA
Suite 1150
15301 Dallas Parkway
Addison, TX
75001
USA
T: +1 972 702 0909
F: +1 972 702 0910

Eriva
 

--- Felipe Navarrete [EMAIL PROTECTED] wrote:

  

Hi All,

This is my first post on the list so hello fellow Biofuelers.

I found a source for buying methanol here in Miami Florida.
Location:
South florida performance 18728 SW 107th Ave
Miami, FL (305) 233-8520

Product: B.P.  methanol.  I believe he said it was  m100.
This is 100% percent methanol according to the guy on the
phone.
Anyone familiar with this product? will this do the trick?
Price: 5 gallon pale= $33 Is this a reasonable price?
It must be special ordered.






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