Re: RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for BD makin g?]

2005-05-06 Thread lendzian_michael

Pedro, que pasa amigo?

Michael here.

Hope you are doing well.  If you want to see me in Alabama when you 
leave Pittsboro, you are welcome.

-Michael

- Original Message -
From: Pedro Ordonez <[EMAIL PROTECTED]>
Date: Friday, May 6, 2005 11:47 am
Subject: RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for BD 
makin g?]

> -Original Message-
> From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED] 
> On Behalf
> Of Jelatancev Denis
> Sent: Friday, May 06, 2005 5:31 AM
> To: [EMAIL PROTECTED]
> Subject: RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for 
> BD makin
> g?]
> 
> >So if I understand it correctly, it seams that after transforming 
> SVO/WVOto
> >BD polymerzation problem does not exisit any more,
> 
>   Yes, that's right. Once you have separated the fatty acid chains
> from the glycerin backbone the probability of 2 double bonds 
> "finding" each
> other and reacting is greatly reduced. That means that high IV 
> oils should
> be OK to make biodiesel from. The resulting biodiesel will take a 
> lot longer
> to polymerize than the oil. It will happen, though, just not as 
> fast.  
> 
> Pedro Ordonez
> 
> 
> 
> 
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RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for BD makin g?]

2005-05-06 Thread Pedro Ordonez

-Original Message-
From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED] On Behalf
Of Jelatancev Denis
Sent: Friday, May 06, 2005 5:31 AM
To: [EMAIL PROTECTED]
Subject: RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for BD makin
g?]

>So if I understand it correctly, it seams that after transforming SVO/WVO
to
>BD polymerzation problem does not exisit any more,

Yes, that's right. Once you have separated the fatty acid chains
from the glycerin backbone the probability of 2 double bonds "finding" each
other and reacting is greatly reduced. That means that high IV oils should
be OK to make biodiesel from. The resulting biodiesel will take a lot longer
to polymerize than the oil. It will happen, though, just not as fast.  

Pedro Ordonez




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RE: [Biofuel] Re: soybeanoil/Sunflower a bad choice for BD makin g?]

2005-05-06 Thread Jelatancev Denis

Hi to all,

There was similar question about Sunflower Oil about month ago, and answer
from Ken Provost [EMAIL PROTECTED] was:

"> Sunflower oil has an IV of 133. This is even higher than soybean oil.
> Polymerization concerns arise.I am now looking for a sorce of good
> peanut wvo. peanut oil has an IV of 92 (sweet).
> 


*I don't think IV matters much for biodiesel, maybe unless you're
*leaving it around for years before burning it. Check out

www.biodiesel.org/resources/reportsdatabase/reports/gen/20020101_gen-345.pdf

*Structure Indices in FA Chemistry. How Relevant is the Iodine Value?,
*Gerhard Knothe, 2002, Journal of American Oil Chemists' Society.


*Basically, IV only matters if you're burning straight oil. Once you
*turn it into biodiesel, it doesn't matter. Even linseed makes OK
*biodiesel. There's lots of references in the paper to other research
*which arrives at similar conclusions.

*-K"

So if I understand it correctly, it seams that after transforming SVO/WVO to
BD polymerzation problem does not exisit any more,

Am I right, or that also means that Sunflower Oil is also bad choice for BD
making?

Regards,
Denis 
##
-Original Message-
From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED] On Behalf
Of Jan Warnqvist
Sent: Thursday, March 31, 2005 10:44 AM
To: [EMAIL PROTECTED]
Subject: Re: [Biofuel] Re: soybeanoil a bad choice for BD making?]

Hello DB.
Quoting :"Trans esterifying triglyceride oils and fats with
monohydric alcohols to form biodiesel largely eliminates the tendency of the
oils and fats to polymerization and auto-oxidation.." I can add that this is
the exact scenario with methyl ester from fish oil and linseed oil.
Jan
Jan Warnqvist
AGERATEC AB

[EMAIL PROTECTED]

+ 46 554 201 89
+46 70 499 38 45
- Original Message - 
From: "DB" <[EMAIL PROTECTED]>
To: <[EMAIL PROTECTED]>
Sent: Thursday, March 31, 2005 9:16 AM
Subject: Re: [Biofuel] Re: soybeanoil a bad choice for BD making?]


> Anyone making bio-diesel should be concerned with the IV of the oil and
the
> polymerzation of the engine. After a careful reading of the australian
> report "WVO as a Diesel replacement fuel" it is obvious that they are
> concerned with it's use as straight veggy oil and Not  so much
> Bio-diesel.( I would be concerned too) Here is a direct quote from that
> report. " Trans esterifying triglyceride oils and fats with
> monohydric alcohols to form biodiesel largly eliminates the tendency of
the
> oils and fats to polymerization and auto-oxidation.." The base crop for
> european biodiesel being rapeseed with a IV of 98 is a reasonable goal to
> acheve. Most of my stock is soy oil and much of it is hydrogenated. I also
> get cottonseed and peanut oil along with canola (rapeseed) I no longer use
> straight soy oil and try to make a blend. In the past when I only had soy
> oil based biodiesel I would only run BD50. I an no longer worried about
the
> IV of the oil and if you are then just run BD50.Drive down the
road
> Happy...DB ..PS. I have been making biodiesel
> since '02 and have made 1000's of gallons with zero problems.
> - Original Message - 
> From: "TLC Orchids and Such" <[EMAIL PROTECTED]>
> To: <[EMAIL PROTECTED]>
> Sent: Wednesday, March 30, 2005 4:37 PM
> Subject: Re: [Biofuel] Re: soybeanoil a bad choice for BD making?]
>
>
> > Where can we get the veg-based motor oil?
> > Can better oil filtering help with this problem?
> > Racor has a motor oil filter used in race cars.
> >
> > - Original Message - 
> > From: "stephan torak" <[EMAIL PROTECTED]>
> > To: <[EMAIL PROTECTED]>; "stephan torak" <[EMAIL PROTECTED]>
> > Sent: Wednesday, March 30, 2005 5:45 PM
> > Subject: Re: [Biofuel] Re: soybeanoil a bad choice for BD making?]
> >
> >
> >> Thanks for the follow up, Keith.
> >> I have since spent many hours researching the issue and have found some
> >> relevant facts here:
> >>
> >
www.blt.bmlf.gv.at/vero/veroeff/0100_Technical_performance_of_methyl_esthers
> > _e.pdf
> >> <#www.blt.bmlf.gv.atveroveroeff0100_Tec>
> >> Keith Addison wrote:
> >>
> >> > Hello Stephan, Jan and all
> >> >
> >> > I asked Elsbett's Alexander Noack for some comment on what he was
> >> > quoted as saying about soy oil, and got a very brief response from
him:
> >> >
> >> >> Hi Keith,
> >> >>
> >> >> this all is nearly correct, but only for direct injection engines.
> >> >>
> >> >> Mit freundlichen Grüßen / Best regards
> >> >>
> >> >> Alexander Noack
> >> >> ELSBETT Technologie GmbH
> >> >> Weissenburger Straße 15
> >> >> D-91177 Thalmaessing
> >> >> Internet: www.elsbett.com
> >> >> e-mail:  [EMAIL PROTECTED]
> >> >> phone:  +49 (0)9173 77940
> >> >> Fax:  +49 (0)9173 77942
> >> >
> >> >
> >> > This was the quote in question:
> >> >
> >> >> "Soybean oil is bad. Whether it is straight vegetable oil or soybean
> >> >> based biodiesel. It is a no-go in diesel engines. Why? In diesel
> >> >> engines you have sligh