[time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 1:48 AM, Magnus Danielson wrote:

On 05/05/2013 10:05 AM, Attila Kinali wrote:

On Sat, 4 May 2013 12:36:20 -0700
Tom Van Baak (lab)t...@leapsecond.com  wrote:


Rule of thumb: quartz is best short term, Rb or H-maser mid-term,
and Cs by far the best long-term.


Ah.. so it's a fundamental limitation. And i was looking for something
GPS specific.

Any references i could read on those limitations? A quick google
did not produce any good results.


There is a handful of references but picking up a book like Quantum
Leap is a good start.

Quartz is a bit of (syntetic) rock, cut at some angle(s), cleaned,
mounted in some hermetic sealed chamber with residue dirt, and mounting


snip



For rubidium gas-cell, there is a bunch of systematics, including

snip


The caesium atomic beam does not have wall-shifts, but rather it has
much lower systematics. One of the major onces being magnetic field.

snip


The above is a summary of things collected from a variety of sources,
but I think this coarse walk-through of issues gives some insight as to
what issues pops up where and the milage vary a lot within each group.
Modern high-performance rubidium gas-cells outperform the early
caesiums, high-performance crystals outperform several rubidiums.
The HP5065A is an example of an old clock with really good performance,
so modern is not everything, and the modern compact telecom rubidiums
and for that mater CSAC is more space/power oriented than ultimate
performance of the technology as such.



I wonder where mercury ion fits in the scheme of things, since that's 
where we're spending some money for spacecraft applications right now. 
It's supposed to be orders of magnitude better than Rb.



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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Bob Camp
Hi

Mercury was tried very early on as a vapor standard. They had some significant 
problems with it in the 1950's. It's not surprising that after 60 years 
somebody might want to take another swing at it.

Bob

On May 5, 2013, at 9:59 AM, Jim Lux jim...@earthlink.net wrote:

 On 5/5/13 1:48 AM, Magnus Danielson wrote:
 On 05/05/2013 10:05 AM, Attila Kinali wrote:
 On Sat, 4 May 2013 12:36:20 -0700
 Tom Van Baak (lab)t...@leapsecond.com  wrote:
 
 Rule of thumb: quartz is best short term, Rb or H-maser mid-term,
 and Cs by far the best long-term.
 
 Ah.. so it's a fundamental limitation. And i was looking for something
 GPS specific.
 
 Any references i could read on those limitations? A quick google
 did not produce any good results.
 
 There is a handful of references but picking up a book like Quantum
 Leap is a good start.
 
 Quartz is a bit of (syntetic) rock, cut at some angle(s), cleaned,
 mounted in some hermetic sealed chamber with residue dirt, and mounting
 
 snip
 
 
 For rubidium gas-cell, there is a bunch of systematics, including
 snip
 
 The caesium atomic beam does not have wall-shifts, but rather it has
 much lower systematics. One of the major onces being magnetic field.
 snip
 
 The above is a summary of things collected from a variety of sources,
 but I think this coarse walk-through of issues gives some insight as to
 what issues pops up where and the milage vary a lot within each group.
 Modern high-performance rubidium gas-cells outperform the early
 caesiums, high-performance crystals outperform several rubidiums.
 The HP5065A is an example of an old clock with really good performance,
 so modern is not everything, and the modern compact telecom rubidiums
 and for that mater CSAC is more space/power oriented than ultimate
 performance of the technology as such.
 
 
 I wonder where mercury ion fits in the scheme of things, since that's where 
 we're spending some money for spacecraft applications right now. It's 
 supposed to be orders of magnitude better than Rb.
 
 
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Richard (Rick) Karlquist

At HP in the 1990's, Len Cutler's group built some experimental
mercury ion standards for USNO (IIRC).  They were of the
trapped ion type.  BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.
When people say rubidium is inferior to cesium, they really
mean a gas call is inferior to an atomic beam, etc.

Rick Karlquist N6RK

On 5/5/2013 8:20 AM, Bob Camp wrote:

Hi

Mercury was tried very early on as a vapor standard. They had some significant 
problems with it in the 1950's. It's not surprising that after 60 years 
somebody might want to take another swing at it.

Bob

On May 5, 2013, at 9:59 AM, Jim Lux jim...@earthlink.net wrote:


On 5/5/13 1:48 AM, Magnus Danielson wrote:

On 05/05/2013 10:05 AM, Attila Kinali wrote:

On Sat, 4 May 2013 12:36:20 -0700
Tom Van Baak (lab)t...@leapsecond.com  wrote:


Rule of thumb: quartz is best short term, Rb or H-maser mid-term,
and Cs by far the best long-term.


Ah.. so it's a fundamental limitation. And i was looking for something
GPS specific.

Any references i could read on those limitations? A quick google
did not produce any good results.


There is a handful of references but picking up a book like Quantum
Leap is a good start.

Quartz is a bit of (syntetic) rock, cut at some angle(s), cleaned,
mounted in some hermetic sealed chamber with residue dirt, and mounting


snip



For rubidium gas-cell, there is a bunch of systematics, including

snip


The caesium atomic beam does not have wall-shifts, but rather it has
much lower systematics. One of the major onces being magnetic field.

snip


The above is a summary of things collected from a variety of sources,
but I think this coarse walk-through of issues gives some insight as to
what issues pops up where and the milage vary a lot within each group.
Modern high-performance rubidium gas-cells outperform the early
caesiums, high-performance crystals outperform several rubidiums.
The HP5065A is an example of an old clock with really good performance,
so modern is not everything, and the modern compact telecom rubidiums
and for that mater CSAC is more space/power oriented than ultimate
performance of the technology as such.



I wonder where mercury ion fits in the scheme of things, since that's where 
we're spending some money for spacecraft applications right now. It's supposed 
to be orders of magnitude better than Rb.


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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 8:42 AM, Richard (Rick) Karlquist wrote:

At HP in the 1990's, Len Cutler's group built some experimental
mercury ion standards for USNO (IIRC).  They were of the
trapped ion type.  BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.
When people say rubidium is inferior to cesium, they really
mean a gas call is inferior to an atomic beam, etc.



OK, that's interesting..

So the Hg ion they're building for Deep Space Atomic Clock (DSAC) is a 
trapped ion type. The whole thing is, as I recall, 1 liter, 1 kilo, 
including both the physics package and the electronics.


It's targeting USO type applications.



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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

Hi Jim,

On 05/05/2013 03:59 PM, Jim Lux wrote:

On 5/5/13 1:48 AM, Magnus Danielson wrote:

The above is a summary of things collected from a variety of sources,
but I think this coarse walk-through of issues gives some insight as to
what issues pops up where and the milage vary a lot within each group.
Modern high-performance rubidium gas-cells outperform the early
caesiums, high-performance crystals outperform several rubidiums.
The HP5065A is an example of an old clock with really good performance,
so modern is not everything, and the modern compact telecom rubidiums
and for that mater CSAC is more space/power oriented than ultimate
performance of the technology as such.



I wonder where mercury ion fits in the scheme of things, since that's
where we're spending some money for spacecraft applications right now.
It's supposed to be orders of magnitude better than Rb.


Mercury standards is of the ion trap variety. It has about 40,5 GHz of 
frequency, very high Q due to long unperturbed observation-time and also 
cool due to ion locking which reduces doppler shifts as well as thermal 
shift. If you also cool the ion trap physics to low temperature, the 
black body radiation shift can be reduced significantly. Ion traps can 
also be combined with laser cooling.


Ion traps is the new and fancy stuff in a historical perspective. HP did 
an attempt to build a commercial device as I recall it. Would not mind 
having one.


I think it is an interesting addition to the traditional mix. It 
achieves very high stability for the size. The CSAC is really a gas cell 
like rubidium, with similar issues. The ion trap takes a different route 
to the size issue. It has it's own set of challenges, but toss in a bit 
of engineering and they can be mastered. It has the potential to replace 
caesium beams in many applications.


It would be interesting to see if your effort on space qualified ion 
traps spills over to the commercial market. If you get spare samples, I 
can give you an address to send them. ;-)


Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

On 05/05/2013 06:50 PM, Jim Lux wrote:

On 5/5/13 8:42 AM, Richard (Rick) Karlquist wrote:

At HP in the 1990's, Len Cutler's group built some experimental
mercury ion standards for USNO (IIRC). They were of the
trapped ion type. BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.
When people say rubidium is inferior to cesium, they really
mean a gas call is inferior to an atomic beam, etc.



OK, that's interesting..

So the Hg ion they're building for Deep Space Atomic Clock (DSAC) is a
trapped ion type. The whole thing is, as I recall, 1 liter, 1 kilo,
including both the physics package and the electronics.

It's targeting USO type applications.


They have been targeting this goal for a very long time. Several 
interesting papers is to be found at PTTI, NIST etc.


Getting good performance with small volume and power is definitely 
interesting, and it does not have to be on the rice-grain level.


Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 10:05 AM, Magnus Danielson wrote:

On 05/05/2013 06:50 PM, Jim Lux wrote:

On 5/5/13 8:42 AM, Richard (Rick) Karlquist wrote:

At HP in the 1990's, Len Cutler's group built some experimental
mercury ion standards for USNO (IIRC). They were of the
trapped ion type. BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.
When people say rubidium is inferior to cesium, they really
mean a gas call is inferior to an atomic beam, etc.



OK, that's interesting..

So the Hg ion they're building for Deep Space Atomic Clock (DSAC) is a
trapped ion type. The whole thing is, as I recall, 1 liter, 1 kilo,
including both the physics package and the electronics.

It's targeting USO type applications.


They have been targeting this goal for a very long time. Several
interesting papers is to be found at PTTI, NIST etc.



Yeah.. some years (6 or 7?) ago, John Prestage had a prototype of the 
physics package working on the bench. Getting from there to a repeatably 
manufacturable space flight qualified has been a few years. Not to 
mention making flight qualified electronics to go around it.  I think 
the first flight will be next year or the year after as a hosted payload 
on something.


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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 10:01 AM, Magnus Danielson wrote:

Hi Jim,

On 05/05/2013 03:59 PM, Jim Lux wrote:

On 5/5/13 1:48 AM, Magnus Danielson wrote:

The above is a summary of things collected from a variety of sources,
but I think this coarse walk-through of issues gives some insight as to
what issues pops up where and the milage vary a lot within each group.
Modern high-performance rubidium gas-cells outperform the early
caesiums, high-performance crystals outperform several rubidiums.
The HP5065A is an example of an old clock with really good performance,
so modern is not everything, and the modern compact telecom rubidiums
and for that mater CSAC is more space/power oriented than ultimate
performance of the technology as such.



I wonder where mercury ion fits in the scheme of things, since that's
where we're spending some money for spacecraft applications right now.
It's supposed to be orders of magnitude better than Rb.






It would be interesting to see if your effort on space qualified ion
traps spills over to the commercial market. If you get spare samples, I
can give you an address to send them. ;-)



Hah.. getting just one made is a chore.. I've not worked on the project, 
but it's in the same general program as the stuff I do, so we all see 
each others' presentations at the semi-annual reviews.  It took 
significantly more time than expected to get the physics package 
manufacturing worked out.


Then there's whole thing of making 40 GHz electronics that are small, 
low power, radiation tolerant, etc.; I seem to recall that there's a 
tiny PMT in the system too, so that means HV, which is no easy feat 
either.


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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Poul-Henning Kamp
In message 51867df4.4010...@karlquist.com, Richard (Rick) Karlquist writes:

BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.

Well, somewhat.

Some flavours of atoms don't work with some architectures, so for
most of the stuff in reach for us, the atoms do indeed equate an
architecture.

The exception seems to be fountains, which can run on pretty much
any alkali atom you care to feed it, and some even able to use
both Rb og Cs (Built to nail the Rb frequency firmly down, as
I understand it).

However, there seems to be actual differences between the flavours
of atoms in fountains, and USNO have picked Rb over Cs because
they get better results that way.

-- 
Poul-Henning Kamp   | UNIX since Zilog Zeus 3.20
p...@freebsd.org | TCP/IP since RFC 956
FreeBSD committer   | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

Hi Jim,

On 05/05/2013 07:33 PM, Jim Lux wrote:

On 5/5/13 10:05 AM, Magnus Danielson wrote:

They have been targeting this goal for a very long time. Several
interesting papers is to be found at PTTI, NIST etc.



Yeah.. some years (6 or 7?) ago, John Prestage had a prototype of the
physics package working on the bench. Getting from there to a repeatably
manufacturable space flight qualified has been a few years. Not to
mention making flight qualified electronics to go around it. I think the
first flight will be next year or the year after as a hosted payload on
something.


Here is a starting-point:

33rd PTTI 2001:
http://www.pttimeeting.org/archivemeetings/2001papers/paper4.pdf

38th PTTI 2006:
http://trs-new.jpl.nasa.gov/dspace/bitstream/2014/40340/1/07-0487.pdf

39th PTTI 2007:
http://www.pttimeeting.org/archivemeetings/2007papers/paper25.pdf

NIST:
http://tf.nist.gov/general/pdf/742.pdf

JPL:
http://trs-new.jpl.nasa.gov/dspace/bitstream/2014/40206/3/04-2783FN.pdf

That was only a quick search, so it is easy to find those and more.

Would be interesting to see how the lasers could be made affordable and 
compact. It's a bit difficult frequency/wavelength.


Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Attila Kinali
On Sun, 05 May 2013 18:29:53 +
Poul-Henning Kamp p...@phk.freebsd.dk wrote:

 In message 51867df4.4010...@karlquist.com, Richard (Rick) Karlquist 
 writes:
 
 BTW, it is important to understand that
 the architecture is the key factor, not the flavor of atom.
 
 Well, somewhat.
 
 Some flavours of atoms don't work with some architectures, so for
 most of the stuff in reach for us, the atoms do indeed equate an
 architecture.

The alkali atoms are pretty much interchangable.
There have been masers from Rb as well as Cs, beam standards
from Rb and H, and Rb fountains. I have not read of any H fountain
yet, but i guess it's pretty difficult to build given that the
laser light needed for cooling is in the 120nm range (UV) and
lasers in that range are pretty difficult to build (there have
been laser spectroscopy experiments using 120nm lasers nevertheless)
and that H is very light, ie the fountain would get quite long.

I also have never seen a H gas cell standard, probably for the same reason
of needing UV light.

Other classes are charged ions, these are mostly positive charged atoms
where the outermost shell becomes an s orbital with a single electron.
Prime examples are alkaline earth metals (Be, Mg, Ca, Sr,..), but also
group 12 metals (Zn, Cd, Hg) and some lanthanide/actinide (e.g. Yb).
AFAIK these are mostly interchangable as well.

I do not know what the general property of laser cooled neutral atom
frequency standards is.

One property seldom explicitly mentioned is the nuclear spin. The alkali
metal standards seem to depend on the spin being half-integral, while
laser cooled ion standards seem to be possible with both integer (including 0)
and half integer spins.

Attila Kinali

-- 
The people on 4chan are like brilliant psychologists
who also happen to be insane and gross.
-- unknown
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Poul-Henning Kamp
In message 20130505205257.8497f166abb1e49186953...@kinali.ch, Attila Kinali w
rites:

I also have never seen a H gas cell standard, probably for the same reason
of needing UV light.

Hydrogen is very hard to contain.

The way you *filter* hydrogen is to press it through a palladium film,
and that doesn't take a particular high pressure.


-- 
Poul-Henning Kamp   | UNIX since Zilog Zeus 3.20
p...@freebsd.org | TCP/IP since RFC 956
FreeBSD committer   | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

Hi Poul-Henning,

On 05/05/2013 08:29 PM, Poul-Henning Kamp wrote:

In message51867df4.4010...@karlquist.com, Richard (Rick) Karlquist writes:


BTW, it is important to understand that
the architecture is the key factor, not the flavor of atom.


Well, somewhat.

Some flavours of atoms don't work with some architectures, so for
most of the stuff in reach for us, the atoms do indeed equate an
architecture.


Well, the basic rule is that you want a single electron, preferably in 
the S state in the outermost shell. You can have that either as neutral 
atom or ionized. Depending on neutral or ionized you go into the 
classic or ion classes. This is why alkali atoms is so popular, as 
group 1 fits the description well in its neutral state.


Another aspect is how you achieve the state imbalance which can be 
achieved either by state selection magnets or by pumping. Rubidium has 
been selected traditionally because of the suitable spectrum of Rb-85 
and Rb-87 isotopes, and that these is relatively easy to come by (both 
exist in normal rubidium ore) allowing for simple filtering. Modern 
filtering and modern lasers allows a much freer selection.



The exception seems to be fountains, which can run on pretty much
any alkali atom you care to feed it, and some even able to use
both Rb og Cs (Built to nail the Rb frequency firmly down, as
I understand it).


Beam devices has been built for much more than caesium. In the original 
conception caesium was fighting with thallium, with thallium actually 
being somewhat better, but was judged a bit impractical at the time. 
Rubidium was also built as research beam units, but it has higher 
sensitivity to magnetic field pulling, which used to be an issue, which 
now largely is gone with servo capability.


The fountains is just an evolvement of the beam devices, but the beam 
falls backwards halfway through. In the fountain-context rubidium now 
has an edge over caesium. What make fountains feasible is the 
laser-cooling as it not only allows cooling, but also bouncing around 
the ball of atoms.



However, there seems to be actual differences between the flavours
of atoms in fountains, and USNO have picked Rb over Cs because
they get better results that way.


Indeed. Wasn't NPL in UK early out as well?

In the end, the actual atom used for a particular device is a result of 
what makes practical engineering at the time and achieving the best 
performance.


The optical clocks stretches the imagination even more than ion-traps 
ever did, but affordable ion-traps is still very interesting.


Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

On 05/05/2013 09:28 PM, Poul-Henning Kamp wrote:

In message20130505205257.8497f166abb1e49186953...@kinali.ch, Attila Kinali w
rites:


I also have never seen a H gas cell standard, probably for the same reason
of needing UV light.


Hydrogen is very hard to contain.

The way you *filter* hydrogen is to press it through a palladium film,
and that doesn't take a particular high pressure.


Another aspect is that D1 and D2 lines are essentially the same 
(121.5674 nm and 121.5668 nm) while for rubidium its 794.760 nm and 
780.027 nm which is about 25000 times wider. This makes pumping 
state-selection hard for hydrogen but relatively easy with rubidium.


So, for hydrogen you have to do state-selection through magnets, which 
is what is being used in hydrogen masers.


There is so many practicalities that goes in to technical decisions.

Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 11:45 AM, Magnus Danielson wrote:

Hi Jim,

On 05/05/2013 07:33 PM, Jim Lux wrote:

On 5/5/13 10:05 AM, Magnus Danielson wrote:

They have been targeting this goal for a very long time. Several
interesting papers is to be found at PTTI, NIST etc.



Yeah.. some years (6 or 7?) ago, John Prestage had a prototype of the
physics package working on the bench. Getting from there to a repeatably
manufacturable space flight qualified has been a few years. Not to
mention making flight qualified electronics to go around it. I think the
first flight will be next year or the year after as a hosted payload on
something.


Here is a starting-point:



JPL:
http://trs-new.jpl.nasa.gov/dspace/bitstream/2014/40206/3/04-2783FN.pdf



the last reference in that paper is from L.S. Cutler, et al.  Is that 
the same Cutler at HP?



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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

On 05/05/2013 11:14 PM, Jim Lux wrote:

On 5/5/13 11:45 AM, Magnus Danielson wrote:

Hi Jim,

On 05/05/2013 07:33 PM, Jim Lux wrote:

On 5/5/13 10:05 AM, Magnus Danielson wrote:

They have been targeting this goal for a very long time. Several
interesting papers is to be found at PTTI, NIST etc.



Yeah.. some years (6 or 7?) ago, John Prestage had a prototype of the
physics package working on the bench. Getting from there to a repeatably
manufacturable space flight qualified has been a few years. Not to
mention making flight qualified electronics to go around it. I think the
first flight will be next year or the year after as a hosted payload on
something.


Here is a starting-point:



JPL:
http://trs-new.jpl.nasa.gov/dspace/bitstream/2014/40206/3/04-2783FN.pdf



the last reference in that paper is from L.S. Cutler, et al. Is that the
same Cutler at HP?


Indeed it is. Guess who worked on the HP mercury ion clock?

Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Tom Knox
The idea of a Mercury Ion clocks started about 2000 and from about 2005 until 
recently has held the title of worlds most accurate clock.
Approx 1 sec per 1.6 billion years the last I heard. At the heart is a single 
trapped mercury atom. Jim Bergquist at NIST was one of those that lead the 
development.
This link has the basics: http://tf.nist.gov/general/pdf/1957.pdf.   I want two.

Thomas Knox


1-303-554-0307

 Date: Sun, 5 May 2013 06:59:12 -0700
 From: jim...@earthlink.net
 To: time-nuts@febo.com
 Subject: [time-nuts] vs Hg ion? Re:  GPS clock stabilitiy, Rb vs Cs
 
 On 5/5/13 1:48 AM, Magnus Danielson wrote:
  On 05/05/2013 10:05 AM, Attila Kinali wrote:
  On Sat, 4 May 2013 12:36:20 -0700
  Tom Van Baak (lab)t...@leapsecond.com  wrote:
 
  Rule of thumb: quartz is best short term, Rb or H-maser mid-term,
  and Cs by far the best long-term.
 
  Ah.. so it's a fundamental limitation. And i was looking for something
  GPS specific.
 
  Any references i could read on those limitations? A quick google
  did not produce any good results.
 
  There is a handful of references but picking up a book like Quantum
  Leap is a good start.
 
  Quartz is a bit of (syntetic) rock, cut at some angle(s), cleaned,
  mounted in some hermetic sealed chamber with residue dirt, and mounting
 
 snip
 
 
  For rubidium gas-cell, there is a bunch of systematics, including
 snip
 
  The caesium atomic beam does not have wall-shifts, but rather it has
  much lower systematics. One of the major onces being magnetic field.
 snip
 
  The above is a summary of things collected from a variety of sources,
  but I think this coarse walk-through of issues gives some insight as to
  what issues pops up where and the milage vary a lot within each group.
  Modern high-performance rubidium gas-cells outperform the early
  caesiums, high-performance crystals outperform several rubidiums.
  The HP5065A is an example of an old clock with really good performance,
  so modern is not everything, and the modern compact telecom rubidiums
  and for that mater CSAC is more space/power oriented than ultimate
  performance of the technology as such.
 
 
 I wonder where mercury ion fits in the scheme of things, since that's 
 where we're spending some money for spacecraft applications right now. 
 It's supposed to be orders of magnitude better than Rb.
 
 
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Magnus Danielson

Hi Tom,

On 05/05/2013 11:33 PM, Tom Knox wrote:

The idea of a Mercury Ion clocks started about 2000 and from about 2005 until 
recently has held the title of worlds most accurate clock.
Approx 1 sec per 1.6 billion years the last I heard. At the heart is a single 
trapped mercury atom. Jim Bergquist at NIST was one of those that lead the 
development.
This link has the basics: http://tf.nist.gov/general/pdf/1957.pdf.   I want two.


The history is older than that. A quick review of the early history is 
available here:

http://tf.nist.gov/general/pdf/910.pdf

First detection of the transition was in 1973.
Len Cutlers first article on the topic (as referenced in above article) 
was back in 1981.


I have all the Hg-199 and Hg-202 I need for a few clocks, but in it's 
natural mixture. Don't feel like building a separation facility...


Cheers,
Magnus
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Jim Lux

On 5/5/13 2:49 PM, Magnus Danielson wrote:


I have all the Hg-199 and Hg-202 I need for a few clocks, but in it's
natural mixture. Don't feel like building a separation facility...



Use the quadrupole system you're using as a trap as a mass-spec to do 
the separation.




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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Bob Camp
Hi

There were a number of trapped ion papers back in the 70's and 80's. The NIST 
effort to transition from Cs to an ion standard was well underway by the mid 
1980's. 

Bob

On May 5, 2013, at 5:49 PM, Magnus Danielson mag...@rubidium.dyndns.org wrote:

 Hi Tom,
 
 On 05/05/2013 11:33 PM, Tom Knox wrote:
 The idea of a Mercury Ion clocks started about 2000 and from about 2005 
 until recently has held the title of worlds most accurate clock.
 Approx 1 sec per 1.6 billion years the last I heard. At the heart is a 
 single trapped mercury atom. Jim Bergquist at NIST was one of those that 
 lead the development.
 This link has the basics: http://tf.nist.gov/general/pdf/1957.pdf.   I want 
 two.
 
 The history is older than that. A quick review of the early history is 
 available here:
 http://tf.nist.gov/general/pdf/910.pdf
 
 First detection of the transition was in 1973.
 Len Cutlers first article on the topic (as referenced in above article) was 
 back in 1981.
 
 I have all the Hg-199 and Hg-202 I need for a few clocks, but in it's natural 
 mixture. Don't feel like building a separation facility...
 
 Cheers,
 Magnus
 ___
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 To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/time-nuts
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Re: [time-nuts] vs Hg ion? Re: GPS clock stabilitiy, Rb vs Cs

2013-05-05 Thread Bob Camp
Hi

The sawtooth issues of most GPS receivers are much greater than the position 
errors a short / long survey will produce. Unless you have a very fancy self 
correcting receiver or a driver that does sawtooth correction, don't' worry 
about it.

Bob

On May 5, 2013, at 5:33 PM, Tom Knox act...@hotmail.com wrote:

 The idea of a Mercury Ion clocks started about 2000 and from about 2005 until 
 recently has held the title of worlds most accurate clock.
 Approx 1 sec per 1.6 billion years the last I heard. At the heart is a single 
 trapped mercury atom. Jim Bergquist at NIST was one of those that lead the 
 development.
 This link has the basics: http://tf.nist.gov/general/pdf/1957.pdf.   I want 
 two.
 
 Thomas Knox
 
 
 1-303-554-0307
 
 Date: Sun, 5 May 2013 06:59:12 -0700
 From: jim...@earthlink.net
 To: time-nuts@febo.com
 Subject: [time-nuts] vs Hg ion? Re:  GPS clock stabilitiy, Rb vs Cs
 
 On 5/5/13 1:48 AM, Magnus Danielson wrote:
 On 05/05/2013 10:05 AM, Attila Kinali wrote:
 On Sat, 4 May 2013 12:36:20 -0700
 Tom Van Baak (lab)t...@leapsecond.com  wrote:
 
 Rule of thumb: quartz is best short term, Rb or H-maser mid-term,
 and Cs by far the best long-term.
 
 Ah.. so it's a fundamental limitation. And i was looking for something
 GPS specific.
 
 Any references i could read on those limitations? A quick google
 did not produce any good results.
 
 There is a handful of references but picking up a book like Quantum
 Leap is a good start.
 
 Quartz is a bit of (syntetic) rock, cut at some angle(s), cleaned,
 mounted in some hermetic sealed chamber with residue dirt, and mounting
 
 snip
 
 
 For rubidium gas-cell, there is a bunch of systematics, including
 snip
 
 The caesium atomic beam does not have wall-shifts, but rather it has
 much lower systematics. One of the major onces being magnetic field.
 snip
 
 The above is a summary of things collected from a variety of sources,
 but I think this coarse walk-through of issues gives some insight as to
 what issues pops up where and the milage vary a lot within each group.
 Modern high-performance rubidium gas-cells outperform the early
 caesiums, high-performance crystals outperform several rubidiums.
 The HP5065A is an example of an old clock with really good performance,
 so modern is not everything, and the modern compact telecom rubidiums
 and for that mater CSAC is more space/power oriented than ultimate
 performance of the technology as such.
 
 
 I wonder where mercury ion fits in the scheme of things, since that's 
 where we're spending some money for spacecraft applications right now. 
 It's supposed to be orders of magnitude better than Rb.
 
 
 ___
 time-nuts mailing list -- time-nuts@febo.com
 To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/time-nuts
 and follow the instructions there.
 
 ___
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