http://cleantechnica.com/2015/05/28/sodium-ion-electric-bike-wut-wut/
Sodium-Ion Electric Bike — Wut, Wut!
May 28th, 2015  by Christopher DeMorro 

[image  
http://evobsession.com/wp-content/uploads/2015/05/faradion-prototype-electric-bicycle-powered-by-sodium-ion-battery-pack_100511344_m.jpg
(ebicycle w/ rear batt-pack - on display/demo stand)
]

The rise in the popularity of electric bicycles cannot be understated,
especially in places where congested roads or high gas prices make car
ownership unaffordable for many. So while many automakers and technology
companies are focusing on building big battery packs for electric vehicles,
Britain’s Faradion went a different route, building an electric bicycle to
prove its sodium-ion battery concept really works, reports Green Car
Congress.

The use of sodium in batteries is nothing knew. The main advantage of a
sodium-ion battery over a lithium-ion battery is reportedly the cost.
Faradion says its battery design could be 30% per kWh cheaper than a
comparable lithium-ion battery. Sodium-ion batteries are also safer in terms
of thermal runaway scenarios (i.e. fires), and less environmentally caustic.
Unfortunately, these batteries are also much larger for the same energy
density, which is why many automakers have dismissed them.

Undeterred, Faradion has built a 480Wh battery pack for its first vehicle,
an electric bicycle, hoping to demonstrate that sodium-ion batteries have a
place at the table, though only 250Wh are needed for the e-bike itself. The
sodium-ion battery was developed in conjunction with Williams Advanced
Engineering of the Williams Formula One Team, and the famed racing outfit
also provided the controller for the e-bike.

A proof of concept is one thing, though — powering a full-sized vehicle with
a sodium-ion battery is something else entirely. While the 30% lower
production price is attractive, Tesla’s Elon Musk thinks he can bring
lithium-ion battery costs down to $100 a kWh without any major chemistry
changes. Volkswagen is placing a bet on solid-state batteries in the
meantime, and one can’t count out even far-out ideas like the aluminum-air
battery pack.
[© cleantechnica.com]
...
http://www.faradion.co.uk/technology/sodium-ion-technology/
Sodium-ion Technology



http://www.greencarcongress.com/2015/05/20150515-faradion.html
Faradion demonstrates proof-of-concept sodium-ion electric bike
15 May 2015

[images
http://bioage.typepad.com/.a/6a00d8341c4fbe53ef01bb082eed5b970d-800wi
E-bike powered by Faradion prototype Na-ion battery pack. For the
proof-of-concept, the cells were manufactured to be larger than necessary to
avoid unnecessary costs and lengthy manufacturing processes at this early
stage. Click to enlarge.

http://bioage.typepad.com/.a/6a00d8341c4fbe53ef01b8d11481eb970c-800wi
A 48 cell battery pack design by Williams Advanced Engineering,
incorporating Faradion’s 3 Ah Na-ion cells

http://bioage.typepad.com/.a/6a00d8341c4fbe53ef01b8d114859a970c-800wi
Faradion CEO Lawrence Bern with the e-bike battery

http://bioage.typepad.com/.a/6a00d8341c4fbe53ef01bb082eecc9970d-800wi
Comparison of the cathode specific energy densities of some sodium ion
cathode materials achieved in full cells, with LiFePO4 included as a
well-known comparison
]

 British battery R&D company Faradion has demonstrated a proof-of-concept
electric bike powered by sodium-ion batteries at the headquarters of
Williams Advanced Engineering, which collaborated in the development of the
bike. Oxford University was also a partner. Although lithium-ion batteries
are currently the predominant battery technology in electric and hybrid
vehicles, as well as other energy storage applications, sodium-ion could
offer significant cost, safety and sustainability benefits. 

 Sodium-ion intercalation batteries—i.e., batteries using the same process
of ion insertion and removal as in Li-ion batteries—have been discussed in
the literature for some time. (e.g., Earlier post.) Using sodium instead of
lithium in a battery is attractive because it could potentially be much less
expensive (~30% less) and safer, and it would be more environmentally
benign. However, developing efficient Na+ intercalation compounds is a
challenge because sodium ions are much larger than lithium ions—about 70%
larger in radius. Thus, insertion/deinsertion of sodium ions in a host
material is much more difficult than that of lithium ions. 

 Large structural change occur during Na+ insertion and de-insertion,
leading to low capacity and poor cycling stability. For cathode materials,
the reversible, stable capacity of bulk Na+ intercalation is usually limited
to levels far below what can be obtained in Li-ion electrode materials.
(Earlier post.) 

 The battery for the e-bike has a design energy of 418 Wh, 250 Wh of which
has been used in the e-bike proof-of-concept. Faradion’s sodium-ion cells
deliver a specific energy of more than 140 Wh/kg. 

 The e-bike battery pack is made up of four modules, designed and
manufactured by Williams Advanced Engineering, and controlled by a
Williams-designed battery management system. Each module contains 12
Faradion cells. Williams is a proven leader in the design and manufacture of
battery energy storage technology, having developed batteries for the
Formula E electric racing series, Jaguar C-X75 hybrid supercar, and the
Kinetic Energy Recovery Systems (KERS) that helped power the company’s
Formula One racing cars from 2011-2013.

Oxford University’s expertise has been used to maximize battery life and it
is expected that as well as comparable performance, sodium-ion cells can
offer a comparable lifetime to lithium-ion products. 

 As a proof-of-concept, the cells for the e-bike have been manufactured to
be larger than necessary, which helps to avoid unnecessary costs and lengthy
manufacturing processes at this early stage. When optimized, the cells will
be comparable in size to lithium-ion battery packs already on the market. As
such, there is potential to exploit the technology for use in a wide range
of electric and hybrid vehicles, as well as energy storage applications.

 The project to demonstrate Faradion’s sodium-ion battery technology has
been part-funded by Innovate UK, the UK’s innovation agency in its latest
competition for ‘disruptive technologies in low carbon vehicles’. 

Faradion Na-ion technology. Faradion Limited was established in 2011 to
develop low-cost, non-aqueous sodium-ion (Na-ion) rechargeable batteries. A
typical Faradion Na-ion pouch cell would combine a hard carbon anodes, an
electrolyte (typically NaClO4-PC or NaPF6 EC/DXC/PC), and a cathode
material.

Faradion has screened more than 90 classes of novel active cathode materials
so far, including:

Phosphates: Na7M4(P2O7)4PO4, M = V, Fe, Cr, Al etc. Na4M3(PO4)2P2O7, M = Fe,
Co, Ni, Mn etc.; 

Na3M12-xM2xXO6 and Na2M12-xM2xX’O6

Layered oxides, e.g. NaNi1-x-y-zM1xM2yM3zO2

 Faradion’s Na-ion technology has already shown specific energy densities in
full cells exceeding those of other known sodium-ion materials. The Faradion
team have also already developed materials with energy densities exceeding
that of lithium iron phosphate. 

Resources
Sung You Hong, Youngjin Kim, Yuwon Park, Aram Choi, Nam-Soon Choic and Kyu
Tae Lee (2013) “Charge carriers in rechargeable batteries: Na ions vs. Li
ions” Energy Environ. Sci., 6, 2067-2081 doi: 10.1039/C3EE40811F 
[© greencarcongress.com]




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