See e.g. this thread
http://forum.pspad.com/read.php?2,13840

I don't know why on some machines PSPad try to connect to internet.
I can say I don't include any automatic conection. I don't need it. 
If you search older threads, you find different nonsence IP address what PSPad
try to connect.
Maybe it depends of some DNS access of your network...

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