Hi Folks,

I would like to respond to this intricate assessment by Andrew. 

"Albert is right that the ESS excursions are shallow.  All cold-environment 
excursions tend to be shallow as the clathrathe stability zone terminates 
closer to mean sea level in cold waters.  Therefore high latitude methane 
ebulliation is less susceptible to dissolution.  As such, oxygen treatments 
are less likely to be effective, as dissolution is a necessary precursor for 
aerobic metabolism of the methane excursions". The ESAS excursions are both 
a challenge and a benefit duo to the shallowness, yet it is not the only 
area of concern. Regardless of the reduction of dissolution, methane bubbles 
will be present and will represent a large percentage of surface out gassing 
to the atmosphere. As to oxygenation being less effective duo to cold water 
inhibiting bubble production, allow me to take that from two different 
angles. First, maintaining/enhancing the health of the biotic web, is 
important in metabolizing the dissolved methane and is far better at it than 
any effort we can even contemplate.... realistically. Second, as we know, 
the increased GW induced heating in that region will potentially illuminate 
that conditional situation.....Let's hope we have time to avoid that.    .   
   

"Steps could be taken to improve dissolution, such as by mechanically 
breaking up the bubbles, or pumping seawater across bubble vents which has 
low levels of solute gases in.  This will tend to increase dissolution. 
 However, the results obtained are likely to be no better than could be 
achieved by seeking to capture methane bubbles for flaring or 
bottling/piping, and without the according economic benefits." Industrializing 
these very fragile/remote areas for "economic benefit" is a 
thought pattern that has basically brought us to where we are. Flaring 
methane within the atmospheric Polar Cell region would be mainlining ozone 
depleting compounds directly to the Ozone Hole. ESAS just happens to be 
directly under the ascending cell flow. I think flaring, on a mass scale, 
would be profoundly catastrophic. Mechanical shearing of bubbles/pumping 
seawater???? I need help understanding the rational foundation for that 
idea.      

"In environments where dissolution occurs, but where oxygen is scarce and 
methane therefore diffuses from the sea surface, input of oxygen into the 
waters may be of benefit.  However, this is far from simple.  As has been 
pointed out, disruption of benthic ecosystems due to stirring sediments and 
transporting surface waters or oxygen down is unlikely to be desirable." That 
important point is why I proposed oxygenation "well above the biotic layer"   
"As such, any ducts would likely need to be moored some way off the seabed, 
suspended between floats and weighted anchors, or actively depth controlled 
using towed arrays from ships". Yes, that was also indicated in the original 
concept. Towed arrays are appropriate for localized areas needing 
intensive consideration.  "In shallow seas this is even more difficult to 
acheive, as the clearance depth from the sea bed would be a significant 
fraction of the total depth of the water column." Multiple means 
of mechanically/logistically addressing deferent conditions are needed. 
Extreme shallow conditions could benefit from nutrient enhancement and maybe 
rafts of mixers autonomously roving the area guided by remote methane 
monitors. 

"I do not think it viable to use ships for this task.  Oxygenation processes 
would have to be essentially continuous to be effective, and criss-crossing 
with ships is likely to be energetically and logistically expensive.  In 
order to provide year-round power in remote areas, we would need to consider 
wind turbines or tidal turbines, or shore-based power.  Turbines could be 
mounted on anchored barges, or set into the sea bed." See OOI links at the 
main thread.  Wave power is also possible, but only in non-arctic 
environments.  The power so generated could be used to aid downwelling, or 
used to pump air into ducts for venting near the sea bed." This project, if 
it goes forward, has the potential to stimulate needed new green energy 
systems through the sheer number of unit needed. I vote for methane and 
hydrogen fuel cells, as well as, hydrogen/methane uptake polymers. Here are 
a few links to that field.

http://chem.hust.edu.cn/tanbien/uploads/tan46.pdf

http://pubs.acs.org/doi/abs/10.1021/la0355500

http://sqma.myweb.usf.edu/pictures/P-24.pdf

This is just a glimpse of what is available. Even so, with materials like 
these, we could engineer more advanced methane capture concepts. Being able 
to adsorb dissolved methane from seawater would not just allow better buoys 
to be developed, but could lead to mass means to cool/heat wide ocean areas 
and/or new industrial energy supplies. Any project of the size which is 
under discussion has game changing potential within the green energy issue. 
Energy is the foundational issue. Missing this opportunity, if it develops, 
would be a historic failure of thinking.   

I don't fully agree that there's a big risk from mixing waters in the ESS. 
 The sea temperature under the ice is close to freezing point in winter.  In 
summer, surface temperatures may be significantly higher, but pumping would 
not occur at this time. Summertime albedo enhancement of that region, 
through hydrosol deployment, may be crucial to year around health of the 
general ecosystem. In that, the ESAS is shallow and the heat stress does 
degrade a number of aspects within that system. Even a minor decrease in 
solar energy uptake by the waters could provide 
significant system wide benefits. Combining that heat reduction and the 
added oxygenation provided by hydrosols, the GW stress reduction would 
probably be documented within a few seasons.I do remain concerned by mass 
movements induced by ebulliation.  Such movements are non-trivial.  Indeed, 
domestic aquaria use ebulliation to induce mass flow through undergravel 
biological filters.  The bubble diffusers used would have to be capable of 
producing small diameter bubbles which dissolve readily.  These diffusers 
would have to be well distributed, as water around the bubble column would 
quickly saturate with oxygen in the event of a high mass flow of air. I 
believe "mass movements induced by ebulliation" you are referring to an 
"eruption" of methane. If I am correct, then, preventing ebullitions is what 
this effort is about. Such discharges, once found, can be a focal point of 
active conversion of the potential energy fuel to local area cooling of the 
water. Heat is the primary reason for such eruptions. This use of the 
methane energy in cooling the surrounding waters was also claimed in the 
first post.       

As such, any undersea network of bubblers would be very expensive due to the 
complexity, power requirements, high number of vents and extreme 
environment.  The turbines, ducts and bubblers would need to expand over the 
area of an entire sea. Models and maps are now coming to my attention that 
allow for a focused effort on priority sites that currently exist. Selective 
intervention is the best way to ramp up a more broad network. The entire 
region(s) do not have to be blanketed with buoys. The thread under "Lecture 
on Methane.." is where I will try to collect the models/maps. This to me 
seems impractical.  Far better to use SRM to prevent the warming in the 
first place. The policy implications between local/regional intervention and 
global intervention make this view unrealistic, as far as time. If we give 
the ocean methane issue a high priority, the need for Global SRM may be 
delayed.... possibly avoided

One competing idea I considered is the use of foams to arrest methane 
bubbles on the surface.  This will of course cause a reduction in 
oxygenation of the waters, but at least the methane could be recovered and 
could potentially be economically useful. I have no comment.

Thanks for offering this assessment, Andrew. It is this type of questioning 
that can help a new concept evolve. A tree that grows without a breeze, will 
never weather the storm.

Michael

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