Re: [Ifeffit] Any coorelation about 'white line" in K-edge XAS with oxidation states?

2021-12-11 Thread Robert Gordon
Hi Marco, Yes, a s - d transition is dipole forbidden, but the quadrupole transition can occur, as can a transition s - mixed p/d. The edge position in XAFS for metals like Ni and Cu is taken at the inflection point leading to the first main absorption feature, but is considered to have s - d

[Ifeffit] Any coorelation about 'white line" in K-edge XAS with oxidation states?

2021-12-11 Thread Marco Wang
Dear everyone: Ihave some questions about the interpretation of "white line", from anarticle (https://doi.org/10.1038/s41467-021-27116-8) and the figure was attached. In the article, it is said that “the sample was fully reduced to Ni (0) state at ~480 °C judging from the edge position and