Dare I suggest one of the oxidising bleaches like 'Vanish', which remove stains but not colour. Contains no chlorine and is available in two types - one for whites (which I don't use) and one for whites and coloured (which I do). I haven't used it on anything valuable, but as someone who has returned to her childhood and really needs a bib when eating, it gets everything out of my cotton tops that I spill including red wine, blackcurrant juice, strawberry juice and curry sauce. They've all dried before I put them in the washing machine. Sometimes I do a spot treatment with it, but only on the rare occasion when the stain hasn't been removed fully in a normal wash.

Jean in Poole, Dorset, UK
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