Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-30 Thread archer
After a very short drive my daughter was sitting at a traffic light in her 
GL320cdi SUV when she noticed a big white cloud of something that looked 
like it may have come out of her exhaust.  There was no other car close by 
that could have produced it.  The car has just had it's first major service 
since she bought it.  She says she may have gotten a tankful of less than 
the ultra low sulphur fuel.  She hasn't seen any more white clouds behind 
the SUV since then.  Does anyone have an idea what could have caused such a 
cloud?  The only thing I could think of would be a headgasket letting water 
into a cylinder.  The dealer is 60 miles away, so driving it there could be 
risky if there is something seriously wrong.
Thanks,
Gerry

- Original Message - 
From: Peter Frederick [EMAIL PROTECTED]
 The lubricating qualities of the sulfur in diesel fuel are in the
 sulfur containing organic molecules.  There is no free sulfur dissolved
 in diesel fuel, it's all part of some carbon containing molecule (there
 are many).  It's removed by breaking up those molecules and
 precipitating out the molecular sulfur.

 Those sulfur containing molecules provide most of the lubricating
 qualities of diesel fuel, and are in fact quite good high pressure
 lubricants (much better than the paraffins or linear hydrocarbons,
 which make up 90+ % of the bulk diesel).  Taking them out greatly
 reduces the lubricating nature of the fuel.

 Peter


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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-30 Thread Robert Tara Ludwick
Did her AC start blowing not as cold at the same time?
AC blow off valves cutting loose at stop lights on real hot days is 
pretty common., Wind up with an unknown cloud either billowing out from 
under the hood or out the back if the engine fan is kicked in .

---Robert


archer wrote:
 After a very short drive my daughter was sitting at a traffic light in her 
 GL320cdi SUV when she noticed a big white cloud of something that looked 
 like it may have come out of her exhaust.  There was no other car close by 
 that could have produced it.  The car has just had it's first major service 
 since she bought it.  She says she may have gotten a tankful of less than 
 the ultra low sulphur fuel.  She hasn't seen any more white clouds behind 
 the SUV since then.  Does anyone have an idea what could have caused such a 
 cloud?  The only thing I could think of would be a headgasket letting water 
 into a cylinder.  The dealer is 60 miles away, so driving it there could be 
 risky if there is something seriously wrong.
 Thanks,
 Gerry

 - Original Message - 
 From: Peter Frederick [EMAIL PROTECTED]
   
 The lubricating qualities of the sulfur in diesel fuel are in the
 sulfur containing organic molecules.  There is no free sulfur dissolved
 in diesel fuel, it's all part of some carbon containing molecule (there
 are many).  It's removed by breaking up those molecules and
 precipitating out the molecular sulfur.

 Those sulfur containing molecules provide most of the lubricating
 qualities of diesel fuel, and are in fact quite good high pressure
 lubricants (much better than the paraffins or linear hydrocarbons,
 which make up 90+ % of the bulk diesel).  Taking them out greatly
 reduces the lubricating nature of the fuel.

 Peter
 


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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-30 Thread Alex Chamberlain
On 8/30/07, archer [EMAIL PROTECTED] wrote:
 After a very short drive my daughter was sitting at a traffic light in her
 GL320cdi SUV when she noticed a big white cloud of something that looked
 like it may have come out of her exhaust.  There was no other car close by
 that could have produced it.  The car has just had it's first major service
 since she bought it.

I don't know what kind of reputation the dealer service department
where you live has, but around here I'd immediately suspect them of
breaking something.

Alex Chamberlain
'87 300D Turbo kept far from the hamfisted clutches of dealer service

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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-30 Thread archer
I'll ask her.  Thanks Robert.
Gerry

- Original Message - 
From: Robert  Tara Ludwick [EMAIL PROTECTED]
 Did her AC start blowing not as cold at the same time?
 AC blow off valves cutting loose at stop lights on real hot days is
 pretty common., Wind up with an unknown cloud either billowing out from
 under the hood or out the back if the engine fan is kicked in .
 ---Robert

 archer wrote:
 After a very short drive my daughter was sitting at a traffic light in 
 her
 GL320cdi SUV when she noticed a big white cloud of something that looked
 like it may have come out of her exhaust.  There was no other car close 
 by
 that could have produced it.  The car has just had it's first major 
 service
 since she bought it.  She says she may have gotten a tankful of less 
 than
 the ultra low sulphur fuel.  She hasn't seen any more white clouds behind
 the SUV since then.  Does anyone have an idea what could have caused such 
 a cloud?  The only thing I could think of would be a headgasket letting 
 water
 into a cylinder.  The dealer is 60 miles away, so driving it there could 
 be
 risky if there is something seriously wrong.
 Thanks,
 Gerry


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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-30 Thread archer

- Original Message - 
 From: Alex Chamberlain [EMAIL PROTECTED]
 I don't know what kind of reputation the dealer service department
 where you live has, but around here I'd immediately suspect them of
 breaking something.

 Alex Chamberlain
 '87 300D Turbo kept far from the hamfisted clutches of dealer service

True.  They just bought the car and it has a very long warrantee on it, so 
they don't have much choice.  Their main problem is the distance from a 
dealer.
Gerry 


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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-29 Thread Robert Bigham
Sulfur is an anti-flux, that is, it does the opposite of
promoting welding.  That is its function in Extreme 
Pressure Lubricants and also, I suspect, in operation 
of old rotary Bosch IP's.

IMHO, it's a poor deslulfurization process that removes 
something besides sulfur.  I'd need to hear that the latest 
process removes not only the sulfur, but the goodies that
lubricate, with some explanation of process,  from a 
chemical engineer or someone similarly qualified.   

Paraffin is a generic name that refers to hydrocarbons 
having a particular type of structure.  There are a whole 
series of paraffins of different molecular weights.  Paraffin 
is not one chemical.  

That's all the chemical engineering I know or even suspect.
Someone else will have to take it farther. 


Peter Merle wrote:
 It's the sulphur that's the lubricant , not pariffin
 PEter
 
Sulfur is NOT a lubricant (where did you get that idea?). When sulfur is 
removed from the diesel fraction of crude by most usual methods it also 
remove the fractions that are the best lubricants. These CAN be 
replaced, but until forced to, most refiners didn't.
 
Marshall
-- 
Marshall Booth Ph.D.
Ass't Prof. (ret.)
Univ of Pittsburgh School of Medicine
[EMAIL PROTECTED]
 
 



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Re: [MBZ] Ultra low sulfur diesel and old Injector Pumps

2007-08-29 Thread Peter Frederick
The lubricating qualities of the sulfur in diesel fuel are in the 
sulfur containing organic molecules.  There is no free sulfur dissolved 
in diesel fuel, it's all part of some carbon containing molecule (there 
are many).  It's removed by breaking up those molecules and 
precipitating out the molecular sulfur.

Those sulfur containing molecules provide most of the lubricating 
qualities of diesel fuel, and are in fact quite good high pressure 
lubricants (much better than the paraffins or linear hydrocarbons, 
which make up 90+ % of the bulk diesel).  Taking them out greatly 
reduces the lubricating nature of the fuel.

Peter


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