You are INNER JOINING the country table to the query twice without giving
the query separate aliases for each. Also, you are providing only one set
of join conditions so you are going to make a Cartesian product with one
of those joins.
Looks to me like you only need the table once. Here's my s
SELECT u.UserName, u.userID, u.lastip, u.totallogins, u.lastbrowser,
u.lastlogin, u.Password, u.person, u.entryid, u.namerep, u.countryid,
c.countryid, c.image,
c.countryid, c.country
FROM Users as u, Country as c INNER JOIN Country as cc ON
cc.countryid = u.countryid
WHERE UserName = 'angelica'