After all tests have been passed and Postfix decides to accept an email, I'd like to selectively BCC some email for later (manual) inspection. But I don't want to "hold" that mail.

BCC isn't available in Access, stable.

Can always_bcc, recipient_bcc_maps or, sender_bcc_maps be called\applied\set 
from an access_map?

Like:
smtpd_data_restrictions = check_client_access regexp:/etc/postfix/suspect.regexp
...
/static/ do_bcc_here


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