Re: [Biofuel] lye electrolysis for rust removal

2009-10-20 Thread Chris Burck
oh, duh. . . .thanks for the correction.

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-20 Thread Keith Addison
oh, duh. . . .

:-) Never mind... I said the same thing when it finally dawned on me 
that the archives hadn't vanished after all.

thanks for the correction.

You're welcome.

Best

Keith

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Keith Addison
Hi NS

I have used this 'electrolysis method' of rust removal many times. 
It is very effective and useful for recovering 'old bits of iron' 
and bringing back some iron machinery back to life.

However, it should be kept in mind, that once the 'iron' has 
corroded or rusted off the item, it is gone for good and adding 
'zinc' or other things to the electrolyte does nothing to restore 
the iron artifact to original.  It means, once the artifact has been 
pitted or the rust so sever whereby the iron is removed, it cannot 
be replaced.  Electrolysis simply cleans down to the iron that has 
been left untouched by the action of rusting, it replaces nothing.

That's quite right, my own experience too. If there's enough steel 
left for the tool still to be useful, then go ahead, but if it's too 
deeply pitted, forget it. Electrolysis won't repair anything, it only 
removes the rust.

Matthew Gilbert sent me this helpful info:

http://www.holzwerken.de/museum/links/electrolysis_explanation.phtmlhttp://www.holzwerken.de/museum/links/electrolysis_explanation.phtml

has the following to say about the black stuff:

Typically the black stuff that can be rubbed off after electrolysis 
is a mixture of iron metal and magnetite, Fe 3O4 , an oxide of iron.

This site gives a pretty good description of the chemsitry of derusting.

http://en.wikipedia.org/wiki/Ferrofluidhttp://en.wikipedia.org/wiki/Ferrofluid
http://en.wikipedia.org/wiki/Magnetitehttp://en.wikipedia.org/wiki/Magnetite
explain the formation of a fluid of magnetite when in the presence 
of sodium hydroxide...

HTH - best

Keith


I am not an expert scientist on this process, only experienced from 
what I have done with using this method over the years.

cheers!
NS


--- On Sun, 10/18/09, Doug [EMAIL PROTECTED] wrote:

  From: Doug [EMAIL PROTECTED]
  Subject: Re: [Biofuel] lye electrolysis for rust removal
  To: sustainablelorgbiofuel@sustainablelists.org
  Date: Sunday, October 18, 2009, 6:10 PM
  Hi,
   I must admit I haven't used it yet, but washing soda
  (sodium carbonate, soda
  ash) can be used with an iron container or rods (not
  stainless, or you get
  nasty by-product). A battery charger is used for the power
  source.

  look here:
  http://antique-engines.com/electrol.asp
  

  Hope that helps,
  Doug


  On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
   out of curiosity, i did a web search for lye and
  rust.  the search
   gave 650,000 hits, including some discussion right
  here.  some people
   add zinc to the lye solution, the idea being,
  apparently, that the
   zinc replaces the iron in the iron oxide.  anyone
  have any thoughts on
   whether there's any real benefit to this method vs.
  this one:
   
http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
4132.html


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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Chris Burck
hi, all, thanks for the replies.  i do understand that it won't
restore an item to original condition.  i was just curious why some
would choose to add zinc to the lye bath.  seems sort of. . .i'm not
sure what word i'm looking for.  just seems to needlessly complicate
things.  keith, you linked to the same archive entry i did :)  anyway,
thanks again for the comments.

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-19 Thread Keith Addison
Hi Chris

hi, all, thanks for the replies.  i do understand that it won't
restore an item to original condition.  i was just curious why some
would choose to add zinc to the lye bath.  seems sort of. . .i'm not
sure what word i'm looking for.  just seems to needlessly complicate
things.  keith, you linked to the same archive entry i did :)

Yes, but your link doesn't work:
http://www.mail-archive.org/[EMAIL PROTECTED]/msg24132.html

It's .com, not .org:
http://www.mail-archive.com/sustainablelorgbiofuel@sustainablelists.org/msg24132.html
or
http://www.mail-archive.com/biofuel@sustainablelists.org/msg24132.html

Best

Keith

anyway,
thanks again for the comments.


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[Biofuel] lye electrolysis for rust removal

2009-10-18 Thread Chris Burck
out of curiosity, i did a web search for lye and rust.  the search
gave 650,000 hits, including some discussion right here.  some people
add zinc to the lye solution, the idea being, apparently, that the
zinc replaces the iron in the iron oxide.  anyone have any thoughts on
whether there's any real benefit to this method vs. this one:
http://www.mail-archive.org/[EMAIL PROTECTED]/msg24132.html

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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread Doug
Hi,
 I must admit I haven't used it yet, but washing soda (sodium carbonate, soda 
ash) can be used with an iron container or rods (not stainless, or you get 
nasty by-product). A battery charger is used for the power source.

look here:
http://antique-engines.com/electrol.asp 

Hope that helps,
Doug


On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
 out of curiosity, i did a web search for lye and rust.  the search
 gave 650,000 hits, including some discussion right here.  some people
 add zinc to the lye solution, the idea being, apparently, that the
 zinc replaces the iron in the iron oxide.  anyone have any thoughts on
 whether there's any real benefit to this method vs. this one:
 http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
 4132.html
 
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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread no shi
I have used this 'electrolysis method' of rust removal many times.  It is very 
effective and useful for recovering 'old bits of iron' and bringing back some 
iron machinery back to life.

However, it should be kept in mind, that once the 'iron' has corroded or rusted 
off the item, it is gone for good and adding 'zinc' or other things to the 
electrolyte does nothing to restore the iron artifact to original.  It means, 
once the artifact has been pitted or the rust so sever whereby the iron is 
removed, it cannot be replaced.  Electrolysis simply cleans down to the iron 
that has been left untouched by the action of rusting, it replaces nothing.

I am not an expert scientist on this process, only experienced from what I have 
done with using this method over the years.

cheers!
NS


--- On Sun, 10/18/09, Doug [EMAIL PROTECTED] wrote:

 From: Doug [EMAIL PROTECTED]
 Subject: Re: [Biofuel] lye electrolysis for rust removal
 To: sustainablelorgbiofuel@sustainablelists.org
 Date: Sunday, October 18, 2009, 6:10 PM
 Hi,
  I must admit I haven't used it yet, but washing soda
 (sodium carbonate, soda 
 ash) can be used with an iron container or rods (not
 stainless, or you get 
 nasty by-product). A battery charger is used for the power
 source.
 
 look here:
 http://antique-engines.com/electrol.asp
 
 
 Hope that helps,
 Doug
 
 
 On Mon, 19 Oct 2009 07:35:52 am Chris Burck wrote:
  out of curiosity, i did a web search for lye and
 rust.  the search
  gave 650,000 hits, including some discussion right
 here.  some people
  add zinc to the lye solution, the idea being,
 apparently, that the
  zinc replaces the iron in the iron oxide.  anyone
 have any thoughts on
  whether there's any real benefit to this method vs.
 this one:
  http://www.mail-archive.org/[EMAIL PROTECTED]/msg2
  4132.html
  
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 archives (70,000
   messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
  
 
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Re: [Biofuel] lye electrolysis for rust removal

2009-10-18 Thread Keith Addison
Hi Chris

out of curiosity, i did a web search for lye and rust.  the search
gave 650,000 hits, including some discussion right here.  some people
add zinc to the lye solution, the idea being, apparently, that the
zinc replaces the iron in the iron oxide.  anyone have any thoughts on
whether there's any real benefit to this method vs. this one:
http://www.mail-archive.org/[EMAIL PROTECTED]/msg24132.html

This one?
http://www.mail-archive.com/sustainablelorgbiofuel@sustainablelists.org/msg24132.html

Also here:
http://journeytoforever.org/at_billhook.html#rust

Best

Keith

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