Re: [biofuel] Correction to Recipe

2002-01-12 Thread Ken Provost

Keith Addison wrote:


Did you post the recipe? I can't find it.

Also, that's 43% more KOH than NaOH. I've never used KOH.
but most refs I've seen say you need twice as much KOH as NaOH.
You get a reaction with that little?

I sent the recipe to Livio direct, and then posted the correction
to the group -- duhh!  Anyway, the recipe is pretty obvious. I told
Livio if he couldn't get any methanol to mix in, the 1% water in the
ethanol would have to be removed with quicklime or mol sieve, and
the oil would have to be very clean and dry, well-refined. 280-320
ml ethanol, and 7g NaOH or 10g KOH, per liter of oil. Actually I
arrived at the 7g NaOH empirically (it's the molar equivalent of
10g KOH, and it works!) -- the 10g KOH is standard in the literature,
and seems to be the right amount empirically as well.

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Re: [biofuel] Correction to Recipe

2002-01-12 Thread Keith Addison

Ken Provost wrote:

Keith Addison wrote:

 
 Did you post the recipe? I can't find it.
 
 Also, that's 43% more KOH than NaOH. I've never used KOH.
 but most refs I've seen say you need twice as much KOH as NaOH.
 You get a reaction with that little?

I sent the recipe to Livio direct, and then posted the correction
to the group -- duhh!

:-) I know the feeling well. For instance, I think you've corrected 
the over-hasty misspellings in my last message (thanks!). KOK, I 
wrote, reactioon. Yeah - duhh!

Anyway, the recipe is pretty obvious. I told
Livio if he couldn't get any methanol to mix in, the 1% water in the
ethanol would have to be removed with quicklime or mol sieve, and
the oil would have to be very clean and dry, well-refined. 280-320
ml ethanol,

In another message you said: For oil between 1.0 and 2.5, I use a 
mix of 3 parts ethanol to 1 part methanol. Below 1.0 I use a 7-to-1 
mix. What proof ethanol are you using in the mix? You said elsewhere 
you got 90% with your still. 90% is good stuff, apart from being 
easier to make, nice of you could use it as-is like this.

and 7g NaOH or 10g KOH, per liter of oil. Actually I
arrived at the 7g NaOH empirically (it's the molar equivalent of
10g KOH, and it works!)

Interesting - that double it rule for KOH always seemed a bit 
imprecise to me.

-- the 10g KOH is standard in the literature,
and seems to be the right amount empirically as well.

Thanks a lot Ken, sorry to ply you with questions like this. I admire 
the work you're doing.

All best

Keith Addison
Journey to Forever
Handmade Projects
Tokyo
http://journeytoforever.org/

 


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Re: [biofuel] Correction to Recipe

2002-01-11 Thread Keith Addison

Ken Provost wrote:

Livio:

I reread my recipe in your reply, and I see a glaring error:

 For the ethoxide, dissolve 7g NaOH or 10g KOH in every liter
 of alcohol


should read , per every liter of oil, dissolve 7g NaOH or
10g KOH in the ethanol. That'll work better :-).

Hi Ken

Did you post the recipe? I can't find it.

Also, that's 43% more KOH than NaOH. I've never used KOK, but most 
refs I've seen say you need twice as much KOH as NaOH. You get a 
reactioon with that little?

Best

Keith


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