It appears you've calculated the binding energy.
Chris

On 20 April 2011 06:27, Varrun Ashok <[email protected]> wrote:

> Dear all,
>     I wanted to find the free energy (eV) of Oxygen molecule. Now I have 2
> codes' results:
> Free energy of O atom relaxed system:
>  siesta: FreeEng =      -425.805486
> Free energy O2 molecule in relaxed system:
> siesta: FreeEng =      -861.685501
> The difference between [o2]-2[0] Free energy is -8.337 eV
> But what is this number? Is it the Gibbs free energy, enthalphy? What is
> teh physical meaning of these FRee energies. How do I compare it with known
> values such as enthalphy, formation energy available in the internet?
> REgards,
> Varrun Ashok
>

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