If I have understood your question, the COOP analysis may be a good choice.
See for example:
PCCP, 2011, 13, 10091.
In this paper, within of electronic structure section, a coop analysis has been made.
I hope that it may be useful

El 6/3/2011 12:14 PM, Ian Shuttleworth escribió:
Is there any way of doing bond energy analysis in SIESTA - more
specifically, the partitioning of the bond energy into contributions
from each pair of orbitals?

With thanks

Ian Shuttleworth


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