In principle, first-principles can calculate the dielectric constant, but it is 
not implemented in the current official  version of the SIESTA code. Look into 
the following link.
http://www.icmab.es/dmmis/leem/siesta/Databases/BasisSets/
See the example of SrTiO3,e.g.


Dr. Gul Rahman
Assistant Professor,
Department of Physics,
Quaid-i-Azam University,
Islamabad, Pakistan


--- On Sun, 9/12/12, Sergio Ferrari <[email protected]> wrote:

From: Sergio Ferrari <[email protected]>
Subject: Re: [SIESTA-L] Can we use SIESTA to calculate the dielectric constant
To: [email protected]
Received: Sunday, 9 December, 2012, 1:32 AM

I am not an expert, but in my humble opinion there is no way (up to today) to 
calculate ab-initio the dielectic constant of a material. Please any other 
physicist expert in this area correct me if I am wrong.


2012/12/8 郭振东 <[email protected]>

Dear Siesta User

    Can we use SIESTA to calculate the dielectric constant of the material such 
as BN ? 

Best regards

Zhendong






-- 
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Dr. Sergio Ferrari
Depto. de Fí­sica-Fac. de Ingenierí­a

INTECIN (UBA-CONICET)
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Tel: +54 (11) 4342-1396 (Directo)
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