Dear Zahra,

Your system must be periodic in order to calculate the electronic bands. I
visualize it in GDIS and it is no periodic. To be periodic (in Z) you must
remove the hydrogen (to get match).

Also, the CNT is a 1D system, so, the bandline path are only in one
direction.

My suggestion:
1-) remove all the hydrogens.
2-) rearrange your atoms in order to get the CNT centered in the box.
3-) Adjust the Z size of the box to get a periodic system
4-) Do only geometry optimizations, and, for the optimized geometry
calculate the electronic properties.


[]'s,

Camps

On Mon, Dec 21, 2015 at 5:24 AM, Zahra Talebi <[email protected]>
wrote:

> hi every body
> I am working on carbon nanotube. I runed  the fdf file with sista which I
> would bring it at the end of this e-mail but it didn`t get converged. does
> any body knows the problem?
> here is my fdf file
>
> SystemName          nanotube
>
> SystemLabel         cnt70
>
> NumberOfAtoms      98
>
> NumberOfSpecies    2
>
> %block ChemicalSpeciesLabel
>  1  6  C      # Species index, atomic number, species label
> 2   1  H
> %endblock ChemicalSpeciesLabel
>
> LatticeConstant  1 Ang  ## This is only valid for graphene case
>
> %block LatticeVectors
>   30   0.000000  0.00000
>  0.0000  30.000  0.00000
>  0.00000   0.00      35.000000
> %endblock LatticeVectors
>
> AtomicCoordinatesFormat  Ang
>
> %block AtomicCoordinatesAndAtomicSpecies
> 0.0000000000    2.7412404500   -0.0002134000  1
>       1.1900622800    2.4702312900    0.7102282600  1
>       2.1402203900    1.7101089400   -0.0002226100  1
>       2.6702229700    0.6100571700    0.7102144500  1
>       2.6702236500   -0.6100564400   -0.0002101200  1
>       2.1402206800   -1.7101085000    0.7102263700  1
>       1.1900621700   -2.4702313500   -0.0002245400  1
>       0.0000000000   -2.7412399700    0.7102170700  1
>      -1.1900621700   -2.4702313500   -0.0002245400  1
>      -2.1402206800   -1.7101085000    0.7102263700  1
>      -2.6702236500   -0.6100564400   -0.0002101200  1
>      -2.6702229700    0.6100571700    0.7102144500  1
>      -2.1402203900    1.7101089300   -0.0002226100  1
>      -1.1900622700    2.4702312900    0.7102282600  1
>       1.1900621700    2.4702313500    2.1297755100  1
>       2.6702236500    0.6100564400    2.1297899300   1
>       2.1402203900   -1.7101089300    2.1297774300  1
>       0.0000000000   -2.7412404500    2.1297866400  1
>      -2.1402203900   -1.7101089400    2.1297774300  1
>      -2.6702236500    0.6100564400    2.1297899300  1
>      -1.1900621700    2.4702313500    2.1297755100  1
>       0.0000000000    2.7412399700    2.8402171100  1
>       2.1402206800    1.7101085000    2.8402264100  1
>       2.6702229700   -0.6100571700    2.8402144900  1
>       1.1900622700   -2.4702312900    2.8402283000   1
>      -1.1900622700   -2.4702312900    2.8402283000  1
>      -2.6702229700   -0.6100571700    2.8402144900  1
>      -2.1402206800    1.7101085000    2.8402264100  1
>       0.0000000000    2.7412404500    4.2597867000   1
>       1.1900622800    2.4702312900    4.9702283600  1
>       2.1402203900    1.7101089400    4.2597774900 1
>       2.6702229700    0.6100571700    4.9702145500   1
>       2.6702236500   -0.6100564400    4.2597899800  1
>       2.1402206800   -1.7101085000    4.9702264700  1
>       1.1900621700   -2.4702313500    4.2597755600  1
>       0.0000000000   -2.7412399700    4.9702171700  1
>      -1.1900621700   -2.4702313500    4.2597755600  1
>      -2.1402206800   -1.7101085000    4.9702264700  1
>      -2.6702236500   -0.6100564400    4.2597899800   1
>      -2.6702229700    0.6100571700    4.9702145500 1
>      -2.1402203900    1.7101089300    4.2597774900  1
>      -1.1900622700    2.4702312900    4.9702283600  1
>       1.1900621700    2.4702313500    6.3897756100  1
>       2.6702236500    0.6100564400    6.3897900300  1
>       2.1402203900   -1.7101089300    6.3897775300  1
>       0.0000000000   -2.7412404500    6.3897867400  1
>      -2.1402203900   -1.7101089400    6.3897775300  1
>      -2.6702236500    0.6100564400    6.3897900300  1
>      -1.1900621700    2.4702313500    6.3897756100  1
>       0.0000000000    2.7412399700    7.1002172100  1
>       2.1402206800    1.7101085000    7.1002265100  1
>       2.6702229700   -0.6100571700    7.1002145900  1
>       1.1900622700   -2.4702312900    7.1002284000  1
>      -1.1900622700   -2.4702312900    7.1002284000  1
>      -2.6702229700   -0.6100571700    7.1002145900  1
>      -2.1402206800    1.7101085000    7.1002265100  1
>       0.0000000000    2.7412404500    8.5197868000  1
>       1.1900622800    2.4702312900    9.2302284600  1
>       2.1402203900    1.7101089400    8.5197775900  1
>       2.6702229700    0.6100571700    9.2302146500  1
>       2.6702236500   -0.6100564400    8.5197900800  1
>       2.1402206800   -1.7101085000    9.2302265700  1
>       1.1900621700   -2.4702313500    8.5197756600  1
>       0.0000000000   -2.7412399700    9.2302172700  1
>      -1.1900621700   -2.4702313500    8.5197756600  1
>      -2.1402206800   -1.7101085000    9.2302265700  1
>      -2.6702236500   -0.6100564400    8.5197900800 1
>      -2.6702229700    0.6100571700    9.2302146500   1
>      -2.1402203900    1.7101089300    8.5197775900  1
>      -1.1900622700    2.4702312900    9.2302284600  1
>       1.1900621700    2.4702313500   10.6497757100  1
>       2.6702236500    0.6100564400   10.6497901300  1
>       2.1402203900   -1.7101089300   10.6497776300  1
>       0.0000000000   -2.7412404500   10.6497868400  1
>      -2.1402203900   -1.7101089400   10.6497776300  1
>      -2.6702236500    0.6100564400   10.6497901300  1
>      -1.1900621700    2.4702313500   10.6497757100  1
>       0.0000000000    2.7412399700   11.3602173100  1
>       2.1402206800    1.7101085000   11.3602266100  1
>       2.6702229700   -0.6100571700   11.3602146900  1
>       1.1900622700   -2.4702312900   11.3602285000  1
>      -1.1900622700   -2.4702312900   11.3602285000  1
>      -2.6702229700   -0.6100571700   11.3602146900  1
>      -2.1402206800    1.7101085000   11.3602266100  1
>       0.0000000000    2.7412404500   -1.0902134000  2
>       2.1402203900    1.7101089400   -1.0902134000  2
>       2.6702236500   -0.6100564400   -1.0902134000  2
>       1.1900621700   -2.4702313500   -1.0902134000  2
>      -1.1900621700   -2.4702313500   -1.0902134000  2
>      -2.6702236500   -0.6100564400   -1.0902134000  2
>      -2.1402203900    1.7101089300   -1.0902134000  2
>       0.0000000000    2.7412399700   12.4502173100  2
>       2.1402206800    1.7101085000   12.4502266100  2
>       2.6702229700   -0.6100571700   12.4502146900  2
>       1.1900622700   -2.4702312900   12.4502285000  2
>      -1.1900622700   -2.4702312900   12.4502285000  2
>      -2.6702229700   -0.6100571700   12.4502146900  2
>      -2.1402206800    1.7101085000   12.4502266100  2
> %endblock AtomicCoordinatesAndAtomicSpecies
>
>  XC.functional GGA
>  XC.authors    PBE
>
> %block kgrid_Monkhorst_Pack
> 2 0 0 0.0
> 0 2 0 0.0
> 0 0  2  0.0
> %endblock kgrid_Monkhorst_Pack
>
> %block    PAO.BasisSizes
>      C      DZP
>      H   DZP
> %endblock PAO.BasisSizes
>
> MeshCutoff       400.0 Ry
>
> %block ProjectedDensityOfStates
> -10.00 8.00 0.08 5000 eV
> %endblock ProjectedDensityOfStates
>
>
>  # WriteBands          True
> # BandLinesScale      ReciprocalLatticeVectors                # Default
> Value
> # %block BandLines
>  1 0.0000000000     1.0000000000     0.0000000000     X
>  60  0.0000000000     0.0000000000     0.0000000000     GAMMA
>  60  0.0000000000     0.0000000000     1.0000000000     Z
> 60   0.0000000000     1.0000000000     0.0000000000     X
> # %endblock BandLines
>
>
> DM.Tolerance          0.0001          # Tolerance in maximum difference
>
> #DM.NumberPulay        4
>
> SolutionMethod        Diagon        # OrderN or Diagon
> #DM.UseSaveDM   T
> #MD.UseSaveXV  T
> #UseSaveData    T
> DM.MixingWeight         0.091500000000
> DM.NumberPulay       7
>
>
> #MD.TypeOfRun     CG
>
> #MD.NumCGsteps          50          # Number of CG steps for
>
> LongOutput            T
>
> #MD.UseSaveCG          T
> SaveRho   T
>
> MaxSCFIterations     70
> %block LocalDensityOfStates
> -4    1   eV
> %endblock LocalDensityOfStates
>
>

Responder a