>From The Sunday Times

August 19, 2007

Scientists hail 'frozen smoke' as material that will change world

Abul Taher

A MIRACLE material for the 21st century could protect your home
against bomb blasts, mop up oil spillages and even help man to fly to
Mars.

Aerogel, one of the world's lightest solids, can withstand a direct
blast of 1kg of dynamite and protect against heat from a blowtorch at
more than 1,300C.

Scientists are working to discover new applications for the substance,
ranging from the next generation of tennis rackets to super-insulated
space suits for a manned mission to Mars.

It is expected to rank alongside wonder products from previous
generations such as Bakelite in the 1930s, carbon fibre in the 1980s
and silicone in the 1990s. Mercouri Kanatzidis, a chemistry professor
at Northwestern University in Evanston, Illinois, said: "It is an
amazing material. It has the lowest density of any product known to
man, yet at the same time it can do so much. I can see aerogel being
used for everything from filtering polluted water to insulating
against extreme temperatures and even for jewellery."

Aerogel is nicknamed "frozen smoke" and is made by extracting water
from a silica gel, then replacing it with gas such as carbon dioxide.
The result is a substance that is capable of insulating against
extreme temperatures and of absorbing pollutants such as crude oil.

It was invented by an American chemist for a bet in 1931, but early
versions were so brittle and costly that it was largely consigned to
laboratories. It was not until a decade ago that Nasa started taking
an interest in the substance and putting it to a more practical use.

In 1999 the space agency fitted its Stardust space probe with a mitt
packed full of aerogel to catch the dust from a comet's tail. It
returned with a rich collection of samples last year.

In 2002 Aspen Aerogel, a company created by Nasa, produced a stronger
and more flexible version of the gel. It is now being used to develop
an insulated lining in space suits for the first manned mission to
Mars, scheduled for 2018.

Mark Krajewski, a senior scientist at the company, believes that an
18mm layer of aerogel will be sufficient to protect astronauts from
temperatures as low as -130C. "It is the greatest insulator we've ever
seen," he said.

Aerogel is also being tested for future bombproof housing and armour
for military vehicles. In the laboratory, a metal plate coated in 6mm
of aerogel was left almost unscathed by a direct dynamite blast.

It also has green credentials. Aerogel is described by scientists as
the "ultimate sponge", with millions of tiny pores on its surface
making it ideal for absorbing pollutants in water.

Kanatzidis has created a new version of aerogel designed to mop up
lead and mercury from water. Other versions are designed to absorb oil
spills.

He is optimistic that it could be used to deal with environmental
catastrophes such as the Sea Empress spillage in 1996, when 72,000
tons of crude oil were released off the coast of Milford Haven in
Pembrokeshire.

Aerogel is also being used for everyday applications. Dunlop, the
sports equipment company, has developed a range of squash and tennis
rackets strengthened with aerogel, which are said to deliver more
power.

Earlier this year Bob Stoker, 66, from Nottingham, became the first
Briton to have his property insulated with aerogel. "The heating has
improved significantly. I turned the thermostat down five degrees.
It's been a remarkable transformation," he said.

Mountain climbers are also converts. Last year Anne Parmenter, a
British mountaineer, climbed Everest using boots that had aerogel
insoles, as well as sleeping bags padded with the material. She said
at the time: "The only problem I had was that my feet were too hot,
which is a great problem to have as a mountaineer."

However, it has failed to convince the fashion world. Hugo Boss
created a line of winter jackets out of the material but had to
withdraw them after complaints that they were too hot.

Although aerogel is classed as a solid, 99% of the substance is made
up of gas, which gives it a cloudy appearance.

Scientists say that because it has so many millions of pores and
ridges, if one cubic centimetre of aerogel were unravelled it would
fill an area the size of a football field.

Its nano-sized pores can not only collect pollutants like a sponge but
they also act as air pockets.

Researchers believe that some versions of aerogel which are made from
platinum can be used to speed up the production of hydrogen. As a
result, aerogel can be used to make hydrogen-based fuels.

http://www.timesonline.co.uk/tol/news/uk/science/article2284349.ece

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