On Jan 27, 2009, at 4:14 PM, Norton, Steve wrote:

Erik,
I know you are just starting and so many thoughts are being thrown at you but here are a few more. Remember, you don't have to do everything at once to make good CS but over time you can add improvements to your setup. Your electrode spacing is a little close, especially if you are not using a stirrer. If your electrodes are too close you will get increased electroplating of the silver from the anode to the cathode rather than the silver suspending in the water. It can also increase particle size,I believe, caused by silver ions colliding with other silver in suspension. A stirrer works to move the ions coming off the anode out into the water and reduces these effects. Without stirring I would use an electrode separation around 2 inches. Kathryn has mentioned thermal stirring but two other common techniques are a magnetic stirrer and a fish tank bubbler. The bubbler adds impurities from the air and so is not the best but it is easy and quick. However you can make a magnetic stirrer fairly easily (Google "diy magnetic stirrer" for plans). The ones on the net may stir a little fast and you may need to slow the stirrer down some (lower voltage, pulsing the drive voltage, slower motor, add weight to fan drive, etc.) As Kathryn also mentioned, yellow CS is not as good as clear CS which has smaller silver particles. While there may be people on the list making yellow CS, I am not aware of anyone. The pale yellow color is a convenient way to determine when you should stop CS generation if you have no other method of knowing when.
 - Steve N

From: Nils-Erik Stromback [mailto:[email protected]]
Sent: Tuesday, January 27, 2009 9:55 AM
To: [email protected]
Subject: Re: CS>shortcutting of silver wires, what are the effects and consequences?

I used 1/2", now after 2 shortcuts I changed it to about 3 cm. I didn't use any stirring at all in the shortcut cases, but I do it sometime with a plastic straw. I separated the wires to avoid shortcut and also with the thought that maybe less silver ions are getting suspended in the water and the big part of them getting plated  out on the cathode as they are so close.

I still dont understand why my CS does not go yellish as I have seen in so many fotos on internet, no matter if I let the process run for more than five hours.



2009/1/27 Norton, Steve <[email protected]>
Just curious but what spacing are you using between the anode and cathode and are you using any type of stirring?
Thanks,
     Steve N

From: Nils-Erik Stromback [mailto:[email protected]]
Sent: Tuesday, January 27, 2009 9:17 AM
To: [email protected]
Subject: CS>shortcutting of silver wires, what are the effects and consequences?

hi,

Yesterday I was doing some CS and I forgot about it when I started cooking, so time passed and when I remembered it had passed 2 and a half hours and the silver oxide sludge had build a bridge between the cathode and anode. Does this shortcut of wires affect negatively on the particle size in the solution or in any other possible way?

I use 15 volts and a 75 ohm resistor so I guess that the current must have raised to around 200mA when the wires got connected. When this happens does the anode continue liberating positively charge silver ions?

Thanks

Erik


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