Definitely a clear glass whisky bottle. Empty for a long long time. [In a Nitrate rich atmosphere. a barn?] Apparently glass makes a pretty good capacitor plate and that's a surface thing..could be related. But that would account for adhesion [by way of adsorption?] and maybe Gecko feet.


The permeability of glass and fused quartz to water, alcohol and ether and its relation to pressure windows has been studied. These liquids are shown to penetrate to considerable depths if the pressure is maintained for as long as fifteen minutes, in which case the pieces of glass or quartz are shattered if the pressure is rapidly released. However, if the pressure is released over a period of several days little or no breakage occurs. It is, therefore, likely that much of the difference in the behavior of pressure windows as different liquids are used in contact with the windows is due to their ability to penetrate the glass or quartz.

© 1932 The American Physical Society

..small amounts of pressure over long periods of time?

I would think that surface adsorption could be overcome fairly easily...could be wrong.

ode


At 11:19 AM 5/23/2010 -0700, you wrote:
Hi Ode, There is a whole body of science dedicated to the physics of surface chemistry. Surface molecules are not subject to the same dynamics as the molecules in the interior and thus show a different physical profile. The molecules on the surface have a certain amount of "attraction" forces available, thus the adsorption forces. Ceramic bottles containing perfumes dating back thousands of years have been found. As you know perfumes contain highly aggressive compounds such as terpenes.
Your whiskey may have been bottled in a non-glazed pottery jug?
Cheers
Frank

--------------------------------------------------
From: "Ode Coyote" <[email protected]>
Sent: Sunday, May 23, 2010 5:22 AM
To: <[email protected]>
Subject: Re: CS>Using pickle jars and virgin glass jars to make colloidal silver ---



OK, good to know it doesn't go very far in...and needn't go very far to get out.
..but it does adsorb.
Is there a difference between surface structure and the rest of the bottle where a few centuries would make a difference. [a moot point in practical terms ] I found a 100 year old whisky bottle in a barn many years ago and barely grazed it on something on the way out...it instantly turned to dust. [Whoda thunkit]

Ode

At 04:09 PM 5/22/2010 -0700, you wrote:
Ode, What you seem to describe is a well known effect of surface adsorption. It is true that glass and many other surfaces exhibit the property of attracting and retaining organic molecules much in the same way as charcoal and zeolites perform. However this is a surface phenomena ( several molecular layers thick) and it is far from "Glass isn't as "waterproof" as we think it is and just like oil will migrate though cast iron, various things will migrate through glass in either direction" The permeability of glass is such that is used to contain the smallest molecules (hydrogen) at high pressures. It is also used to hold high vacuum values for years (forever, really) Glass is impermeable to any common fluid. Hydrofluoric acid is the only compound that reacts chemically with glass but nothing migrates through. The difficulty in eliminating traces of any prior contents in glass can be eliminated by using aqua regia a mixture of 3 parts of Hydrochloric and one part of Nitric acids and allow to stand for a couple of hours and rinse thoroughly with distilled water. If necessary the mixture can be heated to 70-80C. Proceed with caution this blend is highly corrosive.

Cheers
Frank


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