In a message dated 9/27/99 7:55:35 AM Central Daylight Time, 
[email protected] writes:

<< Here is my theory as to why one of my electrodes became much skinnier than 
the other one - while using a polarity switching CS generator without a 
stirrer. 
 
 This uneven electrode wear occurred while producing a bit less than 24 
batches of 16 oz of DW with a starting current of approx .40 mA and running 
each batch for four hours.
 
 I think the uneven wear started due to my contaminating the one electrode 
more than the other by touching it more with my bare fingers before immersing 
it into the unit in the DW. The usual reason for my touching the electrodes 
was to straighten one of them or to modify the distance between the electrode 
tips, "just a hair."
 
 My presumption is that once one electrode is ever so slightly smaller than 
the other electrode it will have a higher current density and will then wear 
out faster than the other one. Thus begins an ever increasing faster rate of 
wear for the skinnier electrode. Once uneven wear starts, the process is 
irreversible and is also self accelerating.  Polarity switching won't stop 
it, only slow it down.  Agree or disagree?
 
 The running time of four hours was too long. The concluding amperage was 
over 8.0 mA. This speeded up the uneven wear process. And, remember, there 
was no stirring in this generator model I was using.
 
 I always had a bit of sludge below the electrodes and the amount of sludge 
under the skinnier electrode was always greater, unless I had touched the 
other electrode with my bare fingers just before beginning the batch.
 
 What do you two think?
 
 I'm posting this to the silver-list to invite further comment and in hope of 
helping others to avoid my mistakes.
 
 Spiroflex >>
It sounds as if the oil on the skin is protecting the silver surface of one 
electrode from good electrical contact with the conductive solution.  This 
concentrates or lessens the surface area of that electrode.  I could see 
where the erosion then would be more on one electrode than the other.  
Keeping the silver clean by the simple use of surgical gloves during the 
adjustment of them would end this problem.

gene Downey


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