I use a current controlled CS generator, by increasing the 'distance' between 
the electrodes by means of a maze type container would THEORETICALLY help me by 
increasing the resistance of the DW so that i can keep the voltages higher 
where it tends to brew more efficiently, without reaching a low voltage so soon 
and limiting the process.

for example in my setup when i reach below 6v it seems reluctant to brew any 
more.

and that's with a setup where I can increase the distance between the 
electrodes, when I reach a limit, I increase the distance between the 
electrodes so that I can brew again by increasing the voltages.

I can get 38us roughly using this method, although I am an advocate of very low 
current brewing (0.1/0.2ma per SQ inch) and my setup is geared for this in 
mind, so my current controlled setup will go low voltage quicker than most to 
maintain the low currents I am looking for my brew.

the reason I mention this is that I understand the wisdom behind the question 
and agree with this line of reasoning based on my experiences .

Peace to all,

Asif.




From: Marshall 
Sent: Friday, October 26, 2012 3:16 PM
To: [email protected] 
Subject: Re: CS>high PPM EIS concept:


On 10/25/2012 11:01 PM, David AuBuchon wrote: 
  I hope I am not violating some basic law(s) of electrochemistry here...I'll 
give myself a 50% chance of someone correcting me:

  What if you divided the cell with a material that is nonconducting, does not 
react with silver ions, and manages to obstruct the flow of current between the 
electrodes completely.  Then you punched a small hole in the material.  Current 
could pass through that hole.  If that hole could be moved around in the plane 
of that sheet of material, it could confound the silver ions trying to migrate 
towards that hole, as they rarely succeed in passing through it before it has 
moved to somewhere else.  Could this allow an indefinite amount of silver ions 
to get into solution?

  I guess it is like creating an artificial sense of "infinite distance" 
between electrodes without there ever being such a thing.  

  Another concept is to literally create a large distance between electrodes.  
Could this not also be helpful in reaching higher concentrations of silver 
ions?  A way to do this is to create some kind of a maze for the ion to have to 
travel through.  


The problem is that the ions will over a short time diffuse so that they are 
even throughout the solution due to diffusion.  This this would accomplish 
nothing.  However I have heard of people socking the electrode, apparently the 
ions can have a hard time getting through the cloth to the other electrode.  If 
you put a osmosis barrier in there, that just might do what you are wanting.

Marshall



  David



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