----- Original Message -----
From: "Tony Moody" <[email protected]>

Hi Tony,

Thanks for your reply.

> Ivan,
> I guess the complication of using a calibration solution is to cater
for
> any oxidation on the probes faces or to account for the probes not
being
> the exact size and distance apart. There must be some reason.
> This circuit uses a 10kHz rectangular wave oscillator which is high
> enough frequency to prevent electrolysis. DC voltage or current would
> distort the measurement.

You're right... the use of a calibration solution is to compensate for
the discrepencies in the sensing mechanism, and it makes sense to
calibrate in a solution similar to the one you are measuring, but I have
calibration solutions in silver nitrate, potasium chloride and sodium
chloride, and have found that the precision resistor to be spot on. That
may well change over time I suppose, but for the purpose of reading the
concentration of CS, which is different from the theoretical measurement
of Ag+ ions by some margin (although repeatable from batch to batch)
some mis-calibration would not matter much.

> A 555 chip powers a resistance bridge (including the unknown
> conductance) which feeds a TLC272 opamp with feedback to give X10
> amplification, signal is then high quality rectified with the other
> TLC272, buffered with another one and pumped through a 50uA meter for
> indication.
>
> BTW They talk of using two pins from a print header, preferably gold
> plated, for the probes. Also talks about a fixed distance apart but
not
> an enclosed volume.
>
> Tony

Is there a link to this circuit?

Regards - Ivan


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