Roger wrote:
>  

> 
> Ivan& Frank: I propose that the mechanism that permits a slight amount of 
> silver (but sufficient to have germicidal activity) to dissolve in pure 
> water, is based on the type & concentration of impurities alloyed with the 
> silver (which provides micro-corrosion sites to electrochemically dissolve 
> silver into the water). So, why not conduct a simple series of tests. Anyone 
> who has 0.9999 (or, preferably, higher purity) silver should place it in 
> distilled water and measure the conductivity every few weeks. Simultaneously, 
> the same test should be repeated for 0.999 silver, and sterling silver (which 
> contains about 92% silver, I believe). Plot these conductivity values Vs 
> time. I believe what you will find is that the conductivity of the water 
> containing the 0.9999 silver will rise and level off because some of the CO2 
> from the air above will dissolve in the DW, BUT, because of its high purity, 
> practically no silver will dissolve. However, for the less pure silver, the 
> conductivity will continue to rise with time because some of the silver will 
> dissolve in the DW UNLESS the metal surface passivates (a good researcher 
> always has a ready made excuse if his idea doesn't pan out -- helps to remain 
> gainfully employed). However, I don't expect this to happen since silver 
> oxide/hydroxide/carbonate are unlikely to form. The ONE THING that should be 
> kept far, far away form these tests is ANY source of sulfide sulfur (even 
> infinitesimal amounts of H2S from eggs or other sources will screw things 
> up). So do these tests in SEALED bottles. Whatever CO2 is "captured" inside 
> the bottle will reach equilibrium with the DW. AA analysis for silver should 
> be used to confirm some of the "higher" conductivity results. Roger 


I would not depend on conductivity to prove the silver dissolved. I would use 
only an AAS.

If you would like to perform the procedure described above, then send me the 
samples, I will run the AAS test for silver.

frank key


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