In a message dated 9/29/2001 1:16:01 PM Eastern Daylight Time, 
[email protected] writes:


> Subj:Re: CS>Ions vs Particles
> Date:9/29/2001 1:16:01 PM Eastern Daylight Time
> From:    [email protected] (Ode Coyote)
> Reply-to: <A HREF="mailto:[email protected]";>[email protected]</A>
> To:    [email protected]
> 
> 
> 
> 
>   I've heard that [13 PPM limit for ionic silver] but can't recall where
> it came from.
> 
> Practically speaking, I can make 25 PPM ionic/particulate mix with LVDC
> but the PPM drops back a few points in storage over night and the TE
> gains in intensity.
> 
> I have not been able to make a totally ionic sol over about 13 PPM in
> very warm water as it starts to develop a TE around that point or sooner
> and the TE intensifies as the water cools...and conductivity drops.
> 
> So, my question is, what would the practical limits of ionic silver be
> using a given process, at what temperature.  And, doesn't any solute
> precipitate [form a TE] when the temperature drops if it was saturated at
> 


Ken: As my calculation shows there is no practical limit to Ag+ solubility in 
a typical CS process short of adding salt intentionally, or something 
similar, that would precipitate an insoluble silver compound. 

> 
> What happens when the charge leaks off? [ions gain back their electrons
> from the outside, be it from cosmic rays or radio transmissions or
> whatever...maybe even from dissolved oxygen?]  Wouldn't it go
> 


Ken: I think you are referring to the reduction of ionic silver by sunlight 
which is known to occur for silver nitrate and silver halides, neither of 
which should be present in a typical LVDC CS product. Variations is 
particulate silver particle size with time occurs as well. Perhaps Frank or 
Ivan can address that issue, I'm not knowledgeable enough to comment.

> 
> I don't think there should be a difference between a HVAC produced ion
> and a LVDC produced ion. The numbers may be different due to differing
> energy levels in production but what happens when that energy
> 


Ken: Perhaps the "energy is not disipated" in an HVAC CS product because only 
a very small proportion of the total silver is particulate. If only a few PPM 
of silver particulate are present then these particles have a good chance of 
remaining stable.

Roger