Mike,
Yes, we are saturating the filters, drying them, then firing.  Aside
from the tiny amount of CS we use, the filters are made entirely from
local, red clay, combined with a very fine grained combustible, which
burns out, thus aiding permeability. In this case the combustible is
wheat flour, which is inexpensive in Bangladesh. Keeping the materials
simple will help keep the purifiers very cheap.

My primary challenge in developing this purifier has been to achieve
good flow, and get control over the amount of flow. To do this we first
prepare a 'grog,' a pre-fired material comprising 37% flour and 63%
earthenware clay. We do not use a lot of water in the mix, as potters
do, but keep it 'dry,' about 15 to 20% water. We then press this
material into disks using a car jack. The disks are then dried, fired
and crushed to the powder we call 'permeable grog.'

Permeable grog is mixed with un-fired red clay powder, in some ratio
that achieves the amount of flow we want.  Aside from the micro-porosity
of the grog, the mechanism of flow is what appears under the microscope
as a network of elongated pores, appearing to be an average of 100
microns diameter by perhaps 0.05mm. in length. These pores (or planar
shapes) occur because the un-fired clay shrinks away from the grog
during the processes of drying and firing.

As a result our purifiers, 6cms. dia. by 17cms height, with wall
thickness 1.2cms., give a flow ranging from 0.5 to 1.5 liters per hour,
depending on the mix of materials, the column height and several other
variables. By contrast a convnetional earthenware container filled with
water will be merely damp on the outside. The reason for this is that
while there are lots of pores within the earthenware these are only very
poorly inter-connected.

The idea of mixing the clay materials with the CS solution would appear
to be a good one, and I'm anxious to try it. But right now we are simply
doing the things which we know will work. For one thing, if mixing CS in
with the clay did not work I'm afraid we would not immediately know the
reason for this, as there are so many variables, and our 'lab' is a
collection of very primitive devices. It is one thing to do appropriate
technology in the field and quite another to do it in the lab. Still, by
patience, trial and error and appropriate evaluation, over time we hope
to greatly improve our purifier.
Reid

Mike D. said:
Reid,

You're talking about saturating the filter elements in CS then drying
and firing them, correct?

Are the filter elements themselve produced locally? From what kind of
clay medium are they made? If it's a powdered or crushed dry clay that
is re-hydrated before forming or slip casting, would it make sense to
use water with silver in it to wet the clay? Then the bisque firing will
incorporate the silver right in the substrate, in a fashion that will
keep the silver bound but available, I'd bet.

There's no way I can think of to avoid blackening in a reducing
atmosphere, but then I've got *no* experience there. On the other hand,
are you sure that the oxide is not an acceptable form for the silver?

Interesting project. Thanks for sharing it with us.

Be well,

Mike D.



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