Oops! I am afraid I misled you folk as to the measurement of silver by
Atomic Absorption Spectrophotometry. Bob was right in the first instance in
that particles less than about 5 microns do not need acid digestion in order
to vaporise in the machines flame, and so AAS will measure TOTAL content of
CS.

Here is the heads up I received from Frank Key:

AA does not require that the silver
> particles be digested
> with acid if the particles are below about 3-5 microns. No
> particles of that
> size would stay suspended. The flame will vaporize the
> particles and provide
> accurate AA results. This is explained in the paper on
> silver-colloids.com
> titled "Determining Properties of Colloidal Silver".
>
> A spectrophotometer requires that the particles be digested.
> If no digestion,
> then only the ions will measured. AA measures total silver
> (particles + ions)
> without digestion.

Regards
Ivan.


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