Marshall,
Now I'm rereading the last part of your message, and it sounds as if
this is another good suggestion, using AgNO3 with cafeine, along with
some other silver already present.  Just a couple of questions and
observations:

If the first silver in the purifier medium were the nitrate, fired then
going to metal, it seems the particles would be very small.  By contrast
I'm thinking that if using CS the particles may be a lot bigger,
something like 100 nanometers.  This difference wouldn't seem all that
important to me, given that lots of things have worked as disinfectant
so far, various forms of silver and different particle sizes.  But in
these several scenarios, if doing additional treatment with the nitrate
then the caffeine, then enlarging particle size, what would then be the
various implications?  For one thing, according to what you're saying
the existing particles will get bigger, no additional particles
forming.  So far I'm not seeing clearly and maybe a few days of thought
will help.

A novel prospect would appear to be first saturating with the density of
particles desired, albeit small particles, then growing these particles
in the second treatment, to an optimal size.  But while it sounds good
on paper I'm hard put to think what those optimal densities and optimal
sizes would be.
Reid

Marshall Dudley said:
.........I still think that a mixture of CS, silver nitrate, and a
developer could do wonders.  Have you tried that?  The CS
would provide silver atoms/particles for the silver in the silver
nitrate to plate out on, and the developer (even
caffine works if you keep the ph right), will cause the silver to plate
out onto the particles over a few minutes
time.

A way to do this without having to mix up a new batch each time would be
to saturate the unit with CS, or put it
in the original mixture before firing. Then once it is dry, slowly force
a mixture of silver nitrate and developer
through it.  When the silver crystals are as large as you want (the
whole thing should turn grey then black as the
crystals increase in size), flush with clean water to remove the
developer and silver nitrate.  If you let it sit 15
minutes or so, then most of the silver nitrate should reduce, thus
reducing wasted silver.  Be sure to pick a
developer that you can either completely wash out, or one that is
non-toxic.  I think caffine may be a good
choice for that since it is pretty well non-toxic.

For additional insight on this, I suggest researching photo developing
techniques.

Marshall



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