Have you taken a look at Tollens reagent?

This mixture will coat a surface with silver.

http://jchemed.chem.wisc.edu/JCESoft/CCA/CCA5/MAIN/1ORGANIC/ORG12/TRAM12/D/0384525/THUMBS.HTM

http://www.finishing.com/114/08.html

http://home.school.net.hk/~chemmag/issue3/oli/sm.htm

http://download.micron.com/pdf/education/lessonplans/deposition.pdf

The basic operation is to mix silver nitrate with with sodium hydroxide.
This will produce silver oxide.  Since silver oxide has a fairly low
solubility in water it will precipitate out. Then if you add ammonia, it
will form fulminating silver which dissolves back into solution.  The
addition of glucose to this will cause the fulminating silver to reduce to
silver metal, coating every particle in the pottery with a thin silver
coating.

According to
http://www.science.uwaterloo.ca/course_notes/chemistry/chem267l/Pdfs/Exp5_charbohydrates.pdf

if the walls of the beaker are not scrupulously clean, then the solution
will produce a grey black precipitate in the solution which is of course
nano sized silver particles.

So, not only will silver likely adhear to the particles of pottery coating
them, but they will also form as distinct particles, which would hopefully
get trapped in the pottery as well giving a very large surface area of
silver to the pottery.

Do not allow the fumninating silver solution to dry out without being
reduced.  Fulminating silver is a contact high explosive like
nitroglycerine.  However as long as it is kept wet, it is stable.

Marshall




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