Most likely much of these batches have a high silver carbonate. Silver
carbonate is highly unstable and thus very prone to change from any outside
influences.

## That's a possibility, however, silver carbonate is light sensitive and this way strong stuff stays on a sunny window sill unchanged for weeks and weeks. I store all my CS there just to see what happens. Nothing hardly ever does. The container/generator setup is fairly well sealed from air circulation with very little air space. [3 or 4 CCs in air volume with a 2 " diameter of exposed surface area?]
Ode


>
>
> Perhaps past that 25-30 uS solubility limit other configurations of oxides
> start forming??? [Silver Peroxides and Tetroxides maybe?]

That is another possibility that I have not previously considered.

Marshall

>
>
> Ode
>
> At 10:18 AM 12/14/2005 -0700, you wrote:
>
> >
> >
> >Why do the silver ions in a dissolved salt have the possibility of causing
> >Argyria and the free ions in a mixture of colloidal and ionic silver not
> >do that?
> >
> >
> >
> >Jim
> >
> >
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