Caution if fine.  

However, I will go out on a limb by saying that the hydroxide will not
combine with the copper or brass material of the cathode.  I believe
that the negative charge on the cathode would work to repel the
negatively charged hydroxide ion and that therefore they would not be
able to combine.  Perhaps, if the voltage was turned off and the
electrodes were left in the solution then undesirable materials would be
made by the hydroxide combining with the base metals of the cathode.

Dan



>>> Marshall Dudley <[email protected]> 1/5/2006 10:21:45 AM >>>

Dan Nave wrote:

> Perhaps "Ole Bob" will answer this but in the meantime I'll chime in
> with what I've learned here...
>
> The metals will come off the positive electrode (anode) which, in
this
> case, is the silver one.  The brass is the negative electrode so it
is
> not going to be releasing metal ions or particles into the water. 
With
> this DC system we should get the good quality "colloidal silver" that
we
> expect.
>
> Dan

The hydroxide radical is released at the cathode. The hydroxide radical
is
very reactive and will almost certainly react with the copper and zinc
in the
brass producing copper hydroxide, zinc hydroxide and/or copper oxide
and zinc
oxide.  The only metals I know that can be safely be used on the
cathode are
noble metals, maybe chrome, and high chrome stainless steel.  The crome
forms
a non-soluble conductive barrier on the steel surface when it oxidized
preventing further oxidization.

Marshall



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