Hi Jose,
if you're using Skype 4, answers are very simple:
1. ctrl+shift+l has been eliminated for now because of sorts of problems 
which they found with this command;
2. go to tools / Options / General settings, and check the checkbox wich 
says: "When pressing enter on a contact start a call", or something like 
that, I do not remember exactly. It will open the chat window but also start 
the call.
Hth.
Bye!
Barbuz 


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